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Coal Bed Methane: Dr. Keka Ojha Department of Petroleum Engineering Indian School of Mines Dhanbad India
Coal Bed Methane: Dr. Keka Ojha Department of Petroleum Engineering Indian School of Mines Dhanbad India
40.0
35.0
30.0
Billion m3
25.0
20.0
15.0
10.0
5.0
0.0
1970
1972
1974
1976
1978
1980
1982
1984
1986
1988
1990
1992
1994
1996
1998
2000
2002
2004
2006
NG Production NG Consumption Year
Source: BP Statistical Review 2007
Preliminary assessment
indicates that Damodar
Valley Coalfields viz.
Jharia, Bokaro, North
Karanpura and Raniganj
to be most prospective
CBM field. 14
CBM in India
Highlights - India
Blocks allotted: 26
Total resource in the allotted block: 1.4 TCM
Area opened up for exploration: 13600 sq km
Production potential from the allotted block: 38 MMSCMD
Power generation potential: 6700 MW
Reduction in CO2 emissions, if compared with coal
fired electricity generation of similar capacity: 27 MTY
IV ROUND BIDING
Government of India has awarded 7 CBM Blocks under fourth round of CBM bidding. The contracts for these 7 blocks were signed
on 29th July 2010.
The awarded blocks covering an area of 3727 sq.km. are located in the states of Assam (1), Jharkhand (1), Orissa (2), Madhya Pradesh
(1), Madhya Pradesh & Chhattisgarh (1) and Tamil Nadu (1).
The estimated CBM resources of these 7 Blocks is about 330 BCM with expected production potential of 9 MMSCMD.
List of 7 Blocks for which CBM Contracts were signed on 29th July 2010
Arrow Energy-TATA
5. ST-CBM-2008/IV Madhya Pradesh
Power
Arrow Energy- Oil India
6. AS-CBM-2008/IV Assam
Ltd
The largest CBM resource bases lie in the former Soviet Union, Canada, China,
Australia and the United States. However, much of the world’s CBM recovery potential
remains untapped. In 2006 (IEA, 2007) it was estimated that of global resources
totalling 143 trillion cubic metres, only 1 trillion cubic metres was actually recovered
from reserves.
Gas Generation Gas is generated in the source Gas is generated and trapped
rock within
and then migrates into the the coal.
reservoir.
Structure Randomly-spaced Fractures Uniformly-spaced Cleats
Thermogenic methane
GENERATION OF METHANE
Coal is a carbon-rich rock derived from plant material (peat) that
accumulated in swamps and was subsequently buried by ongoing
geological processes.
With increasing depth of burial, the plant material undergoes
coalification, releasing volatile matter (water, carbon dioxide, light
hydrocarbons, including methane) as it begins to transform into coal.
With ongoing coalification, the coal becomes progressively enriched
in carbon and continues to expel volatile matter.
Generation of methane and other hydrocarbons is a result of thermal
maturation in coals, and begins around the sub-bituminous "A" to
high volatile bituminous “C” rank stage, with amounts of methane
generated increasing significantly throughout the medium to low
volatile bituminous coal ranks.
GENERATION OF CBM
CBM is generated either from a biological process as a result of microbial action
or from a thermal process as a result of increasing heat with depth of the coal.
Stages of coalification incorporating four successive steps:
Peatification (anaerobic degradation of organic materials in the peat swamp)
Humification (formation of dark coloured humic substances an organic
residue of decaying organic matter. organic compound - any
compound of carbon and another element or a radical ) by anaerobic
degradation)
Bituminization (generation of hydrocarbons with increase in temperature and
pressure)
Debituminization (thermal degradation of matter and generated hydrocarbons)
COALIFICATION PROCESS
BIOGENIC METHANE &THERMOGENIC
METHANE
CHARACTERIZATION OF COAL
• Proximate analysis
• Elemental Analysis
• Petrographic analysis
• Gas content
• Porosity
• Permeability
• Compressibility of rock
PROXIMATE ANALYSIS PROCESS
Whole Coal
1gm, 72 mesh
1gm, 72 mesh
Heating at 108ºC, 1.5hr.
