PONCHON-SAVARIT

METHOD
ENGR. CRIZALDY V. TUGADE
DEPARTMENT OF CHEMICAL ENGINEERING
TECHNOLOGICAL INSTITUTE OF THE PHILIPPINES - MANILA
Ponchon-Savarit Method

Fractional Distillation using Ponchon-Savarit Method

(aka Enthalpy-Concentration Method)

 molal flow rates need not to be constant

 using enthalpy as well as material balances
Ponchon-Savarit Method

  
When the operating lines are plotted with the equilibrium curve on the x-y
diagram, the McCabe-Thiele step-by-step construction can be used to compute
the number of ideal plates. However, unless and are constant, the operating lines
are curved and can be plotted only if the change with concentration in these
internal streams is known. Enthalpy balances are required in the general case to
determine the position of a curved operating line.
Ponchon-Savarit Method
Ponchon-Savarit Method

The enthalpy-concentration diagram requires the following data at a constant

pressure:
(1) heat capacity of the liquid as a function of temperature, composition, and
pressure.
(2) heat of solution as a function of temperature and composition.
(3) latent heats of vaporization as a function of composition and pressure or
temperature.
(4) boiling point as a function of pressure, composition and temperature.
Ponchon-Savarit Method

The diagram at a given constant pressure is based on arbitrary reference states of

liquid and temperature, which is usually taken as the boiling point of the lower
boiling component A.
Ponchon-Savarit Method
The  saturated liquid enthalpy () is:


 𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 ) +∆ 𝐻 𝑠𝑜𝑙

 
Ponchon-Savarit Method
The  saturated liquid enthalpy () is:


 𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 ) +∆ 𝐻 𝑠𝑜𝑙

 
wherein:
in liquid phase
 Ponchon-Savarit Method
The  saturated vapor enthalpy () is:


 𝐻 𝑦 = 𝑦 𝐴 [ ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) ] + ( 1 − 𝑦 𝐴 ) [ ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 ) ]

 
wherein:
in vapor phase
 Ponchon-Savarit Method
𝐻 𝑦 = 𝑦 𝐴 [ ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) ] + ( 1 − 𝑦 𝐴 ) [ ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 ) ]
 
  
Solving in :

 ∆ 𝐻 𝑉𝐴 =𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏𝐴 − 𝑇 0 )+ ∆ 𝐻 𝑉𝐴 𝑏 − 𝐶𝑝 𝑉 𝐴 ( 𝑇 𝑏𝐴 − 𝑇 0 )

 ∆ 𝐻 𝑉 𝐵 =𝐶𝑝 𝐿𝐵 ( 𝑇 𝑏𝐵 −𝑇 0 ) +∆ 𝐻 𝑉 𝐵𝑏 − 𝐶𝑝𝑉 𝐵 ( 𝑇 𝑏 𝐵 − 𝑇 0 )

 
wherein:
Ponchon-Savarit Method
 𝐻𝑒𝑎𝑡 𝐵𝑎𝑙𝑎𝑛𝑐𝑒 𝑎𝑟𝑜𝑢𝑛𝑑 𝑡h𝑒 𝑐𝑜𝑛𝑑𝑒𝑛𝑠𝑒𝑟

 𝑉 𝑛 +1 𝐻 𝑦 , 𝑛+1=𝐿 𝑛 𝐻 𝑥 𝑛+ 𝐷 𝐻 𝑥 𝐷 +𝑞 𝑐

 𝑞 𝑐 =𝑉 1 𝐻 𝑦𝑙 − 𝐿 𝐻 𝑥𝐷 − 𝐷 𝐻 𝑥 𝐷

 𝐻𝑒𝑎𝑡 𝐵𝑎𝑙𝑎𝑛𝑐𝑒 𝑎𝑟𝑜𝑢𝑛𝑑 𝑡h𝑒 𝑤h𝑜𝑙𝑒 𝑑𝑖𝑠𝑡𝑖𝑙𝑙𝑒𝑟

𝑞  𝑟= 𝐷 𝐻 𝑥 𝐷 + 𝐵 𝐻 𝑥 𝐵+ 𝑞 𝑐 − 𝐹𝐻 𝐹
Ponchon-Savarit Method

  𝐷 𝐻 𝑥𝐷 + 𝑞 𝑐
′
𝑄=
𝐷

  ′′ 𝑞𝑟
𝑄 = 𝐻 𝑥𝐵 −
𝐵
Ponchon-Savarit Method
Sample Problem 1:
Prepare an enthalpy concentration plot for benzene-toluene at 1 atm pressure. Equilibrium and physical property data are
given.
Ponchon-Savarit Method
Sample Problem 1:
 We choose a reference temperature of so that the liquid enthalpy of pure benzene () at the boiling point is zero.

 𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 ) +∆ 𝐻 𝑠𝑜𝑙

 We start at

  𝑥 1= ( 0 ) 138.2 𝑘𝐽 𝑘𝐽
𝐻 ( 𝑘𝑚𝑜𝑙 − 𝐾 ) (
( 1 10.6− 80.1 ) + ( 1− 0 ) 167.5
𝑘𝑚𝑜𝑙 − 𝐾)( 110.6 −80.1 ) +0

 
 Ponchon-Savarit Method
Sample Problem 1:  𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 )

At
 
  𝑥 2= ( 0.2 ) 138.2 𝑘𝐽 𝑘𝐽
𝐻 ( 𝑘𝑚𝑜𝑙 − 𝐾 ) (
( 102.21− 80.1 ) + ( 1− 0.2 ) 167.5
𝑘𝑚𝑜𝑙 − 𝐾)( 102.21− 80.1 ) +0

At
 

  𝑥 3 =( 0.4 ) 138.2 𝑘𝐽 𝑘𝐽
𝐻 ( 𝑘𝑚𝑜𝑙 − 𝐾 ) (
( 95.28 −80.1 ) + ( 1− 0 .4 ) 167.5
𝑘𝑚𝑜𝑙 − 𝐾 )
( 95.28 −80.1 ) +0

 
y = -6.5747x3 + 22.177x2 - 46.109x + 110.65
 Ponchon-Savarit Method
Sample Problem 1:  𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 )

At
 
  𝑥 4 =( 0.6 ) 138.2 𝑘𝐽 𝑘𝐽
𝐻 ( 𝑘𝑚𝑜𝑙 − 𝐾 ) (
( 89.50 −80.1 ) + ( 1 −0 .6 ) 167.5
𝑘𝑚𝑜𝑙 − 𝐾 )
( 89.50− 80.1 ) +0

At
 

  𝑥 5 =( 0.8 ) 138.2 𝑘𝐽 𝑘𝐽
𝐻 ( 𝑘𝑚𝑜𝑙 − 𝐾 ) (
( 84.54 − 80.1 ) + ( 1− 0.8 ) 167.5
𝑘𝑚𝑜𝑙 − 𝐾 )
( 84.54 − 80.1 ) +0

 
y = -6.5747x3 + 22.177x2 - 46.109x + 110.65
 Ponchon-Savarit Method
Sample Problem 1:

 𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 )

At
 

  𝑥 4 =( 1 ) 138.2 𝑘𝐽 𝑘𝐽
𝐻 ( 𝑘𝑚𝑜𝑙 − 𝐾 ) (
( 80.09 − 80.1 )+ (1 −1 ) 167.5
𝑘𝑚𝑜𝑙 − 𝐾)( 80.09 −80.1 ) +0

y = -6.5747x3 + 22.177x2 - 46.109x + 110.65

Ponchon-Savarit Method
 𝐻 𝑥 = 𝑥 𝐴 𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏 − 𝑇 0 ) + ( 1 − 𝑥 𝐴 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝑏 − 𝑇 0 )

6000

0.00 5000
f(x) = 2780.31 x² − 7824.43 x + 5075.44
0.20 R² = 1

0.20
0.40 4000

0.60 3000
0.40
0.80
1.00 - 2000
0.60
1000
0.80
0
0 0.2 0.4 0.6 0.8 1 1.2
1.00
-1000
Ponchon-Savarit Method
Remember:
𝑇  0=80.1 ℃

𝐻 𝑦 = 𝑦 𝐴 [ ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) ] + ( 1 − 𝑦 𝐴 ) [ ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 ) ]
 

 Solving in :

 ∆ 𝐻 𝑉𝐴 =𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏𝐴 − 𝑇 0 )+ ∆ 𝐻 𝑉𝐴 𝑏 − 𝐶𝑝 𝑉 𝐴 ( 𝑇 𝑏𝐴 − 𝑇 0 )

