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6,7,9. Separation - Centrifg - Decnt - Masking
6,7,9. Separation - Centrifg - Decnt - Masking
Techniques
Hanandayu Widwiastuti, S.Si., M.Si.
Politeknik Kesehatan Kemenkes Malang
Why We Need Separation Techniques?
Illustration showing
separation by equilibrium-
density-gradient
centrifugation.
DECANTATION
It is simply to pour off of upper liquid layer
MASKING
MASKING
In complexation reactions, several ligands react with a metal
atom to form a coordination complex. This is achieved by
providing lone pairs od the ligand into empty orbitals of the
metal atom and formng dipolar bonds. The ligands are Lewis
bases, they can be both ions and neutral molecules.
In chemistry, a coordination complex, consists of an atom or
ion (usually metallic), and a surrounding array of bound
molecules or anions, that are in turn known as ligands or
complexing agents.
Coordination refers to the "coordinate covalent bonds" (dipolar
bonds) between the ligands and the central atom. Originally, a
complex implied a reversible association of molecules, atoms,
or ions through such weak chemical bonds.
Separations Based on Complex Formation
MASKING
MASKING
in Analytical Chemistry,
the technique of masking
is mainly used to improve
selectivity in a wide
variety of methods such
as complexometric
titrations,
spectrophomometry,
gravimetry, solvent
extraction, ion-exchange,
chromatography, etc.
MASKING
EXAMPLE