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Joel Composites Presentation
Joel Composites Presentation
• Various materials were being used for dental restorations since time
immemorial. These included stone chips, cork, turpentine, gum, lead, gold
leafs, resins, etc. Yet, none of these materials were able to provide
satisfactory results.
• Finally, by 7th century A.D, the Chinese developed & started using
‘Amalgam’ which had quite favorable properties.
• Over the years, it was developed to provide even better properties &
thereby the better clinical results.
• Therefore, the search for a primary permanent restorative material
for posterior teeth was eventually successful with the development
of Amalgam.
• Since this material was unaesthetic, it was not accepted for
restoration of anterior teeth. Then began the search for an aesthetic
restorative material.
• By 1878, Fletcher developed the first translucent material called
“Silicates”. This material, though initially well accepted, was found to
have drawbacks such as being highly irritating to pulp, high
marginal leakage, staining, poor in adhesion & unsatisfactory in
esthetics.
• Self curing acrylic resins were developed in 1930’s in Germany but
not marketed till late 1940’s because of the World War II.
Failed silicate cement restorations displaying Acrylic resin restoration displaying marginal
discoloration and loss of contour discoloration
Elliott JE, Lovell LG, Bowman CN. Primary Cyclization in the Polymerization of Bis-Gma and
Tegdma: A Modeling Approach to Understanding the Cure of Dental Resins. Dental Materials, 2001;
• On the other hand, triethylene glycol dimethacrylate TEGDMA has
less viscosity than Bis-GMA (10 mPa.s 23 ̊C[19]) .
• Typically, a 1:1 ratio of TEGDMA and Bis-GMA is used.
• TEGDMA results in a clinically objectionable increase in
polymerization shrinkage
Chae KH, Sun GJ. Phenylpropanedione; a New Visible Light Photosensitizer for Dental Composite
Resin with Higher Efficiency Than Camphorquinone. Bulletin of the Korean Chemical Society, 1998;
COUPLING AGENT
• The bond between the polymer matrix and the filler particles is
usually accomplished by the use of the silane coupling agent, 3-
methacryloxypropyl trimethoxysilane (MPTMS).
• A significant advantage of silane coupling agents is that the
hydrolysis (and reformation) of the chemical bond between silane
coupling agents and filler materials is a reversible process. This is
beneficial as it may reduce internal stresses in the material.
Venhoven BAM, De Gee AJ, Werner A, Davidson CL. Silane Treatment of Filler and Composite
Blending in a One-Step Procedure for Dental Restoratives. Biomaterials, 1994; 15: 1152-1156.
INORGANIC FILLER
O'Brien WJ. Dental Materials and Their Selection. Chicago: London: Quintessence
Pub. Co.; 2002.
• Other commonly used fillers include borosilicate glass, lithium,
barium aluminium silicate, and strontium or zinc glass.
• A range of silica-based glass fillers is available, including
amorphous or colloidal silica, fused silica and sol-gel zirconia silica
CLASSIFICATION
1. Isolation problems
2. Teeth with heavy or abnormal occlusal forces
3. Subgingival caries
4. Patient allergic or sensitive to resin composite
• Esthetic
• Conservative of tooth structure removal (less exten- sion, uniform
depth not necessary, mechanical retention usually not necessary).
• Less complex when preparing the tooth.
1. Root caries
2. Time consuming and costly then amalgam restorations
3. Technique sensitive
4. Have a higher LCTE, resulting in potential marginal percolation if
an inadequate bonding technique is used.
1. INTRODUCTION
2. HISTORY/ EVOLUTION OF COMPOSITES
3. DEFINITION
4. COMPONENTS OF COMPOSITES
5. CLASSIFICATION
6. INDICATIONS & CONTRINDICATIONS
7. ADVANTAGES & DISADVANTAGES
CONTENTS
1. Properties
2. Curing Systems
3. Curing Techniques
4. Curing Lamps
5. Hazards Of Curing Lights
6. Recent Advances
7. Conclusion
8. References
PROPERTIES
1. CONTINUOUS
CURING
TECHNIQUES :
2. DISCONTINUOUS
CURING
TECHNIQUES
CURING LAMPS
1. Tungsten-halogen :
• Many halogen curing lamps use a 50- to 100-watt bulb to produce
500 mW of light that peaks at 468 nm.
• This approach yields an efficiency rate of only 0.5%; the other
99.5% of the energy is simply given off as heat.
• Ham WT. Ocular hazards of light sources: review of current knowledge. J Occup
Med 1983;25:101–3.
• Ham WT, Ruffolo JJ, Mueller HA, Guerry DK. The nature of retinal radiation
damage: dependence on wave- length, power level, and exposure time. Vision
Res 1980;20:1105–11.
• Ham WT, Mueller H, Sliney D. Retinal sensitivity to damage from short
wavelength light. Nature 1976; 260:153–4.
• Ham WT, Mueller HA, Ruffolo JJ, etal. Basicmech- anisms underlying the
production of photochemical lesions in the mammalian retina. Curr Eye Res
1984;3:165–74.
• The first researchers to study eye damage from blue light were
Zigman and Vaugh.
1. ANTIMICROBIAL COMPOSITE:
• Silver and titanium particles were introduced into dental composites,
respectively, to introduce antimicrobial properties and enhance the
biocompatibility of the composites.
• Hansel C, Leyhausen G, Mai UE, et al. Effects of carious resin composite (co)monomers and
extracts on two caries associated microorganisms in vitro. J Dent Res. 1998; 77:60- 67.