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Mine Gases and Dust
Mine Gases and Dust
Mine Gases and Dust
INTRODUCTION
Part of total air conditioning that deals with the quality
of air that is being supplied to mine workings.
When dealing with mine ventilation, it is one of more
important problems.
All the underground mine workings contain the
potential for release of air contaminants such as strata
gas, dust, blasting gases, and diesel exhaust.
Before the problem of maintaining the quality of the air
can be solved, it is important to be familiar with the
properties of the impurities that may be encountered.
Why is it important to know the
class of ore that we are mining
in mine ventilation?
CONTAMINANTS
Any undesirable substance not normally present in
air or present in an excessive amount.
Contaminants or impurities may be either
nonparticulate (gases or vapors) or particulate
(liquids and solids).
Liquid contaminants include mists and fogs, and
solid contaminants include dust, fumes, smoke and
organisms (bacteria, pollen etc)
Most common types underground: gases and dusts.
Cont.
Threshold Limit Value (TLV) as re- commended by
ACGIH: airborne conc. of substance & conditions to
which nearly all workers may be repeatedly
exposed to without adverse health effects.
Respirable Dust
Total Dust
Isolation
Isolation is another means to protect workers from exposure
to harmful dust.
In this technique, the worker is placed in an enclosed cab
and supplied with fresh, clean, filtered air.
MINE GASES
Air enters any mine or other subsurface structure,
it has a volume composition of approximately 78%
nitrogen, 21 % oxygen and 1 % other gases on a
moisture-free basis.
As air progresses into the network of ug openings,
the composition changes.
Some gases may build up in the mine, and can
cause danger to people working underground.
Why is it necessary that the subsurface
environmental engineer should be familiar with the
physical, chemical and physiological properties of
mine gases?
Do you think the TLVs apply to all people?
SOURCES OF GASES
Produced over geological time and remain trapped
within the pores or fracture networks of the rock.
Chemical reactions
The most common gases are:
OXYGEN
Oxygen is the commonest of all elements, nearly a
quarter of the atmosphere & about 90% of the mass
of water [H2O] consists of oxygen.
It diffuses thru the walls of the alveoli in the lungs
to form oxyhaemoglobin in the blood stream which
is unstable.
The quantity of oxygen required is a function of
physical activity.
Respiratory quotient,
Cont.
If the oxygen content of the air declines, for any of
several reasons, is termed oxygen depletion, and the
environment is said to be oxygen-deficient.
Air which has been stagnant for a long period may
have had much of its oxygen removed by the oxidation
of metals & minerals and the decaying of timber, and
some or all of it may have been replaced by CO2.
Such a mixture which is short of oxygen, is neither
poisonous nor explosive, is called black damp in coal
mining.
Cont.
Miner working at a moderate rate consumes 0.07
cfm of O2 and expel 0.063 cfm of CO2.
O2 depletion – can be deadly; caused by dilution
(by other gases) and oxidation (high- & low-
temperatures) process.
Physiological effects will vary depending on
individual.
NITROGEN
Nitrogen is the most common gas in the atmosphere
comprising nearly 80% of it.
Nitrogen compounds are essential to plant & animal life.
Nitrogen combines directly with some metals at high
temperatures to form nitrides, such as aluminium nitride
AlN, and iron nitride, Fe4N2.
It is a constituent of nitric acid HNO3, which forms
nitrates such as sodium nitrate NaNO3 & calcium
nitrate Ca(NO3)2, and also nitrous acid, HNO2, which
forms nitrites such as sodium nitrite NaNO2 and
calcium nitrite Ca(NO2)2.
EXPLOSIVE GASES: METHANE
(CH4)
Methane (CH4) has caused more loss of life in
mines than any other gas for example the Hwange
Mine disaster.
In most coal mines methane is always present or
expected, and consequently underground workers
are always on the lookout for it.
In metalliferous mines the gas usually appears only
at rare intervals & often in unsuspected places,
with the result that people are often caught
unawares.