 ∆ 𝐻 𝑉 𝐵 =𝐶𝑝 𝐿𝐵 ( 𝑇 𝑏𝐵 −𝑇 0 ) +∆ 𝐻 𝑉 𝐵𝑏 − 𝐶𝑝𝑉 𝐵 ( 𝑇 𝑏 𝐵 − 𝑇 0 )
 Ponchon-Savarit Method

 ∆ 𝐻 𝑉𝐴 =𝐶𝑝 𝐿𝐴 ( 𝑇 𝑏𝐴 − 𝑇 0 )+ ∆ 𝐻 𝑉𝐴 𝑏 − 𝐶𝑝 𝑉 𝐴 ( 𝑇 𝑏𝐴 − 𝑇 0 )

  𝑘𝐽 𝑘𝐽 𝑘𝐽
𝐶𝑝 𝐿𝐴 =138.2 ;𝑇 𝑏 𝐴 =80.1 ℃ ; ∆ 𝐻 𝑉𝐴 𝑏=30820 ; 𝑇 0 =80.1 ℃ ; 𝐶𝑝𝑉𝐴 =96.3
𝑘𝑚𝑜𝑙 − 𝐾 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙 − 𝐾

  𝐻 𝑉𝐴 =138.2 𝑘𝐽 𝑘𝐽 𝑘𝐽
∆ ( 8 0.1 −80.1 ) +30820 − 96.3 ( 80.1 −80.1 )
𝑘𝑚𝑜𝑙 − 𝐾 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙 − 𝐾

  𝐻 =30820 𝑘𝐽
∆ 𝑉𝐴
𝑘𝑚𝑜𝑙
 Ponchon-Savarit Method

 ∆ 𝐻 𝑉 𝐵 =𝐶𝑝 𝐿𝐵 ( 𝑇 𝑏𝐵 −𝑇 0 ) +∆ 𝐻 𝑉 𝐵𝑏 − 𝐶𝑝𝑉 𝐵 ( 𝑇 𝑏 𝐵 − 𝑇 0 )

  𝑘𝐽 𝑘𝐽 𝑘𝐽
𝐶𝑝 𝐿 𝐵 =167.5 ;𝑇 𝑏 𝐵=110.6 ℃ ; ∆ 𝐻 𝑉 𝐵 𝑏=33330 ; 𝑇 0 =80.1℃ ; 𝐶𝑝𝑉𝐵 =138.2
𝑘𝑚𝑜𝑙 − 𝐾 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙 − 𝐾

  𝐻 𝑉 𝐵 =167.5 𝑘𝐽 𝑘𝐽 𝑘𝐽
∆ (110.6 −80.1 ) +33330 − 138.2 ( 110.6 −80.1 )
𝑘𝑚𝑜𝑙 − 𝐾 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙 − 𝐾

  𝐻 =34223.65 𝑘𝐽
∆ 𝑉𝐵
𝑘𝑚𝑜𝑙
 Ponchon-Savarit Method
 𝐻 𝑦 = 𝑦 𝐴 ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) + ( 1 − 𝑦 𝐴 ) ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 )
[ ] [ ]
We
  start at

𝑘𝐽 𝑘𝐽 𝑘𝐽 𝑘𝐽
[
  𝑦 =0 30820
𝐻
𝑘𝑚𝑜𝑙
+96.3
𝑘𝑚𝑜𝑙 − 𝐾 ] [
( 80.1 ℃ −80.1 ℃ ) + ( 1− 0 ) 34223.65
𝑘𝑚𝑜𝑙
+138.2
𝑘𝑚𝑜𝑙 − 𝐾
( 80.1 ℃ −80.1 ℃ ) ]
y = -11.518x3 + 3.1097x2 - 22.051x + 110.68
 
 y = -11.518x3 + 3.1097x2 - 22.051x + 110.68

Ponchon-Savarit Method
 𝐻 𝑦 = 𝑦 𝐴 ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) + ( 1 − 𝑦 𝐴 ) ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 )
[ ] [ ]
At
 

