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UNIT 4 Energy From Biomass
UNIT 4 Energy From Biomass
Biomass
ENERGY FROM BIOMASS
Table of Contents
Introduction
Sources of Biomass
Various types of Bio Fuels
Conversion Technologies
Wet Processes
Dry Processes
Biogas Generation & types
Aerobic & Anaerobic Digestion
Factors Affecting Generation of Biogas
Classification of Biogas Plants
Different Indian Digesters
Digester Design Considerations
Gasification Process- Gasifiers- Applications
BIOMASS
Photosynthesis is a
chemical process
that converts
carbon dioxide into
organic
compounds,
especially sugars,
using the energy
from sunlight.
Sources of Biomass
• Biomass is biological organic matter derived from living or
recently-living organisms
• Bioenergy is the energy contained (stored) in biomass
• Biomass is an extremely important energy source, available
nearly everywhere
• Biomass encompasses a large variety of materials, including
wood from various sources, agricultural and industrial residues,
and animal and human waste
• Two forms of biomass :
Raw: forestry products, grasses, crops, animal manure, and
aquatic products (seaweed).
Secondary: materials that undergone significant changes from
raw biomass. Paper, cardboard, cotton, natural rubber products,
and used cooking oils.
Various Types of Bio Fuels
BIO-FUELS
The energy stored in dry biomass like wood & straw is most
easily released by direct combustion or it can be converted into
liquid & gaseous fuels by a variety of techniques.
Solids
Wood Straw
Municipal refuses
Liquids ( Alcohols& vegetable oils Methanol &
ethanol)
Gases etc
Conversion Technologies
Biomass Conversion
Biomass Conversion
Gasification Liquefaction
Anaerobic
Digestion fermentation
Conversion Technologies Contd…
Thermo-chemical Conversion
1.Gasification- takes place by heating the biomass with limited oxygen to
produce low heating value gas or by reacting it with steam & oxygen at high
pressure & temperature to produce medium heating value gas.
3. Pyrolysis-
A wide range of energy-rich fuels can be produced by roasting dry woody
matter like straw and woodchips. The process has been used for centuries
to produce charcoal. The material is pulverized or shredded then fed into a
reactor vessel and heated in the absence of air.
The most obvious way of extracting energy from biomass, the technology of direct
combustion is well understood, straightforward and commercially available. Combustion
systems come in a wide range of shapes and sizes burning virtually any kind of fuel, from
chicken manure and straw bales to tree trunks, municipal refuse and scrap tyres. Some
of the ways in which heat from burning wastes is currently used include space and water
heating, industrial processing and electricity generation. One problem with this method is
its very low efficiency. With an open fire most of the heat is wasted and is not used to
cook or whatever. One method of improving this in developing countries is to build stoves
out of mud and scrap iron.
Pyrolysis
A wide range of energy-rich fuels can be produced by roasting dry woody matter like
straw and woodchips. The process has been used for centuries to produce charcoal.
The material is pulverized or shredded then fed into a reactor vessel and heated in the
absence of air. Pyrolysis can also be carried out in the presence of a small quantity of
oxygen ('gasification'), water ('steam gasification') or hydrogen ('hydrogenation'). One of
the most useful products is methane, which is a suitable fuel for electricity generation
using high-efficiency gas turbines.
Biogas
A mixture containing 55-65% methane, 30-40% CO2
& rest being impurities (H2, H2S & N2)
MESOPHILIC
THERMOPHILIC
10
10 20 30 40 50 60 70 TEMPERATURE
By regulating the daily feed volume , the
retention time can be controlled.
Periods for different materials to get well
fermentation are:
1. Cow & buffalo dung. 50 days
2. Pig-dung 20 “
3. Poultry dropping 20 “
4. Night soil 30 “
This period also depends on the ambient
temperature.
Toilet, Kitchen and Garden Waste
+ Manure
1. Concept
What are Small-Scale Anaerobic Digesters? “The Ecocycle of biogas”
Lightning
Toilet Products
(Excreta, Biogas
Faeces)
Heating
Kitchen / Garden
Organic Waste
(Green Waste)
Electricity
Fuel
Fertiliser
27
What is Anaerobic Digestion ? (1/3)
Degradation of organic material by bacteria. In the absence of air (anaerobic). Four
stages:
•Hydrolisis
• Cleavage of a chemical compound through the reaction with water.
• Insoluble complex molecules are bracken down to short sugars, fatty acids and
amino acids.
•Fermentation (Acidogenesis)
• Products from hydrolysis are transformed into organic acids, alcohols, carbon
dioxide (CO2), hydrogen (H) and ammonia (NH3).
•Acetogenesis
• Organic acids and alcohols are converted into hydrogen (H2), carbon dioxide
(CO2) and acetic acid (CH3COOH). Therefore, oxygen is consumed and anaerobic
conditions are created
•Methanogenesis
• Methanogenic bacteria (methanogenesis), transform the acetic acid, carbon
dioxide and hydrogen into biogas.
