X-RAY DIFFRACTION

Laue diffraction pattern

CRYSTAL STRUCTURE
X-RAY
CRYSTAL INTERACTION
DIFFRACTION PATTERN ANALYSIS.
 CRYSTAL STRUCTURE
Transformation : r’= r +u1 a1+u2 a2+u3 a3
Symmetric restrictions .
Bravais lattices
MILLER INDICES[h,k,l]
X-RAYS AS COLLIMATED BEAMS
 Diffration/Interference
n  2dhkl sin hkl
a
d Cubic crystal
hkl 
h2  k 2  l 2
Some points where we might picture it
wrong.
REFLEXION AND NOT REFLECTION.
MAPPING THE DIFFRACTION PATTERN
• n(r+t)=n(r)
• n(r)=∑n(G)exp(G.R)
• Reciprocal Lattice b1=2*Pi*(a2(cross)a3)/[a1
a2 a3]
• Reciprocal lattice vector G=v1b1+v2b2+v3b3
 DIFFRACTION CONDITION
• ∆k=G
• 2K.G=G^2
• d(hkl)=2*pi/|G|
APPLICATION
 References
Kittel
Anandh Subramanyam
Myers.