Pco Wastewater Sampling and Analysis

EMB-National Capital Region (EMB-NCR) Pollution Control Officers (PCOs)
Training
February 12, 2009
WATER/WASTEWATER
SAMPLING AND ANALYSES
Engr. Mavic S. Quides

DENR-EMB-NCR
2009
03/13/20 1
SAMPLING DEFINITION &
OBJECTIVE, PURPOSE/S
What is SAMPLING? ...
collection of truly representative samples which
when analyzed yield results reflecting actual quality
of the water samples
Objective:
To collect a portion of material small enough in volume to be
transported conveniently and handled in the laboratory while still
accurately representing the material being sampled
Purpose/s:
 Compliance with regulatory requirements
 Evaluation of performance efficiency of WTP system
 Evaluation of effectiveness of in-house waste
minimization measure/s
03/13/20 2
SAMPLING STATIONS
 Influent
– Collected at points at highly turbulent flow and
upstream/above of plant return lines
 Effluent
– Collected at the most representative point downstream
of all treated or untreated combined wastewater
streams before entering the receiving waters
 Mixing Zone
– The average length of the mixing zone from the
point source is approx. five (5) times of the effective
width of the receiving water
 Others
– Outfalls suspected discharging pollutive WW
– Effluent Streams from each treatment units.
03/13/20 3
TYPES OF SAMPLES
 Grab or Catch
– A sample collected at a particular time and
place can represent only the composition of the
source at that time and place
 Composite
– Combination of grab samples collected at the
same sampling point at different times
03/13/20 4
SAMPLE HANDLING
COMPONENTS
 Container Requirements
Plastic or Glass(one may be preferred over the other depending on
the type of parameters)
 Preservation Methods
Refrigeration (Cool @ 4oC)
Chemical Addition
- Acidification (pH adjust <2)
- Biocides (HgCl soln)
- Special Cases (NaOH for CN- analysis)
 Maximum Holding Time
03/13/20 5
SUMMARY OF SPECIAL SAMPLING
OR HANDLING REQUIREMENTS
Minimum Maximum
DETERMINATION Container Sample Sample Preservation Storage
Size Type Recommended/
mL Regulatory
Acidity P,G (B) 100 g Refrigerate 24h/14d
Alkalinity P, G 200 g Refrigerate 25h/14d
BOD P, G 1000 g Refrigerate 6h/48h
Boron P 100 g, c None required 28d/6mos
Bromide P, G 100 g, c None required 28d/28d
Carbon, organic, G 100 g, c Analyze immediately; or refrigerate and 7d/28d
total add H3PO4 or H2SO4 to pH<2
Carbon dioxide P, G 100 g Analyze immediately stat/N.S.
COD P, G 100 g, c Analyze as soon as possible, or add 7d/28d
H2SO4 to pH<2; refrigerate
Chloride P, G 50 g, c None required 28d
Chlorine, residual P, G 500 g Analyze immediately 0.5h/stat
Chlorine dioxide P, G 500 g Analyze immediately 0.5h/N.S.
Chlorophyll P, G 500 g, c 30d in dark 30d/N.S.
Color P, G 500 g, c Refrigerate 48h/28h
Conductivity P, G 500 g, c Refrigerate 28d/28d
Cyanide:
Total P, G 500 g, c Add NaOH to pH>12, refrigerate 24h/14d;24h if
Sulfide present
Clesceri, Eaton & Greenberg "Standard Methods for the Examination of Water and Wastewater" 19th Ed. 1995 pges. 1-22 to 1-23
03/13/20 6
Minimum Maximum
mL Regulatory
Cyanide amenable to P, G 500 g, c Add 100 mg Na2S2O3/L stat/14d;24h if
chlorination sulfide present
Fluoride P 300 g, c None required 28d/28d
Hardness P, G 100 g, c Add HNO3 to pH<2 6mos/6mos
Iodine P, G 500 g, c Analyze immediately 0.5h/N.S.
Metals, general P(A), G(A) 500 g For dissolved metals filter immediately 28d/28d
add HNO3 to pH<2
Chromium VI P(A), G(A) 300 g Refrigerate 24h/24h
Cu by colorimetry*
0
Mercury P(A), G(A) 500 g, c Add HNO3 to pH<2, 4 C 28d/28d
Nitrogen:
Ammonia P, G 500 g, c Analyze as soon as possible, or add 7d/28d
H2SO4 to pH<2; refrigerate
Nitrate P, G 100 g, c Analyze as soon as possible, or 48h/48h (28d for
refrigerate chlorinated sples)
Nitrate+Nitrite P, G 200 g, c Add H2SO4 to pH<2, refrigerate none/28d
Nitrite P, G 100 g, c Analyze ASAP or refrigerate none/48h
Organic, Kjeldahl* P, G 500 g, c Refrigerate; add H2SO4 to pH<2 7d/28d
Odor G 500 g Analyze ASAP, refrigerate 6h/N.S.
03/13/20 7
Minimum Maximum
mL Regulatory
Oil and Grease G,wide-mouth 1000 g, c Add HCl to pH<2, refrigerate 28d/28d
calibrated
Organic Compounds:
MBAS P,G 250 g, c Refrigerate 48h
Pesticides G(S),TFE-lined 1000 g, c Refrigerate;add 1000mg ascorbic 7d/7d until extraction;
cap acid/L if residual chlorine present 40d after extraction
Phenols P, G 500 g, c Refrigerate, add H2SO4 to pH<2 */28d
Purgeables* by G, TFE-lined 2x40 g Refrigerate; add H2SO4 to pH<2; add 7 d/14 d
purge and trap cap 1000mg ascorbic acid/L if residual
chlorine present
Oxygen, Dissolved: G, BOD bottle 300 g
Electrode Analyze immediately 0.5h/stat
Winkler Titration be delayed after acidification 8h/8h
Ozone G 1000 g Analyze immediately 0.5 h/N.S.
pH P, G 50 g Analyze immediately 2h/stat
Phosphate G(A) 100 g For dissolved phosphate filter 48h/N.S.
immediately; refrigerate
Salinity G, wax seal 240 g Analyze immediately or use wax seal 6mos/N.S.
Silica P, G 200 g, c Refrigerate, do not freeze 28d/28d
03/13/20 8
Minimum Maximum
mL Regulatory
Silica P, G 200 g, c Refrigerate, do not freeze 28d/28d
Sludge digester gas G, gas bottle g N.S.
Solids P, G 200 g, c Refrigerate 7d/2-7d; see cited
reference
Sulfate P, G 100 g, c Refrigerate 28d/28d
Sulfide P, G 100 g, c Refrigerate; add 2 drops 2N Zn 28d/7d
Acetate/100mL; add NaOH to pH>9
Taste G 500 g Analyze ASAP; refrigerate 24h/N.S.
Temperature P, G g Analyze immediately stat/stat
Turbidity P, G 100 Analyze same day; store in dark 24h/48h
03/13/20 9
SIGNIFICANT PARAMETERS FOR
SELECTED TYPES OF INDUSTRIES
TYPE OF INDUSTRY SIGNIFICANT PARAMETERS
A. BEVERAGE INDUSTRY BOD5, pH, Total Suspended Solids (TSS),
Settleable Solids, Oil and Grease (O/G)
B. CEMENT CONCRETE pH, TSS, Total Dissolved Solids (TDS), Temp.
C. DAIRY PRODUCT PROCESSING BOD5,COD, pH, TSS, TDS, Settleable Solids
D. DISTILLERY BOD,COD, pH, TSS, Settleable Solids, Temp.
E. FERROALLOY MFG. TSS, Chromium (VI), O/G