28
What is Anaerobic Digestion ? Contd...
Factors Affecting Generation of Biogas
GAS STORAGE
SCUM LAYER
SLUDGE ACTIVITY
INLET DIGESTING SLURY
GAS STORAGE
GAS STORAGE
SLUDGE SLUDGE SCUM LAYER
SUPERNATANT OUTLET
INPUT OUTLET
MIXER SUPERNETANT LAYER
SLUDGE
INLET DIGESTED
SLUDGE
SLUDGE HEATER SLUDGE
OUTLET
FIRST STAGE COMPLETELY MIXED
SECOND STAGE STRATIFIED
ii) Double stage process
The acidogenic stages & methanogenic stage are physically
separated in to two chambers. The first stage of acid production is
carried out in a separate chamber and only the diluted acids are fed in to
the second chamber where bio-methanation takes place & the biogas
can be collected from the second chamber.
Batch Type Biogas Plant
The batch plant:
The feeding is between intervals, & the plants emptied once the
process of digestion is complete. A battery of digesters are charged along
with lime, urea etc. & allowed to produce gas for 40-50 days. These are
charged and emptied one by one in a synchronous manner which maintain
a regular supply of the gas through a common gas holder. The bio gas
supply may be utilised after 8-10 days. Their installation & operation being
capital & labour intensive.
The main features of Batch type plant are:
1.The Floating gas holder plant (Also known as KVIC plant), and
The fixed dome is best suited for batch process especially when
daily feeding is adopted in small quantities.
The fixed dome type plant is generally built below the ground level
and is suitable for cooler regions.
Digester Design Considerations
Design Principle’s
Basics: Process Parameters
Nitrogen N2 0–10
Hydrogen H2 0–1
Oxygen O2 0–0
Floating Drum plants
Floating Drum plants
Floating-drum plants consist of a digester and a
moving gas-holder.
Gas pressure increases with the volume of gas stored; therefore the
volume of the digester should not exceed 20 m3. If there is little gas
in the holder, the gas pressure is low.
Advantages: Disadvantages
* Cost of plant is less compare * Needs skilled labour to
to floating drum type plant. operate.
* Loss of heat is negligible * Gas production per m3 of
since these are constructed
digester volume is less.
underground. *
No corrosion problems as in * Gas is produced at variable
fixed dome type. pressure.
* It is maintenance free.
Different Variations in the Drum Type
There are mainly two variation in floating type plant. One with
water seal and other without water seal.
WATER SEAL
OUTLET
INLET
100mm Φ
PIPE
1400 mm
450 mm
300mm
Biogas lamps
Biogas
cooking
stoves
Endothermic Irreversible
Pyrolysis does not involve reactions
with oxygen,water, or any other
reagents.
How?
Pyrolysis is :
Pyrolysis is :
Pyrolysis is :
Pyrolysis is :
Char
Bio Oil
SynGas
Operating temperatures above 430 °C.
For agricultural waste, for example, typical
temperatures are 450 to 550 °C.
Cheap and Requires drying of soil
economical system
Environment- Ineffective in
destroying or physically
friendly, separating inorganics
Energy-efficient from the contaminated
medium.
Requiring proper
treatment, storage,
and disposal for
hazardous wastes.
TYPES OF PYROLYSIS
• Dry pyrolysis
Low TemperatureAnalysis
Medium TemperatureAnalysis
High TemperatureAnalysis
• Oxidizing pyrolysis
Dry Pyrolysis
Heating of biomass
in presence of
limited oxygen and
air (deficient O2/air)
is called
gasification. it
produces gaseous
fuels like
H2,CO,CH4,N2
of low Heating
value.
Gasification
• Conversion of solid
biomass into combustible
gas mixture called
Producer gas (CO + H2 +
CH4) in presence of
limited (O2/air)
.
*Ignition temperature is between 650 and 750C
*Heating value is 18.7 to 26 MJ/m3
* Explosion limit: 5 to 14 % in air.
*Air to Methane ratio for complete combustion is 10 to 1 by volume.
*One cubic meter of biogas is equivalent to 1.613 liter of kerosene or
2.309 kg of LPG or 0.213 kW of electricity.
Applications
Heating
•No pre-treatment required Power generation
•Easiest way to use biogas •Both electricity and heat
can be produced in the
composition of 35% and
65% respectively
Vehicle fuel
•Requires considerable processing
•Water, impurities and particles must be
removed
•Great environmental factors
Industries
•Used for heating premises,
district heating power
Gas network production, heating ovens
•Natural gas being used for gas etc.
cookers, heaters, baking ovens,
water heaters etc.
Fermentation-
Bioethanol production process
Fermentation-
Bioethanol production flow diagram