Professional Documents
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Biomethne and Biogas
Biomethne and Biogas
Sludge Biogas
Gas
Nutrient
Cycle
Cycle
&
3
Compost Piles
H
N
us
AEROBIC
um
H
Natural
Dead plants, 2
animals, manure CO
& 3
H
N
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Artificial
Sl
Air-tight digester
ANAEROBIC
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og
Bi
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Guts of Animals
Natural
at
Pe
Decay under water
History
• Anaerobic decay started …… “In the
beginning” One of the Earth’s oldest
processes.
• Louis Pasteur once discussed possibility of
methane production from manure.
• China, India, and Africa have used for a
long time
History cont.
• During WW II, fuel shortages in Germany
lead to methane production plants in rural
areas. Gas used as tractor fuel
• Previous digester projects in the U.S. for
animal waste control were not very
successful.
– Can’t ignore the system, need skills and time
– Incompatible systems applied to situation
History cont.
• “Cookie cutter” designs don’t work. Of 30
plug flow digesters built, 19 by one
designer, 90% failed to function.
• Incorrect sizing of equipment or
noncorrosion resistant pipes and fittings
• Inadequate training
• Insufficient financial returns on investment
Biology of Anaerobic Digestion
• Biological process
• Oxygen destroys bacterial activity
• Initially, oxygen in fresh batch is used up by
aerobic bacteria which produce CO2.
• Only after all oxygen is used up can digestion
begin.
• Different kinds of bacteria are prevalent at
different stages of digestion.
Biology cont.
• Bacteria feed off by-products of previous
group.
• Stage 1- Acid producing bacteria break fats,
proteins and most starches into simpler
compounds. They rapidly reproduce, are
tolerant of environmental changes, excrete
enzymes that work on volatile acids.
Importance of Volatile Acids
• Low molecular weight organic acids.
Important example is acetic acid (vinegar),
which is a by-product of all fat, starch, and
protein digestion. About 70% of methane
produced during fermentation comes from
acetic acid.
Methane Producing Bacteria
• Next step in digestion
• Convert volatile acids into methane gas.
• Reproduce slowly
• Sensitive to environmental changes
Digesters
• Vessels or ponds that hasten anaerobic
digestion process.
• Three main types
– 1. Covered Lagoons
– 2. Complete Mix Digester (Batch Load)
– 3. Plug Flow (Continuous Load)
Covered Lagoons
• Treats liquid manure with less than 2%
solids.
• Large volume, preferable >12 ft deep
• Covered
Complete Mix (Batch Load)
• Heated tanks above or below ground
• 3-10% solids
• Tank is filled and left alone until gas
production stops
Plug Flow (Continuous Load)
• Daily load added on one end which displaces
previous material.
• 11-13% solids
• Not suitable process for swine manure due to lack
of fiber
• Digestion occurs as progresses through vessel
with bubbles of gas formed along way.
• Near end, little gas produced.
• Residues begin to stratify.
Phase Useable Resource
GAS Biogas COMBUSTABLE GAS
FERTILIZER,
Scum INSULATOR
LIQUID
BIOLOGICALLY
Supernatant ACTIVE
Inorganic Solids
TRASH, DISCARD
What do you feed a digester?
• Slurry!
– A mixture of water, manure, plant material, or
vegetative matter
• Sludge- spent solids, volume reduced to
about 40% of raw volume
• Supernatant- spent liquids of original slurry.
Great fertilizer value.
• Scum- coarse, fibrous material, released from
raw manure, gas, and liquid. Removal is big
problem because it can inactivate digester in
large amounts.
pH and buffering
• Important for maintaining balance between
acid forming and methane forming bacteria.
• pH range for digesters is 7.5-8.5
• At start of digestion, pH may drop below 6
for a couple of weeks then rise over next
couple of months while volatile acids and
nitrogen compounds are digested. Ammonia
formed during this stage.
• Methane production starts at about pH 7.
• Mixture is well buffered at 7.5-8.5
• Small amounts of fresh slurry can be added
after pH 7.5
• Batch load (plug flow) digesters require
continuous feeding or else enzymes will build
up, organic solids become exhausted and
methane production ceases.