(electric furnace w/ wet APC)
F. FERTILIZER INDUSTRY Chloride, Chromium, TDS, Nitrate, TSS
Nitrogen Fertilizer Industry pH, Phosphorous, Suspended Solids
Phosphate Fertilizer Temperature, Cadmium, Arsenic
G. FLOUR & STARCH INDUSTRY BOD5 pH, Suspended Solids, Temperature
WATER QUALITY MONITORING MANUAL, Environmental Management Bureau, DENR, 1994.
03/13/20 10
H. INORGANIC CHEMICALS, pH, TSS, TDS, Chlorides, Sulfates, COD, Temp
ALKALIES AND CHLORINE
INDUSTRY
I. LEATHER TANNING & FINISHING BOD5, COD, Chromium, Oil and Grease, pH,
INDUSTRY TSS, Color, TDS
J. LIVESTOCK INDUSTRY BOD5, COD, TSS, pH, Color, Total Coliforms
K. MEAT, FISH AND FRUIT CANNING BOD5, COD, TSS, pH, O/G, TDS
L. MEAT PRODUCTS & INDUSTRY BOD5, COD, TSS, Settleable Solids, O/G, Total
Coliforms, Toxic Materials
M. METAL FINISHING INDUSTRY O/G, Heavy Metals (Cr, Cd, etc.), TSS, Cyanide
N. MINERAL ORE PROCESSING TSS, Heavy metals (Hg, CN, Cd, etc.), Arsenic
O. ORGANIC CHEM’LS INDUSTRY BOD5, COD, pH, TSS, O/G, Phenols

