Anggota Kelompok

• William Renaldi (1606825146)

• Ricky Yuwon Pahlawan (1606824244)
• Rahmat Prayogi (1606835052)
• Ig Satrio Wicaksono (1606904213)
• Nurul Anwar (1606901760)
• Lukman Satrio A (1606874280)
• Dzaky
Exercise 2.8 (A)
A sample of 1.00 mol H2O(g) is condensed isothermally and
reversibly to liquid at 100°C. The standard enthalpy of vaporization of
methanol at 100°C is 40.656 kJ/mol.
Find w, q, ΔU, and ΔH for this process.

n = 1.00 mol ΔH= -ΔvapH x n

= -1.00 x 40.656 kJ/mol
T = 100°C + 273 = 373 K = -40.656 kJ
w = pxΔv
ΔvapH = 40.656 kJ/mol = nxRxΔT
= 1.00x8.3145x(373)
= 3101 J = 3.101 kJ
Exercise 2.8 (A) Solution
Dikarenakan keadaan system yang bekerja adalah isothermal reversible
maka tekanan luar selalu konstan sehingga:
q = qp = ΔH = -40.656 kJ
Dan dengan mengasumsikan bahwa air bekersa dalam system gas ideal
maka dapat kita simpulkan lagi, bahwa:
ΔU = q + w
ΔU = -40.656 + 3.701
ΔU = -37.525 kJ
Exercise 2.21 (A)
A sample consisting of 3.00 mol of diatomic perfect gas molecules at 200 K is
compressed reversibly and adiabatically until its temperature reaches 250 K. Given
that CV,m = 27.5 J K-1 mol-1 .
Calculate q, w, ΔU, ΔH, and the final volume and pressure

n = 3.00 mol

T = 200 K

T = 250 K

CV,m = 27.5 J K-1 mol-1

Exercise 2.21 (A) Solution
Dikarenakan adiabatic reversible, maka
q = qrev = 0
Sehinggga kita bisa mengatakan bahwa ΔU dan ΔH nya sebagai:
ΔU = n x CV,m x ΔT ΔH = n x Cp,m x ΔT
= 3.0 x 27.5 x (250-200) = n x (CV,m + R) x ΔT
= 4125 J = 4.125 kJ = 3.0 x (27.5+8.3145) x (250-200)
= 5372 J = 5.372 kJ
Dimana kita bisa cari w nya dengan
ΔU = q + w
ΔU = 0 + w
ΔU = w = 4.125 kJ
Exercise 2.21 (A) Solution

Final Volume Final Pressure

Untuk mencari volume akhirnya maka Untuk mencari tekanan akhirnya maka
pertama akan kita cari volume mulanya pertama akan kita cari tekanan mulanya
dengan rumus dengan rumus
 Exercise 2.28 (A)
Calculate the standard enthalpy of hydrogenation of 1-hexene into hexana given
that the standard enthalpy of combustion of 1 hexene is -4003 kJ/mol.
CH3(CH2)3CH=CH2 (l) + H2 (g) -------> CH3(CH2)4CH3 (l)

ΔHo298 K, combustion[1-hexene] = -4003 kJ/mol

ΔHo298 K, combustion[hexane] = -4163.12 kJ/mol
o
ΔH 298 K, combustion [hidrogen] = -241 kJ/mol

ΔHo[1-hexene] + ΔHo[hidrogen] - ΔHo[hexane] = Δhhydro

-4003 + (-241) – (-4163.12) = -80.88 kJ/mol

Problem 4.5
• A Carnot cycle uses 1.00 mol of monoatomic perfect gas as the
working substance from an initial state of 10.0 atm and 600 K. It
expands isothermally to a pressure of 1.00 atm (step 1), and then
adiabatically to a temperature of 300 K (step 2). This expansion is
followed by an isothermal compression (step 3), and then an
adiabatic compression (step 4) back to the initial state. Determine the
values of q, w, ΔU, ΔH, ΔS, and ΔStot for each stage of the cycle and for
the cycle as a whole. Express your answer as a table of values.
Step 1 (Isothermal ke P=1 atm)
ΔU = ΔH = 0

W = 1 x 8,3145 x 600 x ln 0,1

W = -11,487 kJ
ΔU = q + W
q = -w
q = 11,487 kJ
Step 2 (Adiabatik ke T=300 K)
Q=0
ΔU = nCvmΔT
ΔU = 1 x 1,5 x 8,3145 x (-300)
ΔU = -3,74 kJ
Q + w = ΔU
W = -3,74 kJ
ΔH = ΔU + P ΔV
ΔH = -3,74 + (1 x 8,3145 x (-300))
ΔH = -6,23 kJ
Step 3 Carnot
n = 1.00 mol
R = 8.3145 J/K.mol
  10
T1 = 300 K 𝑤=1 ×8.3145 × 300 ln
1
=− 5.743 𝑘𝐽

T2 = 600 K 𝑞=−
  𝑤=5.743 𝑘𝐽

 
Step 4 Carnot
n = 1.00 mol
R = 8.3145 J/K.mol
T1 = 300 K  ∆ 𝑈 =1 × 3 × 8.3145× ( 600 −300 ) =3.74 𝑘𝐽
2
T2 = 600 K  
 
 
  

 
 
 
Table Carnot