Coking at Volatile
500ºC, 30 min Combustion at 750 ºC, 910 ºC 7 Matter
30-60 minutes minutes
27
Fixed Carbon = 100-(Ash%+ M% + V.M. %)
Proximate analysis result of samples from Well
30
CHNS analyser 31
van Krevelen diagram
Composition of generated Hydrocarbons
Diagenesis
Catanesis
Meta
Friday, October 4, 2019
Kerogen Origin of organic Petroleum
H:C ratio O:C ratio
type material products
Mainly natural
Land plants in
Type III 1.0–0.3 0.4–0.02 gas with very
coaly sediments
little oil
Oxidised and No petroleum 33
Type IV 0.45–0.3 0.3–0.02
charred wood potential
Elemental analysis result of samples from
35
Carbon content Hydrogen content
well J1: 79.64 % to 90.23 % and well J1: 3.84 % to 5.30 % and
well J1: 0.60 % to 2.11 % and well J1: 0.49 % to 2.10 % and well J1: 3.26 % to 10.98 % and
well J2: 0.58 % to 1.99 % well J2: 0.56 % to 1.72 % well J2: 4.69 % to 8.94 %.
J1 J2
37
For studied coal samples, modified rice equation was also used to calculate the value of
vitrinite reflectance (Ro %)
Ro %= -2.056 × log (VM) + 4.203.
39
Friday, October 4, 2019
Well No. Maceral (Vol.)% Mean
Vitrinite Semi- Liptinite Inertinite Mineral Ro%
vitrinite matter
Well J1 32.04 to 73.35 0.60 to 4.10 0.02 to 15.02 to 51.03 5.73 to 23.00 1.23 to 1.65
0.98
Well J2 41.20 to 74.90 1.80 to 2.60 0.20 18.20 to 35.00 4.60 to 5.80 1.58 to 2.03
Well J3 43.70 to 59.00 0.60 to 2.00 0.20 to 20.00 to 45.10 6.20 to 35.10 1.42 to 1.79
0.40
J J
J 3
1 2
Porosity
Permeability
Density
Strength
Compressibility
Rank (Reflectance R)
In-situ cleat widths affect coal seam permeability, but difficult to quantify. Width
aperture may vary from mm to nm range, and height may range from microscopic
to seam thickness.
Cleats occur in coals of all geologic ages and are related to coal rank. Cleat
developments begins in lignites, which often exhibit poorly develped cleats with
irregular spacing and limited lengths.
Bituminus coals frequently show well-developed face and butt cleats with small
aperture spacingd.
Anthracite are often poorly cleated due to cleat healing during metamorphosis.
Better cleat development is associated with less mineral matter and ash.
POROSITY
Dual porosity system: Cleat or fracture porosity & matrix
porosity
Butt and face cleats porosity of coal of medium volatile
bituminus through anthracite rank is typically less than
5%: often less than 1%
Coal gas reservoir Engg is concerned with mobile water
porosity which is defined as the void space in a coal
containing water that will flow through the fracture in
response to a applied pressure differential.
Matrix porosity is comprised of irregular shaped voids in
organic matrix. Some porosity is due to relict of plant
while some is the product of coalification.
DENSITY
Coal density is less than conventional rock, varying from 1.25 -
1.70 (mineable coal) and increase with rank.