03/13/20 11

P. PETROLEUM REFINING BOD, Heavy Metals, COD, Oil (Total) , pH,
INDUSTRY Phenols, TSS, Temperature, TDS
Q. PLASTIC MATERIALS & BOD5, COD, pH, Total Suspended Solids, Oil and
SYNTHETIC INDUSTRY Grease, Phenols
R. PULP AND PAPER INDUSTRY BOD5, COD, pH, Total Susp. Solids
S. STEEL INDUSTRY O/G, pH, Cyanide, Phenol, TSS, Temp.,

Chromium
T. SUGAR CANE PROCESSING BOD5, pH, TSS, Oil and Grease
U. TEXTILE FINISHING AND BOD5, COD, pH, TSS, O/G, Phenols, Chromium,
LAUNDRY Surfactants, Color
V. THERMAL POWER GENERATION BOD5, pH, Chromium, TSS, O/G, Phosphate,
Temperature, Color
03/13/20 12
SAMPLING TECHNIQUES
 Use sampling devices whose materials will not affect the
composition of water samples
 Field instrument should be checked and calibrated before
using
 The sampling container shall be kept unopened until the
time at which it is required for filling
 Hold the bottle near the base with one hand and remove
the stopper, immerse into the water mouth downward tilt
towards the current to fill return the cap immediately
 If the above procedures is not enough , a bucket or jug
type sampler maybe employed lower down the bucket with
the use of rope to collect samples
 Pour the collected samples into the sampling container
03/13/20 13
SAMPLE CONTAMINATION
PREVENTION TIPS
 Field measurements (e.g., pH) should always be made on a
separate sub-sample
 New sampling containers is a MUST!! Clean according to
recommended methods
 Bottles for REAGENTS USE should never be used as sample
containers.
 Preserve all samples for a particular group of parameters
together.
 Inner portion of sample containers and caps are not to be
touched with bare hands, gloves, etc.
 Spilled Petroleum products (gasoline, oil, exhaust fumes) or
drippings must be removed immediately.
 Exhaust fumes and cigarette smoke contaminate samples with
lead and other heavy metal.
 Air conditioning units are sources of trace metal contamination.
03/13/20 14
FIELD QUALITY CONTROL
 FIELD BLANKS
Effectiveness and purity of preservatives
Sampling containers, equipment contamination
 DUPLICATE SAMPLES
Check on sampling equipment and techniques.
 SPLIT SAMPLES
Discrepancies in analytical techniques and procedures of
the discharger.
 TRIP BLANKS
Effectiveness and purity of the preservatives
Contamination of containers, sampling equipment
03/13/20 15
CHAIN-OF-CUSTODY (COC)
 DEFINITION
The documentation of the possession and handling of samples
 PURPOSE
- Creates legal “paper trail”
- Reduces miscommunication.
- Provides accurate tracking for systems audits
 COC COMPONENTS
1.Field Log Book
- Clear & complete
- Legal Document
- First hand sampling info is recorded
- Documents any unusual circumstances
03/13/20 16
2. Sample Labels
- I.D. No. (unique to each sample)
- Location No. (may be the same or different from sample ID#)
- Sampling Date ( incl. Months, day and year)
- Sampling Time
- Type of analyses requested
- Others/Remarks
3. Sample Seals
Detect unauthorized tampering with samples up to the time of
analysis
4. Analyses Request Sheet

Accompanies samples to the laboratory
03/13/20 17
5. COC Record
Custody on analyses transfer(including signature and time)
- Shipment (Container, Packaging, Sample Tracking)
- Delivery of to the Laboratory
6. Continuation of COC
COC Procedures in the Laboratory (Receipt of Sample and
so on)
03/13/20 18
SIGNIFICANT WASTEWATER
CONTROL PARAMETERS
 Color  Oil and Grease

