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Internal Combustion Engines-Ii: Diesel Engine Emissions
Internal Combustion Engines-Ii: Diesel Engine Emissions
Introduction
• All vehicles and combustion devices using
hydrocarbon and their derivatives as fuel
contribute to air pollution.
• The amount of emission from engines depend
upon their design, operating conditions , and the
characteristics of fuel.
• The vehicles primarily emit the harmful gases
(pollutants) like CO, unburned HCs, and NOx. In
addition the diesel vehicles also emit smoke
and particulate matter (PM).
Diesel Engine Emissions :
formation, effect of variables and their control
• HC contributed by
– Over lean fuel regions due to flame quenching
– Fuel entering towards end of
combustion ( poor mixing )
Diesel Engine Emissions :
formation, effect of variables and their control
O + N2 ↔ NO + N
N + O2 ↔ NO + O
N + OH ↔ NO + H
Diesel Engine Emissions :
formation, effect of variables and their control
NO Formation in CI Engines
NO Formation in CI Engines
• A fuel spray injected radially outward in swirling air
is shown schematically
Diesel Engine Emissions :
formation, effect of variables and their control
NO Formation in CI Engines
• Air entrained into spray and the spray gets
slow down and deflected in the direction of
swirl
NO Formation in CI Engines
• Large regions containing fuel vapour downstream
of the spray core and within it ignition takes place
in slightly leaner region where fuel has spent most
time within flammable limits
NO Formation in CI Engines
NO Formation in CI Engines
• As combustion proceeds the already burned
gases keep on mixing with cooler air and fuel
vapour changing its composition and
temperature.
NO Formation in CI
Engines Types of CI
Engines
• In naturally aspirated engines the contribution
of premixed combustion to NO formation is
more significant
NO Formation in CI Engines
• In modern turbocharged, high-pressure direct
injection engines with retarded injection
timing, more than half of NOx is produced after
peak pressure
Diesel Engine Emissions :
formation, effect of variables and their control
NO Formation in CI Engines
• In IDI (Indirect Injection ) engines combustion takes place in two
stages. In first stage a rich mixture burns in pre-chamber where all
the fuel is injected.
NO Formation in CI Engines
• In IDI engines combustion takes place in two
stages.
- In second stage most fuel burn as lean mixture
NO + H 2O
→ NO2 + H2 NO
+ O2 →
NO2 +
O
– Diffusion combustion :
Aromatics > Acetylene > Olefins > Parafins >
Alcohols
Diesel Engine Emissions :
formation, effect of variables and their control
Diesel Smoke
• Soot emissions from diesel engines are manifested
as a visible smoke
Diesel Smoke
• Smoke emission increase with load, longer
duration of diffusion combustion phase and
reduced oxygen concentration.
Diesel Smoke
Compression Ratio
- An increase in CR - shorter ignition
delay & higher comb. temp.
- tend to oxidize ubHC - lower HC
- and higher NOx.
- For lowest NOx & particulate opt. CR
required
I C ENGINES - II
Diesel Engine Emissions : effect of variables
-
I C ENGINES - II
Diesel Engine Emissions : effect of
variables
I C ENGINES - II
Diesel Engine Emissions : control technology
• Background
– Diesel emission regulations limit CO, HC, Nox, and
particulate matter (PM)
– Diesel Catalysts
• Oxidation Catalysts
• De-NOx Catalyst ;
– Nox Storage - Reduction (NSR)
Catalyst
– Urea - Selective Catalytic Reduction
(SCR)
Gasoline Two-Wheelers
CO g/km 2.0* 1.5* 1.0*
HC+Nox g/km 2.0* 1.5* 1.0 *
Gasoline Three-Wheelers
CO g/km 4.0* 2.25* 1.25*
HC+NOx g/km 2.0* 2.0* 1.25*
Diesel Two & Three-Wheelers
CO g/km 2.72 1.0 0.50
HC+NOx g/km 0.97 0.85 0.50
PM g/km 0.14 0.10 0.05
I: BASIC THEORY
II: FUEL INJECTION SYSTEM
III: AIR MOTION, COBUSTION &
COMBUSTION CHAMBERS
IV: SUPERCHARGING and TUBOCHARGING
V : EMISSION AND THEIR CONTROL
TECHNOLOGY VI : DIESEL FUEL
VII: DIESEL ENGINE TESTING & PERFORMAMCE