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The Nucleus: A Chemist's View
The Nucleus: A Chemist's View
The Nucleus:
A Chemist’s View
Review - Nucleus
Collection of nucleons
Subdivided into neutrons and protons
Composed of smaller particles called quarks
Atomic number (Z): Number of protons in a nucleus
Mass number (A): Sum of protons and neutrons in a nucleus
Isotopes: Atoms with identical atomic numbers
but different mass number values
Review - Nuclide
Nuclear Stability
Positron γ-ray
production production
Alpha-Particle Production
Spontaneous Fission
Gamma-Ray Production
Positron Production
Electron Capture
Inner-orbital electron
b. 214
83 Bi produces a β particle
c. 237
93 Np produces an α particle
Positron
A 214
Therefore, X must be Z 84 Po
Decay Series
Critical Thinking
Rate of Decay
ΔN
Rate kN
Δt
Half-Life (t1/2)
Exercise
Exercise - Solution
Nuclear Transformation
Particle Accelerator
An ion is introduced at
the center of the device
The device accelerates the
ion in a spiral path by
using alternating electric
fields in the presence of a
magnetic field
Fission Reactors
206
Atoms of Pb now present 0.115 115
82
238
0.115
Atoms of 92U now present 1.000 1000
N 0.693
ln ln 0.8969 t
4.5 10 years
9
N0
E mc 2
First, calculate ΔE
Divide molar mass value of the nucleus by Avogadro’s
number
Amount is calculated in million electronvolts (MeV),
where 1 MeV = 1.60×10–13 J
Next, calculate ΔE per nucleon by dividing by A,
the sum of neutrons and protons
Binding Energy
12 J 1 MeV
BE per nucleon 1.14 10 13
nucleon 1.60 × 10 J
= 7.13 MeV/nucleon
Nuclear Fission
Chain-Reaction
Self-sustaining fission
process
Requires one neutron
from each fission event
to split another nucleus
Critical Mass
Nuclear Reactors
Reactor Core
Control Rods
Breeder Reactor
Reaction process
As the reactor runs, uranium-235 is split
Excess neutrons are absorbed by uranium-238 to
produce plutonium-239
Plutonium-239 is separated out and used as fuel for
another reactor
The reaction breeds nuclear fuel as it operates
Disadvantage - Hazards in handling plutonium
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Section 19.6
Nuclear Fission and Nuclear Fusion
Fusion Reactions
Critical Thinking
Depend on:
Energy of the radiation
Penetrating ability of the radiation
Ionizing ability of the radiation
Chemical properties of the radiation source
Radiation Hazards
Linear model
Damage from radiation is proportional to the dose,
even at low exposure levels
Any exposure is dangerous
Threshold model
No significant damage occurs below the level of
threshold exposure