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The Combined Gas Law

When measured at STP, a quantity of gas has a volume of


500 dm3. What volume will it occupy at 0 oC and 93.3 kPa?
PV PV
1 1
 2 2 (101.3 kPa) x (500 dm3) = (93.3 kPa) x (V2)
T1 T2 273 K 273 K

(101.3) x (500) = (93.3) x (V2)


P1 = 101.3 kPa
T1 = 273 K
V1 = 500 dm3 V2 = 542.9 dm3
P2 = 93.3 kPa
T2 = 0 oC + 273 = 273 K
V2 = X dm3
Gay-Lussac’s Law
Temperature Pressure P/T
The pressure and absolute
(K) (torr) (torr/K)
temperature
248 (K) of a gas
691.6 2.79 are
273 760.0 2.78
directly
298
related
828.4 2.78
– at373
constant 1,041.2
mass & volume
2.79

P
P
k
T
T
Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem
Gay-Lussac’s Law
The pressure and absolute
temperature (K) of a gas are
directly related
– at constant mass & volume

P
P
k
T
T
Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem
Combined Gas Law
P
V
PV
PV = k (CHARLES’
(BOYLE’S
(COMBINED
(Gay-Lussac’s
GASLAW)
LAW)

T
P1V1 P2V2
=
T1 T2
P1V1T2 = P2V2T1
Courtesy Christy Johannesson www.nisd.net/communicationsarts/pages/chem
Charles’ Law
Boyle’s Law
V = k
PV = k
T

P and V T and V
Ideal
change change
Gas Law
n, R, T are P, n, R are
constant constant
PV = nRT

P, V, and T change
Gas Law n and R are constant

Calculations Combined
Gas Law

PV
= k
T

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