Bulk density of coal may be written as
If ‘a’ is expressed in micron and ‘b’ is expressed in mm, then the equation becomes
For ‘n’ no of cleats Flow rate in the cleat system described by Poiseulli’s equation becomes:
Where
Where is the hydrostatic stress, cf is the cleat compressibility. With vertical and hydrostatic stresses equal, the variation of permeability with depth
can be written as
Assuming a lithostatic gradient of 1psi/ft and a normally pressure basin with pressure gradient of 0.433psi/ft
=0.567d
At a particular depth or constant lithostatic pressure, the permeability variation with change in pore pressure may be expressed as (in hydrostatic stress
regime)
Hence, variation of permeability with depth can be expressed as
1
mean stress
Horizontal stress
0.1 Hydrostatic stress
0.01
1E-3
K/Ki)
1E-4
1E-5
1E-6
0 1000 2000 3000 4000 5000 6000
Pi-P (psia)
RESERVOIR PROPERTIES
C gi C ga
Recovery Factor RF Cgi = initial gas content,
C gi Cga = abandonment gas content,
f
= Fracture effective porosity,
Swfi = fracture water saturation (=0.80)
Bgi = initial gas formation volume factor
ρc = pure coal density,
fa = fractional ash content by weight,
fm = fractional moisture content by weight
Gi = Initial gas content
RF = Recovery Factor
The gas-in-place equation is:
G =1359.7AhρCgi
Where:
G = gas-in-place volume, scf
A = reservoir area, acres
h = reservoir thickness, feet
r = average in-situ rock density at the average
insitu rock composition, g/cm3
Cgi = average gas content at the average in-situ rock composition,
scf/to
PARAMETERS INFLUENCING THE TOTAL GAS-
IN-PLACE AND DELIVERABILITY
Coal
53
METHODOLOGY FOR CBM
PRODUCTION
A fully fractured coal may have the following natural fractures:
•Face cleats (primary).
•Butt cleats (secondary).
•Tertiary cleats.
•Fourth-order cleats.
•Joints.
CHANGE OF PERMEABILITY WITH
PRODUCTION:
1. Physical Adsorption
2. Chemical or Chemisorption
Physical Adsorption
Involves intermolecular forces (van der Waals
forces) between the gas molecules and the
coal (solid) molecules.
Chemisorption
Chemisorption's usually involves transfer
of electrons.
Desorption of Methane
PROPERTIES EFFECTING ADSORPTION CAPACITY
Ash content
Volatile matter
POVBN
PPORE
Cleat
Desorption
width
Adsorption
Flow through cleats
Coal
SCHEMATIC OF SORPTION CAPACITY WITH
GEOLOGIC PARAMETERS.
The typical formulation of Langmuir isotherm is:
where:
P = pressure (psia)
V = amount of gas at P, also known as gas content (scf/ton)
VL = Langmuir volume parameter (scf/ton)
PL = Langmuir pressure parameter (psia)
The Langmuir isotherm equation has 2 parameters:
1. Langmuir Volume (VL): This is the maximum amount of gas that can be adsorbed on a piece
of coal at infinite pressure. This value is asymptotically approached by the isotherm as the
pressure increases. The following image is of a typical isotherm and shows its relationship with
VL:
Typically, the units for the Langmuir volume parameter (VL) are scf/ton (volume gas per mass of
unit coal). The volume parameter can be converted to a scf/ft3 (volume gas per volume unit coal)
by multiplying it by the coal bulk density.
2. Langmuir Pressure (PL): This parameter affects the shape of the isotherm. The Langmuir
pressure is the pressure at which the Langmuir volume can be adsorbed.
Adsorption capacity of different rank of
coal as a function of pressure
MEASUREMENT OF IN-SITU GAS CONTENT
The Direct method involves following
components :
Sampling of Coal cores.