𝑘𝐽 𝑘𝐽 𝑘𝐽 𝑘𝐽
[
  𝑦 =0.2 30820
𝐻
𝑘𝑚𝑜𝑙
+96.3
𝑘𝑚𝑜𝑙 − 𝐾 ] [
( 106.30 ℃ −80.1 ℃ ) + ( 1− 0.2 ) 34223.65
𝑘𝑚𝑜𝑙
+138.2
𝑘𝑚𝑜𝑙 − 𝐾
( 106.30℃ − 80.1℃ ) ]
 

At
 

𝑘𝐽 𝑘𝐽 𝑘𝐽 𝑘𝐽
[
  𝑦 =0.4 30820
𝐻
𝑘𝑚𝑜𝑙
+ 96.3
𝑘𝑚𝑜𝑙 − 𝐾 ] [
( 101.62℃ −80.1 ℃ ) + ( 1 −0.4 ) 34223.65
𝑘𝑚𝑜𝑙
+138.2
𝑘𝑚𝑜𝑙 − 𝐾
( 101.62℃ −80.1 ℃ ) ]
 
 y = -11.518x3 + 3.1097x2 - 22.051x + 110.68

Ponchon-Savarit Method
 𝐻 𝑦 = 𝑦 𝐴 ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) + ( 1 − 𝑦 𝐴 ) ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 )
[ ] [ ]
At
 

𝑘𝐽 𝑘𝐽 𝑘𝐽 𝑘𝐽
[
  𝑦 =0.6 30820
𝐻
𝑘𝑚𝑜𝑙
+ 96.3
𝑘𝑚𝑜𝑙 − 𝐾 ] [
( 96.08℃ − 80.1℃ ) + ( 1 −0.6 ) 34223.65
𝑘𝑚𝑜𝑙
+138.2
𝑘𝑚𝑜𝑙 − 𝐾
( 96.08 ℃ − 80.1 ℃ ) ]
𝑘𝐽
  𝑦 =33988.27
𝐻 @ 𝑦 𝐴 =0.6
𝑘𝑚𝑜𝑙

At
 

𝑘𝐽 𝑘𝐽 𝑘𝐽 𝑘𝐽
[
  𝑦 =0.8 30820
𝐻
𝑘𝑚𝑜𝑙
+96.3
𝑘𝑚𝑜𝑙 − 𝐾 ] [
( 89.13 ℃ −80.1 ℃ ) + ( 1 −0.8 ) 34223.65
𝑘𝑚𝑜𝑙
+138.2
𝑘𝑚𝑜𝑙 − 𝐾
( 89.13 ℃ −80.1 ℃ ) ]
𝑘𝐽
  𝑦 =32446.2 2
𝐻 @ 𝑦 𝐴 =0.8
𝑘𝑚𝑜𝑙
 y = -11.518x3 + 3.1097x2 - 22.051x + 110.68

Ponchon-Savarit Method
 𝐻 𝑦 = 𝑦 𝐴 ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) + ( 1 − 𝑦 𝐴 ) ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉 𝐵 ( 𝑇 𝑑 − 𝑇 0 )
[ ] [ ]
At
 

𝑘𝐽 𝑘𝐽 𝑘𝐽 𝑘𝐽
[
  𝑦 =1 30820
𝐻
𝑘𝑚𝑜𝑙
+96.3
𝑘𝑚𝑜𝑙 − 𝐾 ] [
( 80.2 ℃ − 80.1℃ ) + (1 −1 ) 34223.65
𝑘𝑚𝑜𝑙
+138.2
𝑘𝑚𝑜𝑙 − 𝐾
( 80.2℃ −80.1 ℃ ) ]
𝑘𝐽
  𝑦 =30829.63
𝐻 @ 𝑦 𝐴 =1.0
𝑘𝑚𝑜𝑙
Ponchon-Savarit Method
 𝐻 𝑦 = 𝑦 𝐴 ∆ 𝐻 𝑉𝐴 +𝐶𝑝 𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) + ( 1 − 𝑦 𝐴 ) ∆ 𝐻 𝑉 𝐵 +𝐶𝑝 𝑉
[ ] [ 𝐵 (𝑇 𝑑 − 𝑇 0 )]

45000

0.00 40000
f(x) = − 58345.6 x⁴ + 128118.82 x³ − 89874.17 x² + 12421.05 x + 38479.67
0.20 35000 R² = 1
0.20
0.40
30000
0.60
0.40 25000
0.80
1.00 20000
0.60
15000