METHANE GAS
Methane is sometimes called marsh gas, in collieries it is
called firedamp.
It is produced by the decay of vegetable matter under
water or by the distillation of coal.
Methane gas burns but does not support combustion.
The ignition temp of methane is about 650 deg C, hence it
needs a flame, or hot spark to ignite it.
There are very strict rules about what can be taken
underground and about care of working machines.
SG = 0.55 & will usually be found towards the back/roof of
the excavation.
Cont.
Methane is colourless, odorless, tasteless,
nontoxic, highly flammable, and lighter than air.
When the barometer falls, methane is forced out of
the strata, so underground safety may be affected
by surface weather conditions.
In well ventilated mines, methane should not build
up, but it is lighter than air, so will rise into higher
points within underground workings.
Cont.
It is highly flammable & explosive when mixed with air or oxygen
between certain limits..
Mixtures of methane in air 0 – 5% methane are not explosive but will
burn near a hot source.
Mixtures in the range 5 – 14% methane are flammable because,
once ignited, flame will self-propagate throughout the mixture
independently of & away from the source of the ignition.
This is also the explosive range because a pressure increase is
associated with the flame propagation.
The most explosive mixture is 9.8% & the most easily ignited
mixture is 7.5%.
Mixtures > 15% are not explosive, do not support combustion but
will burn if mixed with air.
The question is more relevant than the answer.
The question determines the solution, it clarifies
our intention and determination. An answer can
be subjective, wrong or undetermined hence it
depends entirely on the question. If the question
is wrong then the answer is respectively of no
benefit. In philosophy the question says many
things and questions are not for answer but for
enlightenment.
Cont.
While the lower explosive limit in air 5% remains
relatively constant the upper limit 14% will
increase with increases in temp., pressure &
oxygen concentration.
Conversely as the oxygen % drops so does the
upper limit fall, equaling the lower limit at 12.4%
oxygen.
Specific methane emission, expressed as the
volume of methane emitted per ton of coal
produced.
Cont.
The flame safety lamp was developed as a safe
means of lighting in mines that may have methane.
The lamp not only provides light without the risk of an
explosion, but can also be used to test for methane.
A testing flame in these lamps is very small and
shows a triangular blue gas cap if there are high
quantities of methane in the air.
While these lamps are still used today to test for gas,
multi-purpose Solaris detectors are also used.
Controlled by: dilution, sealing and drainage.
HYDROGEN (H2)
Hydrogen (H2) with a SG of 0.07 is non-poisonous but
does not support life.
It is combustible & will burn in air or oxygen forming
water vapour.
Mixtures with air in the range 4 –74.2 % are flammable.
It is considered to be most dangerous because of the
wide flammable range low ignition temp 580deg C, and
with an ignition energy about half of that required by
methane.
Following a methane or coal dust explosion, hydrogen
is present in similar quantities to CO.
Cont.
It is a colourless, odourless, tasteless, nontoxic,
and the lightest of all gases found underground.
Hydrogen sources are battery charging, the action
of water or steam on hot materials, and action of
acid on metals.
Although methane requires at least 12% oxygen for
ignition, hydrogen can explode when the oxygen
content of the air is as low as 5%.
Battery charging stations should be located in
intake air with a duct at roof level that connects
into a return airway
CARBON DIOXIDE (CO2)
Has an SG = 1.53 & forms 0.03% of atmospheric
air. It is an incombustible gas & will not support
combustion.
In some mines it is given off from the strata in
blowers or outbursts, also produced by mine fires,
human respiratory process, blasting, acid action on
carbonates & diesel exhausts.
Blackdamp is a mining term for a build-up of carbon
dioxide.
This gas is not poisonous, but because it replaces
oxygen in the air, it means that people have
nothing to breathe and can suffocate.
Cont.
Carbon dioxide can form due to oxidation, where coal
that is in contact with the air uses up the oxygen to
produce carbon dioxide.
It is not usually a problem when mine workings are well
ventilated. It is heavier than air, so will lie in lower
areas of a mine or in old, disused roadways.
It is colorless, odorless, noncombustible gas that may
have an acid taste when present in high concentrations.
This gas it’s a miner’s friend hence we live in it gives
warning of more dangerous gases ahead of you thus the
reason for the term miner’s friend.
Cont.
Flame safety lamps can detect air that has less oxygen.
The flame will go out when oxygen reaches about 16% or
less, but people will become affected when oxygen levels
reach about 17% or less.
Deputies in mines carry flame safety lamps when
investigating poorly ventilated workings, and keep a
close eye on the flame.
They know to move quickly back to a fresh air base if a
lamp held low down goes out.
Care must be taken when holing thru into old workings
which were not ventilated for sometime.
Cont.
Cont.
Example:
Assuming vigorous activity, an oxygen content of
21%, and a carbon dioxide content of 0.03% in the
intake air, find the quantity of air Q in cfm that must
be supplied per individual if the downstream air
current is to be maintained at acceptable levels (i.e.,
19.5% 0 2 and 0.5% C02).
CARBON MONOXIDE (CO)
Is the most dangerous toxic gas encountered in mines. Why?
It replaces oxygen to form carboxyhaemoglobin (COHb)
which is relatively stable
The COHb blood level is dependant on the carbon monoxide
concentration, the length of exposure, and the level of
activity of the individual exposed.
Its also referred to as “whitedamp”.
The gas is colourless, tasteless and does not smell, so
cannot be easily detected by people.
It is almost always encountered in emergency situation
where breathing apparatus is utilized.
The mixture of gases, including carbon monoxide, resulting
from a mine explosion, is often referred to as afterdamp.
Cont.
It will always be present if smoke is visible.
It is produced in mines from diesel engines, mine
fires and explosions, overheated air compressors,
low temperature oxidation & blasting.
It has an SG= 0.97, is both flammable & explosive,
will burn in air, flammable limits are 12.5 – 74%
with the most explosive concentration being 29%.
The explosive risk is minimal compared to the
physiological effects.
TLV-TWA: 50ppm (0.005%)
TLV-STEL: 400ppm (0.04%)
Cont.
Carbon monoxide affects small animals more
quickly than people.
Caged canaries were used as a simple way of
detecting carbon monoxide.
The birds would fall from their perch before the
miners were affected, and they could move quickly
to an area of fresh air.
Canaries affected in this way could often be
revived.
Modern equipment can detect carbon monoxide
and tell miners exactly how much of the gas is
Cont.
Because of the risks of carbon monoxide if a fire
starts underground, all miners must wear a self-
rescuer.
The self-rescuer is contained in a small metal case
carried on miners’ belts.
After a fire the case is opened to reveal a mouth-
piece and breathing apparatus.
Within the apparatus are chemicals which turn the
poisonous carbon monoxide into carbon dioxide.
The self-rescuer lasts for about an hour-and-a-half.
Cont.
NITROUS FUMES OR OXIDES OF
NITROGEN
Include nitric oxide (NO), nitrogen dioxide (NO2) and
nitrogen peroxide (N2O4)
Nitric oxide in air converts to NO2 so in mining the
properties of oxides of nitrogen maybe related to NO2.
Note: nitrous oxide (N2O) does not occur underground.
Nitrogen dioxide (NO2) is reddish brown in colour, has
a pungent smell & an acid taste, is soluble in water
forming nitric and nitrous acids.
It has an SG 1.6 and although incombustible and non-
flammable it will support combustion.
OXIDES OF NITROGEN
It is extremely poisonous and the effects are treacherous
because in the early stages of exposure, the person will feel ill
& cough violently, then may appear to recover, however
several hours later the symptoms of bronchitis and pneumonia
may develop & death may ensue.
Oxides of nitrogen are produced by diesel exhausts or by
explosives of the nitroglycerine type if incompletely
detonated.
NO2 & oxides of nitrogen can be identified with detector
tubes.
TLV-TWA: 5ppm (0.0005%)
TLV-STEL: 5ppm (0.0005%)
Cont.
The toxic oxides of nitrogen react with moisture to
form nitrous and nitric acid.
Relatively small quantities of these gases may
cause death by combining with the moisture in the
lungs and corroding the respiratory passages.
Death may happen several days later as a result of
pulmonary edema (water in the lungs).
Cont.
HYDROGEN SULPHIDE (H2S)
Hydrogen Sulphide (H2S) is an extremely poisonous gas
which sometimes issues from rock fissures together with
water or other gases.
It has an SG =1.19, an unpleasant odour of rotten eggs &
burns with a bright blue flame producing SO2 & water vapour.
It is referred to as a “stinkdamp” because of its odour, which
resembles that of rotten eggs, is a colorless, toxic, and
explosive gas formed by the decomposition of sulfur
compounds.
Low concentrations may be found in air from gob fires or may
be released from water seeping in from the strata.
Cont.
Large concentrations occur in natural gas and oil fields
and in some sulfur and gypsum mines.
It is quite soluble in water and may be carried into
active mine workings by groundwater.
Although hydrogen sulphide has a distinctive odour, the
sense of smell cannot be relied upon as a means of
detection, because after one or two inhalations, the
olfactory nerves become paralyzed and the odour can
no longer be detected.
Hydrogen sulphide is produced by acidic action or the
effects of heating on sulphide ores.
Cont.
It forms a flammable mixture in air in the range 4.5
– 45%.
It is an extremely toxic gas, it irritates the lungs &
respiratory tract but in particular it has a narcotic
effect on the nervous system.
TLV-TWA: 10ppm (0.001%)
TLV-STEL: 15ppm (0.0015%)
and as little 1ppm can be detected by smell,
However nasal sensitivity decreases with exposure
& increased concentration levels.
SULPHUR DIOXIDE (SO2)
It is a colorless, nonflammable, toxic gas formed whenever sulfur
or sulfur compounds are burnt.
Formed during blasting of certain sulfur ores, internal combustion
engines, or during fires involving sulfur compounds such as
pyrite.
SG is 2.26 and in very low concentrations is irritating to the eyes,
nose, and throat.
It can be detected at very low concentrations both by its acidic
taste and the intense burning sensation it causes to the eyes and
respiratory tracts.
TLV-TWA: 5ppm (0.0005%)
TLV-STEL: 5ppm (0.0005%)
RADON
It is a gaseous, chemically inert, radioactive product of the
disintegration of radium.
It is found primarily in uranium mines, although present in
trace amounts in other types of mine including coal mines.
It diffuses from the rock strata into the mine environment,
where the decay process continues.
Once radon is released into the mine environment, the
decay process continues with the formation of radium A,
which decays to radium B, which produces radium C and so
forth.
The products formed by the decay of radon are referred to
as radon daughters.
Cont.
The daughter products, however because they are
particles of matter, attach themselves to the dust
that is present in the environment and when inhaled,
tend to be deposited and concentrated in the
respiratory system.
Exposure to excessive concentrations of radon and
radon daughters has been linked with a high
incidence of lung cancer.
ALDEHYDES
Are a series of organic compounds, the lowest
member of the family is formaldehyde.
Several aldehydes, with formaldehyde
predominating, are present in exhaust gases from
diesel engines.
They have a pungent smell, are irritating to the
eyes, the mucous membranes and the skin.
AMMONIA (NH3)
Has a very pungent smell, smelt after blasting with
ammonia explosives, can appear in dangerous
quantities when leaked from cooling plants which
use it as a refrigerant.
In such cases it causes intense irritation of the
eyes, nose & throat & produces coughing.
In high concentrations it may arrest respiration.
SG -0.6, colourless and pungent smell
FREON