Lost Gas Estimation
Measurement of Desorbed Gas
Determination of Residual Gas
Total Gas Volume
Gas content (cc/g) Q= (Q1+Q2+Q3)/W, Canister for desorption study
Q= gas content
Q1= lost gas
Q2=desorbed gas
Q3=residual gas
W=weight of sample
77
Crushing apparatus
78
Desorption Test Lost Gas
Lost Gas Calculation
4000
3000
2000
1000
0
1000 0 5 10 15 20
2000
2000 14000
3000 Sq.Rt. of lost time (min)
4000
5000
6000
7000
8000
9000
10000
11000
12000
13000
14000
Sq.Rt. of lost time (min)
RELATION BETWEEN MEAN MAXIMUM REFLECTANCE OF
VITRINITE AND VOLATILE MATTER
0.9
0.8
Volatile matter (%, dry)
0.7
0.6
0.5
0.4
22 24 26 28 30 32 34 36 38 40 42
Vitrinite Reflectance (R0, max)
PROXIMATE ANALYSIS OF COAL
Dry basis :
Moisture Ash % = (Ash% as received basis /100 – M) × 100
Volatile matter
Vm % = (Vm % as received/100-M) ×100
Dry ash free basis (daf):
Fixed carbon
82
Reserve Estimation of CBM in Place by USBM method
3
7
Y= -10.61x+10.47
2
R =0.998
6
3
0.0 0.1 0.2 0.3 0.4 0.5 0.6
Ash + Moisture Content(fraction)
36
34
Langmuir Volume (VL)
32
30
28
26
24
22
10 15 20 25 30 35 40 45 50
2.18
2.16
2.14
2.12
Langmuir Pressure (MPa)
2.10
2.08
2.06
2.04
2.02
2.00
1.98
1.96
1.94
1.92
1.90
0.4 0.5 0.6 0.7 0.8 0.9
Vitrinite Reflectance (R0, max)
87
Output results Moisture Equibrated (daf) 88
Langmuir Volume (VL) (cc/g) 14.2 16.12
Langmuir Pressure (PL) (kPa) 3954 4027
Output results Moisture Equilibrated daf
89
Langmuir Volume (VL) (cc/g) 14.70 16.39
Langmuir Pressure (PL) (kPa) 4123 4213
Methane Adsorption Methane Adsorption
Isotherm Sample No: Isotherm Sample No:
RC01 RC02
90
91
Porosity
Permeability
Density
Strength
Compressibility
Rank (Reflectance R)
Higher productivity
Typical VCBM Well in Production
FRACTURING
Pumps Blender Hydraulic
fracturing
Pad fluid • Creation of highly conductive
path in the reservoir
Sand slurry Well • Fracture connects far
reservoir with wellbore
Displacing fluid • Allows untapped hydrocarbon
to flow into the well
50-1000ft
Propped Frac
Shale
Reservoir
Shale
113
HYDRAULIC FRACTURING
Job stages:
Effect:
generated
Sensitivity to water
118
UNCONVENTIONAL FRAC-FLUIDS
26-04-2012
Polymer Systems
Aqueous Methanol Based
Ojha-ISM,Dhanbad,India
WSEOR-Xian,China-Presented by Dr. K
Non-Aqueous Methanol Based
VES Foams
Hydrocarbon Based
119
GRAPHICAL REPRESENTATION OF CBM
FRACTURING
• Before we even consider CBM issues such as embedment, coal fines
plugging, and multiphase flow, there is reason to suspect that our propped
fractures have inadequate conductivity.
RCS
40%
Economy LWC
Porosity (percent)
30%
25%
27% more porosity
(9 porosity units)
20%
15%
0 2000 4000 6000 8000 10000 12000 14000
Multiphase flow
Coal Fines Plugging / Flowback
Coal compaction with high treating pressures
Erosion of coal frac faces during treatment by
angular sand is likely more severe than with
round ceramic. Erosion may contribute to
width, but also “contaminates” pack with fines.
– SPE 48886
Low reservoir energy to cleanup gel residue.
LWC clean up easier than sand.
Embedment
Additives
CONCLUSIONS
The conductivity needs of low pressure CBM wells are
often underestimated
For rapid dewatering and ability to handle multiphase
flow, superior fracture conductivity is needed
Many frac gels are extremely damaging to coals. It is
desirable to use low damage fluids but maintain
conductivity
Light weight ceramic proppants provide superior
productivity
Gas
Water
(production
fluid)
Coal Bed
WATER DISPOSAL
Water production and disposal assume a greater degree of importance in
coalbed methane (CBM) projects than in conventional oil or gas operations. In
marginally economic coalbed projects, the water disposal costs and the
attendant environmental accounting are critical factors in the investment
decision;
water
disposal costs economically make or break a marginal project.
Normally, water must be removed from the coal to lower the pressure and to
initiate methane desorption; however, near mining operations there may be
only small amounts of water to produce. The operator can also anticipate large
amounts of water being produced early in the process but decreasing
thereafter to an eventual low level.