0.80 10000

5000
1.00
0
0 0.2 0.4 0.6 0.8 1 1.2
Ponchon-Savarit Method
45000
𝐵𝑒𝑛𝑧𝑒𝑛𝑒
  −𝑇𝑜𝑙𝑢𝑒𝑛𝑒 𝐸𝑛𝑡h𝑎𝑙𝑝𝑦 𝐶𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑡𝑖𝑜𝑛 𝐷𝑖𝑎𝑔𝑟𝑎𝑚
40000
f(x) = − 58345.6 x⁴ + 128118.82 x³ − 89874.17 x² + 12421.05 x + 38479.67
R² = 1
35000

30000

25000

20000

15000

10000

5000
f(x) = 2780.31 x² − 7824.43 x + 5075.44
R² = 1
0
0 0.2 0.4 0.6 0.8 1 1.2

-5000

Hx Polynomial (Hx) Hy Polynomial (Hy)

Ponchon-Savarit Method
Sample Problem 2:

A liquid mixture of benzene-toluene is to be distilled in a fractionating tower at

101.3 kPa pressure. The feed of 100 kmol/h is liquid, containing 45 mol %
benzene and 55 mol % toluene, and enters at 54.4oC. A distillate containing 95
mol % benzene and 5 mol % toluene and a bottoms containing 10 mol %
benzene and 90 mol % toluene are to be obtained. The reflux ratio is 1.755. The
average heat capacity of the feed is 159 kJ/(kmol K) and the average latent heat
is 32099 kJ/kmol. Use enthalpy balances to calculate the flow rates of the liquid
and vapor at various points in the tower and plot the curved operating lines.
Determine the number of theoretical stages needed using Ponchon-Savarit
Method.
Ponchon-Savarit Method
Given: Required:
    A liquid mixture of benzene-toluene is to be
distilled in a fractionating tower at 101.3 kPa
pressure. The feed of 100 kmol/h is liquid,
containing 45 mol % benzene and 55 mol %
toluene, and enters at 54.4oC. A distillate
containing 95 mol % benzene and 5 mol %
toluene and a bottoms containing 10 mol %
benzene and 90 mol % toluene are to be
obtained. The reflux ratio is 1.755. The average
heat capacity of the feed is 159 kJ/(kmol K) and
the average latent heat is 32099 kJ/kmol. Use
enthalpy balances to calculate the flow rates of
the liquid and vapor at various points in the
tower and plot the curved operating lines.
Determine the number of theoretical stages
needed.
  

Ponchon-Savarit Method
OMB:
 𝑅=1.755
 𝐹=𝐷+ 𝐵   𝐿
 100= 𝐷+ 𝐵 𝑅=
𝐷
  𝐿
CB of MVC: 1.755=
41.18
𝐹 𝑥 𝐹 = 𝐷 𝑥 𝐷 +𝐵 𝑥 𝐵
   𝐿=72.27

100(0.45)=𝐷 (0.95)+𝑊 (0.10)

 
𝐿+𝐷=𝑉
 

Solving simultaneously:
7 2.27+41.18=𝑉
 
  𝐷= 41.18  𝑉 =113.45
  𝐵 =52.82
 y = -11.518x3 + 3.1097x2 - 22.051x + 110.68

Ponchon-Savarit Method
  : 𝑞 𝑐 =𝑉 1 𝐻 𝑦𝑙 − 𝐿 𝐻 𝑥𝐷 − 𝐷 𝐻 𝑥 𝐷
 
y = -6.5747x3 + 22.177x2 - 46.109x + 110.65

𝐻
  𝑦𝑙 = 𝑦 𝐴 [ ∆ 𝐻 𝑉𝐴 +𝐶𝑝𝑉𝐴 ( 𝑇 𝑑 − 𝑇 0 ) ]+ ( 1 − 𝑦 𝐴 ) [ ∆ 𝐻 𝑉 𝐵 +𝐶𝑝𝑉 𝐵 ( 𝑇 𝑑 −𝑇 0 ) ]

  ;

