Professional Documents
Culture Documents
Omw 052
Omw 052
Presented by
Kinetic Investigations and Special Services (KISS)
Representative: Breanna Lee, Researcher
Di-olefins hydrogenation requires a catalyst
to promote the formation of product
https://en.wikipedia.org/wiki/Hydrogenation
http://philschatz.com/chemistry-book/contents/m51104.html
Intrinsic rate of reaction is evaluated in a
non-isothermal CSTR
Power Law Rate Equation
=
First Order, =1
Design Equation
, ,
=
= .
Linearization of the rate law determines
reaction order and intrinsic rate constant
= + ( ) 0.25 0.45 0.65 0.85 1.05 1.25
-0.9
= . .
-1.1 y = 1.09x - 2.55
= . R = 0.995
-1.3
, 95 = 0.0817
ln(r)
-1.5
, 95 = 0.0747 -1.7
-1.9
Feed Flow Rate Range :
3 -2.1
1.0 6.0
-2.3 ln(C)
Arrhenius equation produces intrinsic
activation energy and pre-exponential factor
0.0027 0.0029 0.0031 0.0033 0.0035
= 0
-2
= . .
-4
= .
ln(k)
-6
, 95 = .
-8
y = -9892.4x + 25.504
, 95 = . R = 0.9998
-10
-12 1/T [K ]
Temperature Range: 280 K - 360 K
Diffusion factors limit rate at high T,
while the intrinsic rate limits rate at lower T
Temperature Dependence
Peak moves
More
to molecules
higher
exceed
energyactivation
energy
2
= 1 , Ea = 82.3 KJ/mol
0 At low
0.0023 0.0028 0.0033 = 0.892 , Ea = 77.9 KJ/mol
temperatures,
-2 =1
ln(k)
-10
1/T K-1
Additional runs indicate neglible mass
transfer limitations beyond 400 K
5
3
440 K
425 K 3
2
1
1
-10.0021 0.0025 0.0029 0.0033
ln (k)
0
ln (k)
-1
-5
420 K
-2 < 1 at T > 400K -7 Overall Ea = 91.1 8.4
Intrinsic Ea = 83.0 0.2
-3 = 1 Ea= 82.4 0.1 kJ -9
0.8
0.6
0.4
0.2
0
0 50 100 150 200 250 300 350
Hours on Oil (t)
At T= 350K, the 1st order deactivation
model indicates catalyst deactivation
Experimental Data Trend
0.2
=
0.1 No Deactivation
0
0 50 100 150 200 250 300 350 400 450
-0.1
ln (a(t))
-0.2
-0.3
-0.4
-0.5
0.8
Activity
0.6
0.4
0.2
0
0 50 100 150 200 250 300
1.2
Intrinsic Rate, r .
1
Intrinsic Rate Constant, .
0.8 Reaction Order, . .
Activity
0.1
0
0 50 100 150 200 250 300 350 400 450
-0.1
ln (a(t))
-0.2
-0.3
-0.4
-0.5
Experimental Data Trend
-0.6
Linear (No Deactivation) y = -0.0011x
-0.7 R = 0.1892
Hours on Oil (t)