Therefore, water disposal problems decrease with time, and the greatest
economic burden is placed on the operator in the first few years.
•Water purity ranges from nearly fresh in the Powder River basin to
marginally saline in the Warrior basin to a brine in the deepest coals. Water
purity and the quantity produced determine the means of disposal and the
costs of disposal.
•Suspended solids, total dissolved solids, and oxygen demand of produced
waters have the most impact on water treatment.
•High initial water flow rates normally decline as the hydrocarbon production
rate increases, which is counter to the conventional oil and gas process.
Lack of understanding of the unusual pattern of water flow and its relation to
methane desorption probably delayed recognition that methane could be
produced profitably from the country’s vast coal reserve.
Exponential decline in water production rate
Q. # 2
How is coalbed methane removed?
A. # 2
CBM is removed by removing water pressure which holds CBM in
place. Methane that was held in place by water pressure tends to
follow the water as it is pumped to the surface, where it is
captured and transported through pipelines. Fraccing fluids are
often first injected into the coal bed to break up the coal, making it
easier for the water and gas to flow to the surface.
UNAFFECTED HYDROLOGY
CBM EFFECTS ON HYDROLOGY
EFFECTS OF DISCHARGE TO SURFACE
WATER
WATER QUALITY
Max min max Min Max Min Max min max min
(mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L) (mg/L)
Na 861.0 112.0 800.0 110.00 2673. 1976. 5939. 3674. 3100. 570.0
Ca 128.00 2.70 69.00 5.90 1839.00 13.20 118.70 6.50 100.00 2.50
Mg 23.50 0.20 46.00 1.60 7.77 0.00 39.00 2.88 34.00 1.10
Meq Na 37.45 4.87 34.80 4.78 116.27 85.95 258.34 159.82 134.85 24.79
Meq Ca 6.39 0.13 3.44 0.29 91.77 0.66 5.92 0.32 4.99 0.12
Meq Mg 1.93 0.02 3.79 0.13 0.64 0.00 3.21 0.24 2.80 0.09
SAR 18.36 17.72 18.30 10.37 17.11 149.77 120.90 301.66 68.33 75.57
HYDROLOGY EFFECTS WITH
REINJECTION
Transport of gas in coal is a three stage process:
136
ADSORPTION ISOTHERM
Need of Dewatering
138
139
CHALLENGES TO CBM DEVELOPMENT
•Technical Challenges
• Other Problems-
Most mines are not accessible to gas pipeline network - lack of
natural gas transportation infrastructure in the coal producing regions
Limited drainage technologies/low drainage rates
Lack of Technology development due to cost and lack of
investment capital
Technical Difficulties:
Peculiar mechanical properties of coal
Dewatering & produced water treatment cost
Large number of parameter dependency
CHARACTERISTICS OF CBM RESERVOIR
• Coal is a source rock and a Reservoir Rock
• Gas Storage Mechanism of coal : adsorbed on surface- not free gas like
conventional gas reservoir
• Fracture system of coal reservoir : contains small naturally occurring fracture (several
in an inch) face cleat & butt cleat. Orientation, size, spacing of which controls gas flow
once desorbed & diffused to pore space
• Flow mechanism :
• Unique mechanical properties of coal compared to conventional reservoir rock
• Gas content = f(coal rank, reflectance, isotherm, reservoir pressure, CO2content etc.
• Dual Porosity
• Production behavior- similar to gas reservoir but rock is very much different
from sandstone or carbonate rock
• Variation of coal properties with production
• Gas composition variations during production
• dewatering
OTHER UNIQUE QUALITIES OF COAL
(GOB ) areas
Methane is a very powerful green house gas, (GHG) Twenty one times more
potent than CO2 .
Its adverse impacts are felt more intensely due to its shorter residence and
higher potency in the atmosphere than carbon dioxide.
Methane is remarkable clean fuel when burnt and its combustion produces no
SO2 or particulates and only about half of the CO2 associated with coal
combustion.
Emission of Methane is related to various human activities -Rice cultivation,
livestock management landfills and coal mining.
Global methane concentration is increasing by about 1% per annum.
CONCLUSIONS