𝐻
  𝑦𝑙 =0.95 [ ∆ 𝐻 𝑉𝐴 +96.3 ( 82.66 −80.1 ) ]+ ( 1 −0.95 ) [ ∆ 𝐻 𝑉 𝐵 +138.2 ( 82.66 −80.1 ) ]
  𝑘𝐽
𝐻 𝑦𝑙 =31242.35
𝑘𝑚𝑜𝑙

𝐻
  𝑥𝐷 = 𝑥 𝐹 𝐶𝑝 𝐿𝐴 ( 𝑇 𝐹 −𝑇 0 ) + ( 1− 𝑥 𝐹 ) 𝐶𝑝 𝐿𝐵 ( 𝑇 𝐹 −𝑇 0 )

  ;

𝐻
  𝑥𝐷 =0.95(138.2) ( 81.17 − 80.1 )+ (1 − 0.95 ) 167.5 ( 81.17 − 80.1 )

  𝑘𝐽
𝐻 𝑥𝐷 =150.03
𝑘𝑚𝑜𝑙
 Ponchon-Savarit Method
𝑞 𝑐 =𝑉 1 𝐻 𝑦𝑙 − 𝐿 𝐻 𝑥𝐷 − 𝐷 𝐻 𝑥 𝐷
 

; 

  𝑘𝐽 𝑘𝐽 𝑘𝐽
𝑞 𝑐 =( 113.45 𝑘𝑚𝑜𝑙 ) 31242.35
𝑘𝑚𝑜𝑙 (
−72.27 𝑘𝑚𝑜𝑙 150.03
𝑘𝑚𝑜𝑙 ) (
− 4 1.18 𝑘𝑚𝑜𝑙 150.03
𝑘𝑚𝑜𝑙 )
  𝑘𝐽
𝑞 𝑐 =3527423.704
𝑘𝑚𝑜𝑙
 y = -11.518x3 + 3.1097x2 - 22.051x + 110.68

Ponchon-Savarit Method
  : 𝑞 𝑟= 𝐷 𝐻 𝑥 𝐷 + 𝐵 𝐻 𝑥 𝐵+ 𝑞 𝑐 − 𝐹𝐻 𝐹
 
y = -6.5747x3 + 22.177x2 - 46.109x + 110.65

 𝐻 𝐹 = 𝑥 𝐹 𝐶𝑝 𝐿𝐴 ( 𝑇 𝐹 − 𝑇 0 ) + ( 1− 𝑥 𝐹 ) 𝐶𝑝 𝐿 𝐵 ( 𝑇 𝐹 − 𝑇 0 )

  ;

𝐻
  𝐹 =( 0.45 ) 138.2 ( 5 4.40 −8 0.1 ) + ( 1 −0 .45 ) 167.5 ( 5 4.40− 80.1 )
 

45000
40000
35000 f(x) = − 58345.6 x⁴ + 128118.82 x³ − 89874.17 x² + 12421.05 x + 38479.67
30000 R² = 1
25000   using the enthalpy concentration:
20000
15000 2
𝐻
  𝑥𝐵 = 2780.3 𝑥 −7824.4 𝑥 +5075.4
10000

 𝑥𝑊 =𝑥 𝐵 =0. 10
5000
0 f(x) = 2780.31 x² − 7824.43 x + 5075.44
R² = 1
-50000 0.2 0.4 0.6 0.8 1 1.2
  𝑘𝐽
Hx Polynomial (Hx) 𝐻 𝑥𝐵 =4 320.763
Hy Polynomial (Hy)
𝑘𝑚𝑜𝑙
 Ponchon-Savarit Method
𝑞 𝑟= 𝐷 𝐻 𝑥 𝐷 + 𝐵 𝐻 𝑥 𝐵+ 𝑞 𝑐 − 𝐹𝐻 𝐹
 

  𝑥𝐷 =150.03 𝑘𝐽 ; 𝐻 𝑥𝐵 =4320.763 𝑘𝐽 ; 𝑞 =3527423.704 𝑘𝐽 ; 𝐻 𝐹 =−3965. 90 𝑘𝐽 ; 𝐷 =41.18; 𝐵=52.82; 𝐹=100

𝐻
𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙 𝑐 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙

 𝑞 =41.18 ( 150.03 ) +52.82 ( 4320.76 ) +3527423.704 − 100(−3965.90)

