Self healing nanotechnology

Presented By:-
Maulik Mittal
CM15219
B.E. Chemical with MBA
4th Year
 FEW QUESTIONS!

• What Is Self Healing Nanotechnology?

• Why Is Self Healing Nanotechnology Required?
Reference:- Mehdi Mahmoudiana,⁎, Ehsan Nozada, Mahmoud Ghasemi Kochameshkib, Mojtaba Enayatib, Preparation and investigation of hybrid self-healing coatings containing
linseed oil loaded nanocapsules, potassium ethyl xanthate and benzotriazole
on copper surface, Progress in Organic Coatings 120 (2018) 167–178
Reference:- Mehdi Mahmoudiana,⁎, Ehsan Nozada, Mahmoud Ghasemi Kochameshkib, Mojtaba Enayatib, Preparation and investigation of hybrid self-healing coatings containing
linseed oil loaded nanocapsules, potassium ethyl xanthate and benzotriazole
on copper surface, Progress in Organic Coatings 120 (2018) 167–178
Reference:- Mehdi Mahmoudiana,⁎, Ehsan Nozada, Mahmoud Ghasemi Kochameshkib, Mojtaba Enayatib, Preparation and investigation of hybrid self-healing coatings containing
linseed oil loaded nanocapsules, potassium ethyl xanthate and benzotriazole
on copper surface, Progress in Organic Coatings 120 (2018) 167–178
 CONCLUSION
Hybrid self-healing anti-corrosion coating was prepared with the incorporation of LO containing poly(urea-formaldehyde)
nanocapsules and anti-corrosion agent into the coating matrix. Copper surface were studied by optical microscopy and FESEM.
Results showed that created scratches were filled completely in hybrid coatings and corrosion resistance was considerably
improved by utilization of anti-corrosion agents, it can be said that polyurethane coatings showed better adhesion and
corrosion resistance compared to epoxy coatings, potassium ethyl xanthate as an anti-corrosion was more effective than
benzotriazole and consequently, cu7 which contained 3 wt% nanocapsules and 5 wt% potassium ethyl xanthate as anti-
corrosion agent in the polyurethane matrix was selected as optimal sample.
Weijie Wang a, Jian Yan a, c, *, Jiaqin Liu a, Dawei Ou a, Qingqing Qin a, Binbin Lan a,
Yu Ning a, Dan Zhou b, **, Yucheng Wu, Self-healing polyaniline-graphene oxides based electrodes with
enhanced cycling stability, Electrochimica Acta 282 (2018) 835 -844
Weijie Wang a, Jian Yan a, c, *, Jiaqin Liu a, Dawei Ou a, Qingqing Qin a, Binbin Lan a,
Yu Ning a, Dan Zhou b, **, Yucheng Wu, Self-healing polyaniline-graphene oxides based electrodes with
enhanced cycling stability, Electrochimica Acta 282 (2018) 835 -844
Weijie Wang A, Jian Yan A, C, *, Jiaqin Liu A, Dawei Ou A, Qingqing Qin A, Binbin Lan A, Yu Ning
A, Dan Zhou B, **, Yucheng Wu, Self-healing Polyaniline-graphene Oxides Based Electrodes
With Enhanced Cycling Stability, Electrochimica Acta 282 (2018) 835 -844
 CONCLUSION

• In this work, an effective strategy has been developed to enhance the cycling stability of PANI based electrodes by
improving the electrode level structural stability using shps. Reversible hydrogen bonding is able to heal the structure
damages spontaneously, which could rebuild the connection between PANI fragments and electrode matrix resulting in
saving the capacitance loss. As a demo, PANI and PANI-GO based self-healing devices exhibit capacitance retention of about
93% after 9000 cycles. Furthermore, the structure degradation of PANI has been suppressed by shortening the polymer
chain and combing with GO. The AT-GO self healing devices under pressure exhibit very good cycling stability with
capacitance retention up to 97.5% after 9000 cycles.
 REFERENCES
• “Nanotechnology – A Gentle Introduction To The Next Big Idea” By “Mark Ratner” And “Daniel Ratner”.
• Https://En.Wikipedia.Org/Wiki/Nanotechnology.
• Https://En.Wikipedia.Org/Wiki/Self-healing_material
• Weijie Wang A, Jian Yan A, C, *, Jiaqin Liu A, Dawei Ou A, Qingqing Qin A, Binbin Lan A, Yu Ning A, Dan Zhou B, **,
Yucheng Wu, Self-healing Polyaniline-graphene Oxides Based Electrodes With Enhanced Cycling Stability,
Electrochimica Acta 282 (2018) 835 -844
• Mehdi Mahmoudiana,⁎, Ehsan Nozada, Mahmoud Ghasemi Kochameshkib, Mojtaba Enayatib, Preparation And
Investigation Of Hybrid Self-healing Coatings Containing Linseed Oil Loaded Nanocapsules, Potassium Ethyl
Xanthate And Benzotriazole On Copper Surface, Progress In Organic Coatings 120 (2018) 167–178