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A Simple Method For The Syntheses of Nanomaterials: Electrodeposition
A Simple Method For The Syntheses of Nanomaterials: Electrodeposition
A Simple Method For The Syntheses of Nanomaterials: Electrodeposition
By Jingpeng Wang
CHEM*7530
Jan 24. 2006
What is electrodeposition?
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Definition: the process that exploits the creation of solid materials directly fro
m electrochemical reactions in liquid compositions with substrate materials.
One of the chemical methods; Also known as electroplating.
Two technologies for plating:
Electroplating: Substrate is placed in electrolyte. When an electrical pot
ential is applied between a conducting area on the substrate and a coun
ter electrode in the liquid, a chemical redox process takes place resultin
g in the formation of a layer of material on the substrate and usually som
e gas generation at the counter electrode.
Electroless plating: Substrate is placed in a more complex chemical
solution, in which deposition happens spontaneously on any surface
which forms a sufficiently high electrochemical potential with the sol
ution. No external electrical potential and contact to the substrate ar
e required, but more difficult to control the thickness and uniformity o
2
f the deposits.
Electroplating:
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Active template-assisted
electrodeposition:
The formation of nanostructures
results from growth of the nuclei that
invariably nucleate at the holes and
defects of the electrode substrate.
Subsequent growth of these nuclei at
the template yields the desired
surface morphology of the • Highly oriented pyrolitic gr
aphite (HOPG)
nanostructures, which can therefore
• Graphite surface
be synthesized by choosing the • Stainless-steel grain interi
appropriate surface of the electrode. or
• Carbon tape 6
Two Groups of Template
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