 Temperature  Heavy Metals
 pH  Coliforms
 BOD-COD-DO
 Total Suspended
Solids
 Settleable Solids
03/13/20
WW PARAMETERS AND ITS
SIGNIFICANCE
 COLOR
– Water naturally contaminated by soils, decayed leaves and branches
and other naturally occurring organic and inorganic compounds has a
yellow-brown color.
– This is approximated by a solution of potassium chloroplatinate tinted
with small amounts of Cobalt Chloride. A solution with the equivalent
of 1mg/L cobalt produces a color defined as one (1) std color unit (std
Pt.Co color unit or PCU). The color of water samples is determined
against this standard.
– Color in excess of 150 units in the receiving water may inhibit
photosynthesis and reduce dissolve oxygen supply to the extent that
propagation and growth of fishes and aquatic plants are affected.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
•TEMPERATURE
– Temperature affects the efficiency of the biological process. Most
biota are acclimated to the specific temperature ranges in their
immediate environment. While fishes and aquatic plants can
thrive within a naturally occurring variation of temperatures,
artificially induced temp changes effect their metabolism. The
dissolved oxygen concentration decreases with higher
temperatures.
– Growth and propagation are impaired when a change in temp of
about 30 is artificially induced by the discharge of water at an
elevated temperature.
03/13/20 21
WW PARAMETERS & ITS
SIGNIFICANCE
•pH
– Measure of acidity or alkalinity of water solution or sample.
– Mathematically, the pH is the negative logarithm of the molar
Hydrogen ion concentration. Ions are chemical units with
electrical charges. Hydrogen ions (H+) make a water soln
acidic, hydroxyl ions (OH-) make the solution alkaline.
– Very few organisms survive at pH below 3.0 and above 11.0.
The tolerance level of organisms is between 6.5 and 8.5.
03/13/20 22
WW PARAMETERS & ITS
SIGNIFICANCE
 BOD
– This test is a measurement of the amount of oxygen required, in a 5-day
period by the microorganisms in consuming the organic material in the
WW.
– BOD is simply stated, the amount of oxygen used by the microorganisms
as they biologically decompose organic matter in wastewater. The larger
amount of oxygen that will be needed by these organisms.
– It has a widest application in measuring waterloading to treatment plants
and in evaluating the efficiency (BOD removal) of treatment systems.
– A five-day BOD (Oxygen demand for 5 days) of 50mg/L of oxygen is
deemed low enough to be accommodated by the self oxygenation
capacity of the water.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
 COD
– Chemical Oxygen Demand is measure of the amount of oxygen needed
to decompose all the organic materials and some of the inorganic
compounds in the wastewater.
– The COD measures more than the BOD. BOD measures only the more
readily biodegradable organic matters, while COD uses a more
complete oxidation reaction.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
 DO
– Concentration of oxygen dissolved in the water. It is measured either
in concentration or “% saturation”.
– DO in water comes from air. It mixes into the water by waves or lakes
or fast moving rivers.
– Algae and rooted aquatic plants also add oxygen through
photosynthesis.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
 TOTAL SUSPENDED SOLIDS
– TSS are solids or substances suspended in water including clay, silt,
decaying plant, algae, plankton, sand microbes, animal matter,
industrial wastes and sewage that cause water turbidity.
– TSS decrease water clarity.
– TSS increases water temperatures because suspended particles absorb
more heat hence reduces the concentration of DO.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
•SETTLEABLE SOLIDS
– The term settleable solids applies to solids in suspension
that will settle under quiescent conditions. Only the
coarse suspended solids with specific gravity greater
than that of water will settle.
– Settleable solids are normally measured using the
IMHOFF cone or gravimetric method
03/13/20 27
WW PARAMETERS & ITS
SIGNIFICANCE
 OIL AND GREASE
– Oil and Grease form a thin layer on top of the water surface which
effectively interferes with the oxygen transfer mechanism between air
and water body. Grease and Oil also dries up and forms unsightly
deposits on beaches, ports and harbors. Grease and Oil of mineral
origin are relatively resistant to biodegradation and will require
removal by methods other than biological treatment. When taken by
shellfish and fish, grease and oil adversely affects their tastes.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
 HEAVY METALS
– LEAD is a substance commonly used in paint preparation, drinking

water pipes, various metallic implement such as gasoline additive.
– COPPER is toxic to algae, marine plants, invertebrates and fishes.

