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Solutions of Time-Independent Schrodinger Equation
Solutions of Time-Independent Schrodinger Equation
Schrodinger Equation
dx dt dx dx dt dx
k 0 v k 0 v
dt dt dt k dt dt dt k
wave velocity
If c1= c2 there are two oppositely directed traveling waves that combine
to form a standing wave.
1 t 1
Node position: kx t (n ) x (n )
2 k 2 k
ei(kx t ) ei(kx t ) dx
2
B
k p 2mE
k 2mE /
xp
2
x p 0
p k
The probability density * for a group traveling
These wave functions contain wave function of a free particle. With increasing time
only a single value of the wave the group moves in the direction of increasing x, and
number k. also spreads.
Probability flux
2
( 2 V)(x, t) i (x, t) (1)
2m t
2
*
( V) (x, t) i
2 *
(x, t) (2)
2m t
(1) * (2)
(*) i
[ (* * )] 0
t 2m
*
i
j (* * )
2m
j 0
t
Consider wavefunction
(x, t) Aei(kx t)
* A*A
i
j (* * )
2m
k *
A A vA*A
m
wave velocity
6-3 The step potential (energy less than step height)
2m
1 (x) 2 (E 0)1 (x) 0
(x) 2m (V E) (x) 0
2 2 0 2
1 (x) Ae ik1x
Be ik1x
, k1 2mE /
k2x
2 (x) Ce k2x
De , k 2 2m(V0 E) /
x , (x) 0 C 0 B.C 1
1 (x) Ae Be
ik1x ik1x
, k1 2mE /
k2x
2 (x) De , k 2 2m(V0 E) /
Consider continuity of (x) at x=0 B.C 2
The combination of an
incident and a reflected
wave of equal intensities
to form a standing wave.
Running wave Exponential decay
Forbidden region
Penetration depth
Penetration depth
x 1/ k 2 / 2m(V0 E)
E E Vo
Example 6-1. Estimate the penetration distance x for a very small dust
particle, of radius r=10-6m and density =104kg/m3, moving at the very low
velocity v=10-2m/sec, if the particle impinges on a potential of height equal to
twice its kinetic energy in the region to the left of the step.
Vo-E = K
Example 6-2. A conduction electron moves through a block of Cu at total energy E
under the influence of a potential which, to a good approximation, has a constant value
of zero in the interior of the block and abruptly steps up to the constant value Vo>E
outside the block. The interior value of the potential is essentially constant, at a value
that can be taken as zero, since a conduction electron inside the metal feels little net
Coulomb force exerted by the approximately uniform charge distributions that surround
it. The potential increases very rapidly at the surface of the metal, to its exterior value
Vo, because there the electron feels a strong force exerted by the nonuniform charge
distributions present in that region. This force tends to attract the electron back into the
metal and is, of course, what causes the conduction electron to be bound to the metal.
Because the electron is bound, Vo must be greater than its total energy E. The exterior
value of the potential is constant, if the metal has no total charge, since outside the
metal the electron would feel no force at all. The mass of the electron is m=910-31kg.
Measurements of the energy required to permanently remove it form the block. i.e.,
measurements of the work function, show that Vo-E = 4ev. From these data esitmate the
distance x that the electron can penetrate into the classically excluded region outside
the block.
6-4 The step potential (energy greater than step height)
0 ,x 0
V(x)
V0 ,x 0
2m (I) ( II )
1 (x) 2 (E 0)1 (x) 0
(x) 2m (E V ) (x) 0
2 2 0 2
1 (x) Ae ik1x
Be ik1x
, k1 2mE /
ik 2 x
2 (x) Ce ik 2 x
De , k 2 2m(E V0 ) /
2 (x) Ce ik 2 x
, k 2 2m(E V0 ) /
Consider continuity of (x) at x=0 B.C 2
(k1 k 2 ) 2 4k1k 2
R T 1
(k1 k 2 ) (k1 k 2 )
2 2
R+T=1
k1k2()RTVoVo
V(x)V(x)
Example 6-3. When a neutron enters a nucleus, it experiences a potential energy
which drops at the nuclear surface very rapidly from a constant external value V=0
to a constant internal value of about V=-50 Mev. The decrease in the potential is
what makes it possible for a neutron to be bound in a nucleus. Consider a neutron
incident upon a nucleus with an external kinetic energy K=5Mev, which is typical
for a neutron that has just been emitted from a nuclear fission. Estimate the
probability that the neutron will be reflected at the nuclear surface, thereby failing
to enter and have its chance at inducing another nuclear fission.
A*A
*
[( 2
k 2 2
) sinh 2
( a) 4 2 2
k cosh 2
( a)]/(4 2 2
k )
CC
( 2 k 2 ) 2
sinh 2
( a) cosh 2
( a) , cosh 2
y 1 sinh 2
y
4 k2 2
( 2 k 2 ) 2
1 sinh 2
(a)
4 k 2 2
v3C*C ( 2 k 2 ) 2 1
T [1 sinh 2
( a)]
v1A*A 4 2 k 2
4E(Vo E)
T
4E(Vo E) Vo2 sinh 2 a
For a >> 1
1 1
sinh 2 a (ea e a ) 2 e 2 a
4 4
Vo2 sinh 2 a 1
T [1 ]
4E(Vo E)
Vo2e2a Vo2 e2a
[1 ]1 [ ]1 16E(Vo E) e 2 a
16E(Vo E) 16E(Vo E) V2o
Case of E E V0
i , 2m(E Vo ) /
2 2 2m(E Vo ) /
(k 2 2 )2 1
T [1 sinh 2
(i a)]
42 k 2
Vo2
[1 (i sin a) 2 ]1
4E(E Vo )
4E(E Vo )
4E(E Vo ) Vo2 sin a