This document discusses the Ponchon-Savarit method for analyzing distillation columns. The Ponchon-Savarit method uses enthalpy-composition diagrams which take into account latent heats, heats of mixing, and sensible heats. It provides a graphical procedure combining enthalpy and material balances to determine condenser and reboiler duties without assuming molal flow rates. The document outlines how to construct enthalpy-composition diagrams using heat capacity, boiling temperature, latent heats of vaporization, and heat of solution data. It also provides the equations used to obtain the saturated liquid and vapor lines on the diagram.
This document discusses the Ponchon-Savarit method for analyzing distillation columns. The Ponchon-Savarit method uses enthalpy-composition diagrams which take into account latent heats, heats of mixing, and sensible heats. It provides a graphical procedure combining enthalpy and material balances to determine condenser and reboiler duties without assuming molal flow rates. The document outlines how to construct enthalpy-composition diagrams using heat capacity, boiling temperature, latent heats of vaporization, and heat of solution data. It also provides the equations used to obtain the saturated liquid and vapor lines on the diagram.
This document discusses the Ponchon-Savarit method for analyzing distillation columns. The Ponchon-Savarit method uses enthalpy-composition diagrams which take into account latent heats, heats of mixing, and sensible heats. It provides a graphical procedure combining enthalpy and material balances to determine condenser and reboiler duties without assuming molal flow rates. The document outlines how to construct enthalpy-composition diagrams using heat capacity, boiling temperature, latent heats of vaporization, and heat of solution data. It also provides the equations used to obtain the saturated liquid and vapor lines on the diagram.
SHROFF S.R. ROTARY INSTITUTE OF CHEMICAL TECHNOLOGY
Mass Transfer Operation-2
Ponchon Savorit Method
B. E. III, Semester – VI CHEMICAL ENGINEERING
Prepared By: Varun R Doshi -140990105014
Ponchon-Savarit Method (Enthalpy-composition diagram) a) Takes into account latent heats, heats of mixing & sensible heats. b) No assumption of molal flow rates. c) Graphical procedure combining enthalpy & material balances. d) Provides information on condenser & reboiler duties. The diagram at a given constant pressure is based on reference states of liquid and temperature such as 273K. Use enthalpy concentration data:- The data that require for enthalpy concentration diagram are: 1-Heat capacity of the liquid, Cp 2-Boiling temperature, Tb 3-Latent heats of vaporization, λ 4-Heat of solution, ∆Hmixing The saturated liquid line in enthalpy h kJ/kg can be obtained from the following :- The saturated vapor line can be obtained from the following equation below:-
x & y = mol or mass fractions of liquid & vapor.
T= boiling point of temperature Tr = reference temperature C p,L & C p,v = liquid & vapor heat capacity ∆Hmix = heat of solution at Tr ( neglected for ideal system). Ponchon Savarit method • The difference in enthalpy between the streams passing each other is constant, with the enthalpy of this stream being Q’ = hD + Qc / D , where Q c is the condenser duty in kJ/h. Thank You
Applied Catalysis Volume 69 Issue 1 1991 [Doi 10.1016%2Fs0166-9834%2800%2983297-2] Jean Bandiera; Claude Naccache -- Kinetics of Methanol Dehydration on Dealuminated H-mordenite- Model With Acid and Basic Active Ce