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Group 4 - Ozone Reaction With Manganese
Group 4 - Ozone Reaction With Manganese
Manganese (Mn)
GROUP 4
1. EVAN LIBRIANDY (1406607722)
2. HANDRIANTO WIJAYA (1406568154)
3, KEVIN ANTONIO TITO (1406568091)
4. OSEL SAKADEWA (1406604600)
5. RANA REZEKI NAJEGES (1406553026)
Manganese (Mn) Characteristics
Manganese has 2 valence in MnCO3 compound and has low solubility in water. However,
Manganese compounds such as MnCl2, MnSO4, Mn(NO3)2 have high solubility in water
(Eaton Et.al, 2005; Janelle, 2004 and Said, 2003).
Manganese (Mn) Characteristics
Due to extremely fast kinetics of iron oxidation, uncomplexed Fe(II) can easily
out-complete Mn(II) for ozone. Therefore, on the case where groundwater
contans iron, manganese oxidation occurs at low doses, such that only after
the Fe(II) is nearly gone, the oxidation of Mn(II) begins.
On the case where groundwater and water have low organic contents, the
doses of ozone required to completely oxidize iron and manganese are close
to the theoretic stoichiometric doses, 0.43 mg O3 mg-1 Fe and 0.88 mg O3 mg-1
Mn, that is, if the treated water contains no other ozone-demanding
substances, such as nitrites or sulfide.
Manganese (Mn) Reduction Reaction
by Ozone (O3)
The precise excess ozone dose depends on the bicarbonate concentration: the
presence of high concentration of bicarbonate can modify the consumption of
oxidant such that less ozone is required.
With time, the sand grains become coated with oxides of manganese and iron, and exhibit the
“greensand” effect. This is a catalytic phenomenon that includes adsorption of Mn(II) on the
oxide surface and subsequent oxidation. For this latter process to occur over long periods of time,
the sand surface must be periodically exposed to a chemical oxidant such as chlorine or
permanganate.
The oxidants undergo a redox reaction at the oxide surface, thereby renewing its oxidative
power. As a result, small amounts of permanganate can be removed through filtration; however,
excessive amounts will result in breakthrough.
DAFTAR PUSTAKA
Ahmad bin Jusoh. Et. al. 2005. Study on the Removal of Iron and Manganese in Groundwater by
Granular Activated Carbon. Santa Margherita – Italia : Elsevier.
Anonim. Iron and Manganese Removal. Minnesota – USA : SDWA
Alaerts, G. dan Sri Santika Sumestri. 1987. Metode Penelitian Air. Surabaya: Usaha Nasional
Arifin. 2007. Tinjauan dan Evaluasi Proses Kimia (Koagulasi, Netralisasi, Desinfeksi) di Instalasi
Pengolahan Air Minum Cikokol, Tangerang. Tangerang : PT. Tirta Kencana Cahaya Mandiri.
Arifiani, N.F dan Hadiwidodo, M. 2007. Evaluasi Desain Instalasi Pengolahan Air PDAM Ibu Kota
Kecamatan Prambanan Kabupaten Klaten. Semarang : FT-TL Universitas Diponegoro.
Bruce Seelig. Et. al. 1992. Treatment System for Household Water Supplies ; Iron and Manganese
Removal. USA : NDSU.
C. Calderon. Et. al. 2005. Iron And Manganese Removal From Water. Mexico : Mexican Institute of
Water Technology
Eaton, Andrew. Et.al. 2005. Standard Methods for Examination of Water and Wastewater. 21st Edition.
Marryland – USA : American Public Health Association.
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