𝑟

  𝑘𝐽
𝑞 𝑟=4158414.48
𝑘𝑚𝑜𝑙
Ponchon-Savarit Method
  𝐷 𝐻 𝑥𝐷 + 𝑞 𝑐
′
𝑄=
𝐷
  ′ 41.18 ( 150.03 ) +3527423.704
𝑄 =
41.18

𝑄 ′ =85,808.69 𝑘𝐽 / 𝑘𝑚𝑜𝑙
 

  ′′𝑞𝑟
𝑄 =𝐻 𝑥 𝐵−
𝐵
  ′′ 4158414.48
𝑄 =4320.76 −
52.82
′′
𝑄 =−66,401.33 𝑘𝐽 / 𝑘𝑚𝑜𝑙
 
Ponchon-Savarit Method
100000

  𝐷,𝑄′)¿
(𝑥¿¿
85,808.69
80000

60000

40000

20000

0
0 0.2 0.4 0.6 0.8 1 1.2

-20000
Ponchon-Savarit Method
100000
  𝐷,𝑄′)¿
(𝑥¿¿
85,808.69
80000

60000

40000

20000

0
0 0.2 0.4 0.6 0.8 1 1.2

-20000

-40000

  𝐵,𝑄′′)¿
(𝑥¿¿
-60000
-66,401.33

-80000
Ponchon-Savarit Method
100000
(𝑥¿¿ 𝐷,𝑄′)¿
  VALUE])
(0.95,[Y

80000

60000

40000

20000

0 (0.45, [Y VALUE])
0 0.2 0.4 0.6 0.8 1 1.2
(𝑥  ¿ ¿ 𝐹 ,𝐻 𝐹 )¿
-20000

-40000

(𝑥¿¿
-60000 (0.10, [Y 𝐵,𝑄′′)¿
  VALUE])

-80000
Ponchon-Savarit Method
100000   𝐷,𝑄′)¿
(𝑥¿¿

80000

60000

40000

20000

0
0 0.2 0.4 0.6 0.8 1 1.2
(𝑥  ¿ ¿ 𝐹 ,𝐻 𝐹 )¿
-20000

-40000

-60000   𝐵,𝑄′′)¿
(𝑥¿¿

-80000
Ponchon-Savarit Method
 𝑥 − 𝑦 𝑑𝑖𝑎𝑔𝑟𝑎𝑚 𝑏𝑒𝑛𝑧𝑒𝑛𝑒 −𝑡𝑜𝑙𝑢𝑒𝑛𝑒
Ponchon-Savarit Method

𝑉1
 

𝐿𝑜
 
Ponchon-Savarit Method

𝑉2 𝑉1
   

𝐿1𝐿𝑜
   
Ponchon-Savarit Method

𝑉3 𝑉2 𝑉1
     
𝐿2 𝐿 𝐿
     
1 𝑜
Ponchon-Savarit Method

𝑉 5 𝑉 4𝑉 3 𝑉 2 𝑉 1
         
𝐿4 𝐿 3 𝐿 2 𝐿 1 𝐿 𝑜
         
Ponchon-Savarit Method

𝑉 6𝑉 5 𝑉 4 𝑉 3 𝑉 2 𝑉 1
           

𝐿5 𝐿 4 𝐿 3 𝐿 2 𝐿 1 𝐿𝑜
           
Ponchon-Savarit Method

𝑉 13 𝑉 12 𝑉 11 𝑉 10 𝑉9 𝑉 7 𝑉 6𝑉 5 𝑉 4 𝑉 3 𝑉 2 𝑉 1
         
𝑉8
               

𝐿11 𝐿10 𝐿9 𝐿8 𝐿7 𝐿 6 𝐿 5 𝐿4 𝐿 𝐿 𝐿 𝐿
                       
3 2 1 𝑜
Ponchon-Savarit Method

𝑉 13 𝑉 12 𝑉 11 𝑉 10 𝑉9 𝑉 7 𝑉 6𝑉 5 𝑉 4 𝑉 3 𝑉 2 𝑉 1
         
𝑉8
               

𝐿11 𝐿10 𝐿9 𝐿8 𝐿7 𝐿 6 𝐿 5 𝐿4 𝐿 𝐿 𝐿 𝐿
                       
3 2 1 𝑜  
12 theoretical plates +
reboiler