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D. Jim Livingston: Asst. Professor Department of Chemistry St. John's College
D. Jim Livingston: Asst. Professor Department of Chemistry St. John's College
Jim Livingston
Asst. Professor
Department of Chemistry
St. John’s College.
Nucleus
Electron
Orbit
Energy Levels
According to classical physics, light
should be emitted as the electron
circles the nucleus. A loss of energy
would cause the electron to be drawn
closer to the nucleus and eventually
spiral into it.
Hill, Petrucci, General Chemistry An Integrated Approach 2nd Edition, page 294
Postulates of the Bohr Atomic Model
Electrons revolve around the nucleus in a fixed circular path termed “orbits” or
“shells” or “energy level.”
Every orbit - certain amount of fixed energy.
Electrons will not loss or gain energy as long as they continue to revolve around the
nucleus in the fixed orbit
Postulates of the Bohr Atomic Model
Different energy levels are denoted by n=1 or n=2 or n=3 or K, L, M, N….. Shells
and so on. These are called as quantum numbers.
The electrons move from higer to lower energy level by releasing required energy.
However, when an electron gains energy it moves from lower to higher energy level.
Increasing energy
n=3 of orbits
e- n=2 e-
n=1 e-
e-
e-
e- e
-
e-
e-
e-
e-
A photon is emitted
with energy E = hf
http://en.wikipedia.org/wiki/Category:Chemistry
Distribution of Electrons in Orbits or Shells:
Electrons in N Shell : 2 x 42 = 32
Electrons in M shell 2 x 32 = 18
Electrons in K shell: 2 x 12 = 2
Failure to explain Zeeman Effect