This is the reason why copper compounds are often used to control
algal growth in cooling towers. Copper has a lesser effect on mammals.
Aside from toxicity, copper imparts an undesirable taste to water.
While a concentration of 0.2mg/L can already be toxic to some fishes,
the recommendation limit is 1.0 mg/L for effluent discharges because
of expected dilution effects.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
 HEAVY METALS
– HEXAVALENT CHROMIUM is highly toxic although the trivalent

from is less toxic. It is commonly used for chrome plating and highly
toxic to all life forms.
– MERCURY is perhaps the most widely known poison among the

heavy metals due to the Minamata diseases discovered in Japan.
Organo-metallic or methyl mercury has the highest toxicity while free
mercury used in thermometer has the lowest toxic level of the various
forms of mercury.
03/13/20
WW PARAMETERS & ITS
SIGNIFICANCE
 COLIFORMS
– Coliform organisms (or E. Coli) are the indicator organisms of
fecal contamination in any water body. The presence of coliform
organisms may signify fecal contamination from warm blooded
animals.
– Normal raw sewage contains up to 1,000,000 MPN/100 ml. MPN
is the most probable number as E. Coli are counted using
statistical methods due to its population of animals (Cattle, pigs,
etc.), the E. Coli concentration reaches close to that of a weak
sewage.
– Coliforms are removed from the effluent by chlorination.
However, chlorine gas reacts readily with most organic
substance to form chlorinated hydrocarbon which may have
higher environmental and health related problems.
03/13/20
BASIC ANALYSES
• GRAVIMETRIC
• TITRIMETRIC
• SPECTROPHOTOMETRIC
• POTENTIOMETRIC
03/13/20 32
BASIC ANALYSES
 GRAVIMETRIC
– Calculations are based on mass measurements
Example:
Percent of solid
results are
determined by
dividing the mass
of the residue by
the total mass of
sample aliquot,
times 100.
03/13/20
BASIC ANALYSES
• TITRIMETRIC
– A solution (TITRANT) is
added to the sample where
the constituents in the
sample react with it. The
volume of the titrant added is
used to calculate the amount
of analyte present in the
sample.
– The volume of titrant used to
reach the reaction
ENDPOINT is directly
proportional to the amount
of constituent present in the
sample
03/13/20
BASIC ANALYSES
•SPECTROPHOTOMETRIC
-An analysis measuring the relative
intensities of monochromatic light
as a result of atomic absorption
-COLORIMETRY measures the color
intensity in the visual
spectrum
-STANDARDS of known conc’n are
plotted against their relative
intensities of atomic absorption
(calibration curve)
-Sample concentration is either
taken from the calibration curve or
read directly from the instrument in
concentration units
03/13/20 35
BASIC ANALYSES
•POTENTIOMETRIC
-A direct measurement of
electron potential which the
concentration of an active
ion may be derived
-Ion-specific electrodes are
available for a variety of
analytes
-Calibration points include
zero and ambient air
conditions
03/13/20 36
APPROVED METHODS OF
ANALYSIS
PARAMETER METHOD OF ANALYSIS
1. ARSENIC Silver Diethyldithiocarbamate (Colorimetric)
2. BOD Azide Modification (Dilution Technique)
3. BORON Carmine Method (Colorimetric)

4. CADMIUM Atomic Absorption Spectrophotometry (AAS)
Wet Ashing w/ conc HNO3+HCl
5. CHLORINATED Gas Chromatography (ECD)
HYDROCARBONS
6. CHROMIUM Diphenyl Carbazide (Colorimetric)

HEXAVALENT
7. COLOR Visual Comparison Platinum Cobalt Scale
8. CYANIDE Specific Ion Electrode

DENR ADMINISTRATIVE ORDER NO. 35, Series of 1990. REVISED EFFLUENT REGULATIONS OF 1990.
03/13/20 37
APPROVED METHODS OF
ANALYSIS
9. DISSOLVED OXYGEN Azide Modification (Dilution Technique),
Membrane Electrode (DO Meter)
10. FECAL COLIFORMS Multiple-Tube Fermentation Technique,
Membrane Filter
11. LEAD AAS Wet Ashing w/ conc HNO3+HCl
12. NITRATE AS NITROGEN Bruccine for Saline Waters, Specific Ion

Electrode for Fresh Waters
13. OIL AND GREASE Gravimetric (Petroleum Ether Extraction)
14. ORGANO PHOSPHORUS Gas Chromatography (ECD)

COMPOUNDS
15. PCB Gas Chromatography (ECD)
16. PH Glass Electrode
03/13/20 38
APPROVED METHODS OF
ANALYSIS
17. PHENOLIC SUBSTANCES Chloroform Extraction (Colorimetric)
18. PHOSPHATE AS Stannous Chloride (Colorimetric)

