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Teknologi Pencelupan 2 Pencelupan Serat-Serat Sintetik: Ida Nuramdhani, S.Si.T., M.SC., PH.D
Teknologi Pencelupan 2 Pencelupan Serat-Serat Sintetik: Ida Nuramdhani, S.Si.T., M.SC., PH.D
7SEMESTER
& 14 SEPTEMBER 2018
GANJIL BANDUNG
2019-2020
Fibre – Dyes Interactions 1: Chemical bonds
1. Covalent bond
1. Inonic bond
Dipole-dipole force
Such a situation exists in the dyeing of nylon with simple acid dyes by an ion exchange
mechanism.
The counter ion associated with an alkylammonium ion group in the nylon, under
weakly acidic conditions, is exchanged for a dye anion
The rate of desorption depends only on the fraction of occupied sites (Cf/Cmax).
The rate of adsorption of dye onto the fibre from solution, however, depends upon the
fraction of unoccupied sites (1 – Cf/Cmax) and the concentration of dye in the solution
(Cs).
K1&K2: rate constant of adsorption-desorption; Cmax isthe maximum number of adsorption sites that dye molecules can
occupy in the
fibre. K is the value of k1/k–1.
IDA NURAMDHANI - DEPARTMENT OF TEXTILE CHEMISTRY, POLITEKNIK STTT
Freundlich Isotherm
Monomolecular
Dyeing
dispersion/solid
synthetic fiber
solution system
Konsentrasi >>>, ketuaan warna >>>, tapi lebih suram, dan sedikit pergeseran hue (corak warna)
Ketuaan >>>, ketahanan luntur cuci dan gosok biasanya <<<, ketahan sinar >>>
Strike: the initial slope of exhaustion versus time (kecepatan awal pencelupan).
Dyebath exhaustion as a function of time for (a) rapidly and (b) slowly dyeing at two
temperatures, where Ti>T2