Fluorine F2 (G) Chlorine Cl2 (G) Bromine Br2 (L) Iodine I2 (L) Astatine

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GROUP VII ELEMENTS

FLUORINE F2(G)
CHLORINE CL2(G)
BROMINE BR2(L)
IODINE I2(L)
ASTATINE
GROUP VII ELECTRON CONFIGURATION
COLOUR OF GAS

• Fluorine – light yellow


• chlorine-green
• Bromine-red brown
• iodine-violet
STRUCTURE AND BONDING
F2
all are simple molecular with
Cl2 covalent bonds.
Br2 All are non-polar molecules
with ID-ID forces between
I2 them
Halogens KCl KBr KI

Chlorine Colorless to orange brown


Brown
Cl2rless to brown soln
Soln
Cl2(aq) Cl2(aq) +2KBr(aq)>2Cl(aq)
+Br2(aq)
Cl2(g) +2KI>2KCl2(aq)
+I2(aq)

Bromine Orange brown soln


KCl(aq) +Br2>no reaction
Orange brown soln to dark
brown
Br2(aq) Br2(aq) +2KI>2KBr(aq)
+I2(aq)

Iodine I2(aq) Remains brown


No reaction
Remains brown
No reaction
ELECTRODE POTENTIALS
REACTION WITH NAOH
Chlorine, Bromine, Iodine undergo similar reactions with alkalis. The product
depend On the temperature at which the reaction is carried out.
Cold dilute NaoH
When chlorine is added to dilute NaoH at about 15°c,a mixture of sodium
chloride and sodium chlorate (1) is formed.
Cl2(g) +2NaoH(aq)>NaCl(aq)+NaClo(aq)+H2O(l)
The sodium chlorate (I) produced in the reaction slowly decomposes to sodium
chloride and sodium chlorate(v), NaCLO3
3NaCLO(aq)>2NaCl(aq)+NaCLO3(aq)
Both reaction are fast at 15°c for Bromine and Iodine. Decomposition of iodate
(I) to iodate(v) occur rapidly even at 0°C
• Hot dilute NaoH
• NaoHwhen chlorine is bubbled directly into hot aqueous
NaOH at about 70°c,a mixture of NaCl and sodium
chlorate (v) is formed
• 3Cl2(g)+6NaoH(aq)>5NaCl(aq)+CLO3(aq)+3H2O(l)
HYDROGEN HALIDES
H2(g) +F2(g)>2HF(g) – Explosive in the dark under cold
condition
H2(g)+Cl2(g)>2HCl-slow in dark explosive in light
H2(g)+Br2(g)>2HBr-must be heated and add catalyst, mild
explosive
H2(g)+I2(g)> 2HI(g)-reversible reaction3
BOND ENERGIES

H
F 5

H Cl

H Br

H I
TESTING FOR HALIDE IONS

• https://youtu.be/jh96IGq_S28

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