Anionic Palladium(0)

and Palladium(II)
Intermediates
in Palladium-Catalyzed
Heck and Cross-
Coupling Reactions

• APRIANCE MARISTA
BRIA
• LISTIANI CLARA ROWA
 INTRODUCTION
Anionic Palladium, which
is anionic Pd (0) and
anionic Pd (II) have a
critical role in
Palladium-catalyzed
heck and cross-coupling
reaction
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Palladium-catalyzed coupling
reactions comprise a family of
cross-coupling reactions that
employ palladium complexes
as catalysts. Anions of
palladium used in cross
coupling and Heck reactions,
play a crucial role in these
reactions. The anion ligated to
the palladium affects the
kinetics of the oxidative
additions to Arl as well as the
structure an reactivity of the
arylpalladium complexes
produced in this reaction.
METODOLOGY
1.1 An oxidative addition of the aryl halide to the ussually supposed
to afford a arylpalladium(II) complex after that nucleophilic attack on
trans-Arylpalladium, either added a syn or a trasmetalation. Using
reaction of Palladium mixtures rapidly lead to knowing about
Tricoordinated anionic palladium having a role in oxidative additions.

1.2 Generated in situ from Palladium mixtures for knowing about

anionic pentacoordinated Arylpalladium(II) complexes

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 RESULT AND DISSCUSION
2.1 The oxidative addition kinetics depens on the anion
(released by paladium (II) or by aryl halides during the
reactions but also on cations (delivered by nucleophiles or
reducers) dan protons. Anions ligatedto the palladium (0)
also affect both the structure of arylpalladium(II)
complexes formed by oxidative addition and their
reactivity with nucleophiles.

2.2 Postulated trans arylpalladium complexes are not

produce as main itermdiates, but instead previously
unsuspected complexes are fromed pentacoordinated
anionic complexes arylpalldium.

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EQUATION :

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 CONCLUSION
• The anionic Palladium with halides and acetace is
brought by the precursors of Palladium(0) are used in
catalytic heck and cross-coupling reaction.
• The anionic Palladium is not limited to oxidative
structure and reactivity of the arylpalladium (II)
• Pentacoordinated anionic complexes arylpalladium(II)
and conditions their stability and reactivity.
.

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THANK
YOU

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