PHOSPORUS
19. SETTLEABLE SOLIDS Imhoff Cone
20. SURFACTANTS (MBAS) Methylene Blue (Colorimetric)
21. TEMPERATURE Use of Mercury-Filled Thermometer
22. TOTAL COLIFORMS Multiple-Tube Fermentation Technique,

Membrane Filter
23. TOTAL MERCURY AAS Cold Vapour Technique, Mercury
Analyzer
24. TOTAL SUSPENDED Gravimetric Method
SOLIDS
03/13/20 39
EFFLUENT STANDARDS
EFFLUENT STANDARDS: TOXIC AND OTHER DELETERIOUS
SUBSTANCE (Max. Allowable Limits for Inland Waters “Class C),
DAO-35 Effluent Regulations of 1990
PARAMETER UNIT STANDARDS
ARSENIC Mg/L 0.20
CADMIUM Mg/L 0.05
CHROMIUM HEXAVALENT Mg/L 0.10
CYANIDE Mg/L 0.20

LEAD Mg/L 0.30
MERCURY TOTAL Mg/L 0.005
PCB Mg/L 0.003
FORMALDEHYDE Mg/L 1.00
03/13/20 40
EFFLUENT STANDARDS
EFFLUENT STANDARDS: CONVENTIONAL & OTHER POLLUTANTS IN INLAND WATERS
(Category I & II and in Inland Waters “Class C), DAO-35 Effluent Regulations of 1990
PARAMETER UNIT STANDARDS

COLOR PCU 150
pH (RANGE) 6.5-9.0
COD Mg/L 100
SETTLEABLE SOLIDS (1-HR) Mg/L 0.50
BOD5 at 20oC Mg/L 50
TOTAL SUSPENDED SOLIDS Mg/L 70
SURFACTANTS (MBAS) Mg/L 5.0
OIL & GREASE Mg/L 5.0
PHENOLS Mg/L 0.1
TOTAL COLIFORMS MPN/100ML 10000
03/13/20 41
LABORATORY ACCREDITATION
DENR DAO 98-63
03/13/20 42
THE ENVIRONMENTAL LABORATORY
RECOGNITION PROCESS
Environmental Management Bureau

Department of Environment and Natural Resources
DAO 98-63
GUIDELINES FOR THE DESIGNATION OF DENR
RECOGNIZED ENVIRONMENTAL LABORATORIES
03/13/20 43
DENR-Recognized Environmental Laboratories
CERTIFICATE
NATIONAL ECOLOGY LABORATORY

