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Lect. 8, 9, and 10, Heat
Lect. 8, 9, and 10, Heat
2019-2020
Heat is defined in physics as the transfer of thermal energy
across a well-defined boundary around a thermodynamic system.
It has been observed experimentally, that the decrease in
mechanical energy (kinetic plus potential) of an isolated system
was equal to the increase in internal energy of the system.
Therefore, internal energy U is treated as a form of energy that
can be transformed into mechanical energy and vice versa.
The internal energy includes kinetic and potential energy
associated with the random translational, rotational, and
vibrational motion of the particles that make up the system, and
any potential energy bonding the particles together.
The symbol Q is used to represent the amount of energy
transferred by heat between a system and its environment.
Heat Transfer
Heat transfer is the process of transfer of heat from
high temperature reservoir to low temperature
reservoir. In terms of the thermodynamic system,
heat transfer is the movement of heat across the
boundary of the system due to temperature
difference between the system and the surroundings.
The heat transfer can also take place within the
system due to temperature difference at various
points inside the system.
There are three modes of heat transfer between the
two bodies:
1.Conduction: The transfer of heat between two solid
bodies is called as conduction. It depends on the
difference in temperature of the hot and cold body.
Example of conduction heat transfer is two bodies at
different temperature kept in contact with each other.
Another example is heating one end of the metal like
copper; due to conduction heat transfer the other end of
the metal also gets heated.
2. Convection: The transfer of heat between the solid
surface and the liquid is called as convection heat
transfer. Let us considering a vessel of water being
heated, in this case heating of water due to transfer of
heat from the vessel is convection heat transfer.
3.Radiation: When two bodies are at different
temperatures and separated by distance, the heat transfer
between them is called as radiation heat transfer. In case
of the conduction and convection heat transfer there is a
media to transfer the heat, but in case of the radiation
heat transfer there is no media. The radiation heat
transfer occurs due to the electromagnetic waves that
exist in the atmosphere.
One of the most important examples of radiation heat
transfer is the heat of the sun coming on the earth
Fig. The three modes of heat transfer
SPECIFIC HEAT(c)
The historical definition of the calorie is the
amount of energy necessary to raise the
temperature of one gram of a specific
substance(water)by one degree. That amount is
4.186 J.
Raising the temperature of one kilogram of water
by 1°C requires 4 186 J of energy. The amount of
energy required to raise the temperature of one
kilogram of an arbitrary substance by 1°C varies
with the substance.
From the definition of specific heat, we can express the
energy Q needed to raise the temperature of a system of
mass m by ∆T as
The energy required to raise the temperature of 0.500 kg
of water by 3.00°C, for example, is Q = (0.500 kg) (4 186
J/kg . °C)(3.00°C) = 6.28 J.
when the temperature increases, ∆ T and Q are positive,
corresponding to energy flowing into the system. When
the temperature decreases, T and Q are negative, and
energy flows out of the system.
Latent heat (also known as latent energy, or as
Heat of Transformation) is energy released or
absorbed, by a body or a thermodynamic system,
during a constant-temperature process — usually a
first-order phase transition.
Latent heat can be understood as energy in hidden
form which is supplied or extracted to change the
state of a substance without changing its
temperature. Examples are latent heat of fusion
and latent heat of vaporization involved in phase
changes, i.e. a substance condensing or vaporizing
at a specified temperature and pressure
When a body is heated at constant temperature by
thermal radiation in a microwave field for
example, it may expand by an amount described
by its latent heat with respect to volume or latent
heat of expansion, or increase its pressure by an
amount described by its latent heat with respect to
pressure.
Two common forms of latent heat are latent heat
of fusion (melting) and latent heat of vaporization
(boiling). These names describe the direction of
energy flow when changing from one phase to the
next: from solid to liquid, and liquid to gas.
Specific latent heat
A specific latent heat (L) expresses the amount of
energy in the form of heat (Q) required to
completely effect a phase change of a unit of mass
(m), usually 1kg, of a substance as an intensive
property: