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Historically Ceramics Are Used As Ideal Insulating Materials For Their Good and
Historically Ceramics Are Used As Ideal Insulating Materials For Their Good and
Current Carrier
Metals : Free electrons
Semiconductors : Electrons and electron-holes
Ceramics : Electrons and/or ions
Occupied
valence band
Electrical conductivity, s
proportionality constant between j and E
j nqv
s= = -1cm-1 or S/cm
E E
The drift velocity is directly proportional to the locally
acting electrical field strength, and their ratio is defined
as the mobility, m (i.e., velocity per unit field)
v n (q) v
m= cm-1V-1s-1
s=
E E
s = n (q) m
Absolute mobility, B
drift velocity per unit of applied force F (the virtual force which
acts on a diffusing carrier)
v v s = n (q)2 B
B= =
F (q)E m = (q)B
Ionic Conductivity
Carrier of electrical
charge – charged ionic
vacancy, interstitials defects
moves under the influence of an electric field
based on random ion hopping
D=kBT
Hence
n q D
2
kT
Size
Charge
lattice
q=ze
activation energy
for ion motion
u or, Hm
Energy a (ze)Ea = Fa
Distance
Forward jump rate
(ze)Ea
-u+ kT q = probability of a site
2
f+ = q e is available for a jump
(ze)Ea (ze)Ea
sinh 2kT
2kT
na2(ze)E - u / kT
qe
n = carrier concentration
naf = af = drift velocity
kT
j = n(ze)v = n(ze)af
na2(ze)2E - u / kT
j =
kT
q e
Ionic conductivity
j na2(ze)2 - u / kT
s = E =
kT
q e
n(ze)2
s = Ds n = cion (vacancy mechanism)
kT n = cint (interstitial mechanism)
Ionic diffusivity
-u / kT
Ds = a q e 2
depends
only on D0
Ds Low T
s0 = conductivity of
Extrinsic pure material
High T
Intrinsic
depends on D0 and
vacancy site 1/T
Monoclinic(1170℃)tetragonal(2370℃)cub
ic
(2680℃)
CaO Ca Zr V O
Fig: The ideal fluorite structure
x showing
half a unit cell including a
O O dopant cation and
ZrO 2 a charge-compensating oxygen
vacancy.
β- 11 Al2O3 -
alumina x Na2O
The crystal is made of parallel thin layers of dense alumina
The crystal is made of parallel thin layers of dense alumina
separated from each other by scarcely occupied planes where
all sodium ions are confined.
COMPOSITIONAL Na2O·11Al2O3(β-alumina),Na2O·8Al2O3(β’-
VARIATION alumina),Na2O·5Al2O3(β’’-alumina)
β-alumina is alternate
layer of alumina and
Na2O
Conductivity parallel to
planes is 1 Sm-1:room
temperature,30 Sm-1:300℃
Na2O·11Al2O3(β- Increasing
alumina) conductivity
due to loose
Na22O·8Al22O33(β’- spinel
alumina) packing
Electrode
Electrode
Na
Na22O·5Al22O33(β’’-
Molten Na
Electrode
S
Electrode
Molten S
alumina)
Molten
Molten
Alumina has a close packed spinel structure and as
the number of alumina decreases, the packing
density of spinel layers also decreases
Na/S battery
Battery
Limited Application:
Aerospace and satellite
Fuel Cell
The ceramics used in SOFCs do not
become electrically and ionically active
until they reach very high temperature
As a consequence the stacks have to run
at temperatures ranging from 500 to
1,000 °C.
Reduction of oxygen into oxygen ions
occurs at the cathode. These ions can
then diffuse through the solid oxide
electrolyte to the anode where they can
electrochemically oxidize the fuel.
In this reaction, a water byproduct is
given off as well as two electrons. These
electrons then flow through an external
circuit where they can do work.