East Avenue, Quezon City
-----------------------------------------------------------------
03/13/20 44
DENR-Recognized Environmental
Laboratories ( As of JULY 2008)
RESEARCH AND INTERTEK TESTING
ANALYTICAL SERVICES
SERVICES LABORATORY PHILIPPINES, INC. - LABTEST
2/F ITS Bldg., 2310 Pasong Tamo Ext. Makati City
(RASL)
UP-NSRI, University of the Philippines
Corner Quirino & Velasquez Avenues, Diliman,
Quezon City Scope of Recognition:
Scope of Recognition:
Water and Wastewater Analysis
BOD5, Chromium (Hexavalent), Cadmium
Chromium(Hexavalent), Cadmium(Total),
(Total),COD, Chloride, Coliform (Fecal),
Copper(Dissolved), Copper(Total), Lead, pH,
Coliform (Total), Copper(Dissolved),
Oil & Grease, Total Mercury,Total Dissolved
Copper (Total), DO, Lead, pH, Nitrate as
Solids, Total Suspended Solids
Nitrogen, Oil & Grease, Settleable Solids,
Temperature,Total Dissolved Solids,
Sediment/Biota Analysis
Total Suspended Solids
Total Cadmium, Total Copper, Total Lead,
TotalMercury
03/13/20 45
ADAMSON UNIV. CHEMPRO ANALYTICAL
TECHNOLOGY SERVICES LABORATOIES,
RESEARCH & DEVT CENTER INC.
(AUTRDC) 6th F AF Bldg.,182 Shaw Blvd., Ext., Pasig City
900 San Marcelino Street, Ermita Manila Tel. No. 6717329, 6717207
Tel. No. 5361650, 5229006
Scope of Recognition: Scope of Recognition:
Arsenic, BOD5, Boron, Cadmium (Total),
BOD5, Cadmium, Coliform (Fecal),
Chloride, Chromium (Hexavalent), COD
Coliform (Total), Color, Copper (Total)
Coliform(Fecal), Coliform(Total), Color,
Dissolved Oxygen, Lead, pH,
Copper (Dissolved), Copper (Total),
Total Dissolved Solids, Total Suspended
Cyanide (Free), Dissolved Oxygen, Lead, Solids
Nitrate-N, Oil & Grease, pH, Phenols,
Phosphate as Phosphorous, SettlEable Solids,
Surfactants (MBAS), Temperature, Total
Mercury, Total Dissolved Solids,
Total Suspended Solids
03/13/20 46
SGS PHILIPPINES, INC. MER CHEMICAL
2/F Alegria Bldg., 2229 Don Chino Roces Ave., Makati City LABORATORY
Tel. No. 8175656 AND SERVICES, INC.
Scope of Recognition: No. 7 Major Dizon Street, Industrial Valley
Complex, Marikina City,
Tel. Nos. 6818459-6818463
BOD5, Boron, Cadmium (Total), COD,Chloride, Cr+6
Coliform (Fecal), Coliform (Total), Color, Copper
(Dissolved), Copper (Total), Dissolved Oxygen, Lead, Scope of Recognition:
Oil & Grease, pH, SettlEable Solids,SurfactantsMBAS), Water and Wastewater Analysis
Temperature, Total Mercury, TDS, TSS BOD5, COD, Chloride, Coliform
Ambient Air Analysis (Fecal), Coliform (Total), Color,
Lead, Nitrogen Dioxide, Sulfur Dioxide, Total Dissolved Oxygen, Oil & Grease,
Suspended Particulates (TSP) pH, Total Dissolved Solids,
Stationary Source Emissions Analysis Total Suspended Solids
Particulate Matter (PM), Sulfur Dioxide
Sediments
Cadmium(Total), Lead, Mercury
03/13/20 47
EMD/EP&C LABORATORY FIRST ANALYTICAL SERVICES
ANALYTICAL SERVICES AND
PNPC Complex, Merritt Road, Fort Bonifacio, Taguig, TECH’L COOPERATIVE
Tel. No. 8936001, 8931320 (F.A.S.T)
Scope of Recognition: 6th F AF Bldg.,182 Shaw Blvd., Ext., Pasig City
Tel. No. 9130241
Arsenic, BOD5, Cadmium (Total), Chloride,
Chromium (Hexavalent), Color, Copper (Total),
Lead, Oil and Grease, pH, Temperature, Total Water and Wastewater Analysis
Mercury, Total Dissolved Solids, Total BOD5, COD, Chloride, Coliform (Fecal),
Suspended Solids Coliform (Total), Color, Dissolved Oxygen,
Oil & Grease,pH, Settleable Solids, Temperature,
Sediments and Biota
Total Dissolved Solids, Total Suspended Solids
Arsenic, Cadmium (Total), Cu, Fe, Pb,Mn, Zn,
Total Mercury
Air-Ambient
Total Suspended Particulates
03/13/20 48
MWC LABORATORY PHILIPPINE INSTITUTE OF PURE
SERVICES AND APPLIED CHEMISTRY
MWSS Compd., Katipunan Rd., Balara Quezon City (PIPAC)
Tel. No. 4368000 loc. 3720, 3721,3210 Ateneo De Manila Univ. Campus,Loyola Heights, Q.C.
Tel. No. 4266072, 4266001 loc. 4856,
Scope of Recognition: Scope of Recognition:
Water and Wastewater Analysis Water and Wastewater Analysis

