Professional Documents
Culture Documents
Hydroc 2
Hydroc 2
• Common examples of
organic halides.
– Alkenes can also add to each other in an addition
reaction to form long chains of carbon compounds.
• this is called polymerization
– The atom or group of atoms that are added to the
hydrocarbon are called functional groups.
• Functional groups usually have multiple bonds or lone
pairs of electrons that make them very reactive.
• Alcohols
– An alcohol has a hydrogen replaced by a hydroxyl (-OH)
group.
– The name of the hydrocarbon that was substituted
determines the name of the alcohol.
– The alcohol is named using the
hydrocarbon name and adding
the suffix –ol.
• If methane is substituted with
an OH group it becomes
methanol
• If a pentane group is
substituted with an OH group
it is pentanol.
• For alcohols with more than
two carbon atoms we need
the number the chain so as to
keep the alcohol group as low
as possible.
• Primary alcohols are those with the OH
at the end of the Carbon chain.
1-propanol --------------------------------------
EX: 2 – methyl – 2-
propanol
• Gasoline is a mixture of
hydrocarbons (C8H18 for example)
that contain no atoms of oxygen.
Gasohol contains ethyl alcohol,
C2H5OH, which does contain
oxygen.
H H H OH
C=C + H2O H–C–C–H
H H H H
ethene water ethanol
• The addition of HYDROGEN to an
alkene is called a
HYDROGENATION REACTION.
H H H H
C=C + H2 H – C – C – H
H H H H
ethene hydrogen ethane
End….
Ethers,
Aldehydes,
and
Ketones
Ethers
An ether has a general
formula R-O-R’. Use
“ether” ending.
EX: Diethyl ether C4H10O
CH3CH2-O-CH2CH3
• The best-known ether is the
anesthetic called diethyl ether.
• IUPAC Names:
The carbon(s) attached to the oxygen atom
are named as branches by adding the –oxy
suffix to the stem name.
• Ex. CH3-CH2-CH2-CH2-O-CH2-CH3
• Methanal is a starting
material in the manufacture
of some plastics.
–A ketone has a carbonyl group
attached to an internal carbon
atom. Use “one” ending.
• EX: Propanone C3H6O
CH3
C=O
CH3
• The carbonyl group (A)
is present in both
aldehydes and ketones,
as shown in (B). (C) The
simplest example of
each, with the IUPAC
name above and the
common name below
each formula.
Uses of Ketones
• The simplest ketone is propanone
(common name = acetone).