Professional Documents
Culture Documents
1.6 Bonding
1.6 Bonding
Group 1 2 3 4 5 6 7 8/0
Element Na Mg Al
Charge on ion 1+ 2+ 3+
Melting point (K) 371 923 933
Element Li Na K Rb Cs
Ionic radius
0.076 0.102 0.138 0.152 0.167
(nm)
Melting
454 371 337 312 302
point (K)
Electronegativity
values for some
common elements.
Values given here
are measured on
the Pauling scale.
higher lower
electronegativity electronegativity
17 of 43 © Boardworks Ltd 2009
Electronegativity, protons and shielding
2. The number of unshielded protons
The greater the number of protons in a nucleus, the
greater the attraction to the electrons in the covalent
bond, resulting in higher electronegativity.
greater nuclear
charge increases
electronegativity…
Element H F Cl Br I
Pauling
2.2 4.0 3.2 3.0 2.7
elecronegativities
decreasing polarization
23 of 43 © Boardworks Ltd 2009
Ionic or covalent?
Rather than saying that ionic and covalent are two distinct
types of bonding, it is more accurate to say that they are at
the two extremes of a scale.
Less polar bonds have More polar bonds have more
more covalent ionic character. The more
character. electronegative atom attracts the
electrons in the bond enough to
ionize the other atom.
increasing polarization
24 of 43 © Boardworks Ltd 2009
Polar molecules
Molecules containing polar bonds are not always polar.
Permanent
dipole–dipole
forces (dotted
lines) occur in
hydrogen chloride
(HCl) gas.