BOD5, Chloride, COD, Coliform (Fecal), Arsenic, Cadmium (Total), Copper (Dissolved),
Copper (Total), Lead, pH, Temperature, Total
Coliform (Total), Dissolved Oxygen, pH,
Me4rcury, Total Dissolved Solids,
Settleable Solids, Temperature,Total
Dissolved Solids, Total Suspended Solids
Sediments and Biota
Cadmium (Total), Copper, Fe, Lead, Mn, Ni,
Zinc, Total Mercury
03/13/20 49
(SENTROTEK) SENTRO SA CENTRAL WASTEWATER
PAGSUSURI, LABORATORY
PAGSASANAY AT UNIVERSAL ROBINA
PANGANGASIWANG CORP. (URC)
PANG-AGHAM AT TEKNOLOHIYA E. Rodriguez Jr. Avenue, Bagong Ilog Pasig City
CORPORATION Tel. No. 6717099
208 Pilar St., Mandaluyong City,
Tel. No. 7247511
Scope of Recognition
Water & wastewater Analysis BOD5, Chloride, COD, Coliform
BOD5, Cd Total, COD, Chloride, Cr +6 (Fecal),Coliform (Total), Dissolved
Coliform (Total & Fecal), Color, Oxygen, pH,Color, Temperature,Total
Copper Total, DO, Pb,Nitrate as N, Dissolved Solids, Total Suspended Solids
Oil&Grease, pH, Phenols, Phosphates as P,
Settleable Solids, Surfactants,
Total Hg, TDS, TSS
03/13/20 50
ELARSI, TECHNICAL EXPERTS ON
INCORPORATED ENVIRONMENTAL
Unit 201 Rizalina Annex Building, 1677
MANAGEMENT, INC.
Quezon Avenue, Quezon City (TEEM Laboratory)
Tel. No. 9252849, 927-7715
TEEM Bldg., Lot 10 Blk 6 Orange Drive,
Goodwill II Sucat, Paranaque City
Tel. No. 826-8921, 8269871
Scope of Recognition
Water & wastewater Analysis
BOD5, Chloride, Ambient Air
Coliform (Total & Fecal), Color, Nitrogen Dioxide, Sulfur dioxide
DO, Oil&Grease, pH, Settleable Solids, Total Suspended Particulate Matter
Stationary Source Emission
TDS, TSS
Nitrogen Oxide, Particulate Matter,
Sulfur Dioxide
03/13/20 51
AERONICS INCORPORATED MACH (UNION) WATER
ENVIRONMENTAL LABORATORY
LABORATORY
DIVISION Unit 22-C3 URCI Commercial Bldg., Real St.,
Talon Dos, Las Pinas City
19 Ashley Street, North Fairview, Quezon City Tel. No. 873-6303, 871-2707
Tel. No. 9354339
Scope of Recognition Scope of Recognition:
Water & wastewater Analysis Water and Wastewater Analysis

BOD5, COD, Chloride, Cr +6 ,Coliform BOD5, COD, Coliform (Fecal),
(Total & Fecal), Color, DO, Phosphates Coliform (Total), pH, Color,
as P, Settleable Solids, Surfactants, Total Suspended Solids, Oil and Grease
Temperature, TDS, TSS, Oil and Grease,
pH
03/13/20 52
MARAMING SALAMAT PO!!!
03/13/20 53

Pco Wastewater Sampling and Analysis

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Pco Wastewater Sampling and Analysis

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EMB-National Capital Region (EMB-NCR) Pollution Control Officers (PCOs)

Engr. Mavic S. Quides

 Maximum Holding Time

C. DAIRY PRODUCT PROCESSING BOD5,COD, pH, TSS, TDS, Settleable Solids

D. DISTILLERY BOD,COD, pH, TSS, Settleable Solids, Temp.

E. FERROALLOY MFG. TSS, Chromium (VI), O/G

O. ORGANIC CHEM’LS INDUSTRY BOD5, COD, pH, TSS, O/G, Phenols

TYPE OF INDUSTRY SIGNIFICANT PARAMETERS

S. STEEL INDUSTRY O/G, pH, Cyanide, Phenol, TSS, Temp.,

4. Analyses Request Sheet

 Color  Oil and Grease

– LEAD is a substance commonly used in paint preparation, drinking

– COPPER is toxic to algae, marine plants, invertebrates and fishes.

– HEXAVALENT CHROMIUM is highly toxic although the trivalent

– MERCURY is perhaps the most widely known poison among the

2. BOD Azide Modification (Dilution Technique)

3. BORON Carmine Method (Colorimetric)

6. CHROMIUM Diphenyl Carbazide (Colorimetric)

8. CYANIDE Specific Ion Electrode

12. NITRATE AS NITROGEN Bruccine for Saline Waters, Specific Ion

14. ORGANO PHOSPHORUS Gas Chromatography (ECD)

18. PHOSPHATE AS Stannous Chloride (Colorimetric)

20. SURFACTANTS (MBAS) Methylene Blue (Colorimetric)

21. TEMPERATURE Use of Mercury-Filled Thermometer

22. TOTAL COLIFORMS Multiple-Tube Fermentation Technique,

CYANIDE Mg/L 0.20

PARAMETER UNIT STANDARDS

DENR DAO 98-63

Environmental Management Bureau

NATIONAL ECOLOGY LABORATORY

Scope of Recognition: Scope of Recognition:

Water and Wastewater Analysis Water and Wastewater Analysis

Scope of Recognition Scope of Recognition:

Water & wastewater Analysis Water and Wastewater Analysis

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