• pH 8-8.5 is sign of stable digestion
• Check pH with
– meter (most accurate)
– pH dip strips
– litmus paper (least accurate)
• blue paper--> red in acid 1-7
• red paper--> blue in base 7-14
Condition Reason Solution
3) toxic substances
Indigestible Digestible
Methane Producing
Bacteria
Only feces is figured in total for cow, horse, swine, sheep because of
difficulty in collecting urine too.
Carbon:Nitrogen (C:N) Ratio
• Bacteria utilize carbon in the form of
carbohydrates for energy and nitrogen in
the forms of ammonia, protein, nitrates, etc.
for cell structure. This is their food. Only
the form is different depending on slurry
(raw ingredients).
• C is used about 30 times faster than N
• Both C and N required for digestion.
• If the ratio was 15 times more carbon than
nitrogen, it would be written 15:1, 15/1, or
15.
• If the ratio is unbalanced, the process is
hindered.
• Tables showing C:N ratios vary because
– 1. Lab data is not the same as real-life. Some of
the C digested in lab can’t be digested by bugs.
– 2. Wide variation in plant development stages,
animal diet, confinement etc, so fluctuations in
C/N are common.
Nitrogen
• Forms in slurry
– TKN, NO3, NH3, protein
• Varies by age of plant or manure “ the lot or batch
is variable”
• Body excretes excess N in urine. Is urine included
in your sample?
• Fowl excrete urine and feces together
• Ruminant’s bacteria use much of the N in
digestion so fecal N is lowest of animals.
• Bacteria can use most forms of N so best
way to test and report is as Total N (% of
dry weight)
Carbon
• Exists in many forms but not all are
bacteria-usable.
• Lignin is unusable
• Best to test and report as non-lignin carbon
content
Approx. % and form of N found
in different kinds of manure
Organic
Organic Ammonia
NH3 Ammonia
Ammonia Organic
C:N Handout
Example C/N Ratio Calculation
• You want to compost 50 lbs horse manure and 50
lbs dry wheat straw. Will the C/N ratio be ok?
• First- from table find the C/N ratios for each and
the percent N by dry weight.
– Manure C:N is 25:1 and N% is 0.023
– Straw C:N is 150:1 and N% is 0.005
• Second- Multiply % N by weight of product
– 0.023 x 50 lbs = 1.15 lbs actual N in manure
– 0.005 x 50 lbs = 0.25 lbs actual N in straw
• Third- Multiply carbon value by lbs N in
problem
– 25 x 1.15 lbs = 28.75 for manure
– 150 x .25 lbs = 37.5 for straw
• Fourth- Add the carbon contribution from
the straw and manure into total pounds.
Repeat for the nitrogen. (see next page)
Manure Straw Total
Carbon 28.75 37.5 66.25 lbs
Nitrogen 1.2 .25 1.45 lbs
Biogas 4 (Digesters)
Design
• Two basic types
– 1. Continuous feed
• A) vertical mixing
• B) displacement
– 2. Batch feed – slug of material is left in until
no more gas is produced then more is added
Batch
• Good where raw material availability is
sporadic or limited to coarse plant materials
that don’t completely digest (high lignin).
This undigested material can be removed
when next batch is started.
• Require minimal daily attention.
• Much time and labor for loading and
unloading
Batch continued
• Gas production sporadic. If multiple units
hooked to common gas collector, lags can
be minimized.
Continuous Load general
characteristics
• “Feed” every day or so.
• Gas and sludge production continuous
• Best when raw material is uniform and
easily digestible. Feed examples include
algae, manure, seaweed, etc.
Continuous feed / vertical mixing
• Feed placed into vertical chambers and
slurry rises to top and overflows in the
single chamber design or can be shunted to
a second chamber for further digestion in
the double chamber design.
Outlet
Inlet
Inlet
Biogas 4 (Digesters)
Design
• Two basic types
– 1. Continuous feed
• A) vertical mixing
• B) displacement
– 2. Batch feed – slug of material is left in until
no more gas is produced then more is added
Batch
• Good where raw material availability is
sporadic or limited to coarse plant materials
that don’t completely digest (high lignin).
This undigested material can be removed
when next batch is started.
• Require minimal daily attention.
• Much time and labor for loading and
unloading
Batch continued
• Gas production sporadic. If multiple units
hooked to common gas collector, lags can
be minimized.
Continuous Load general
characteristics
• “Feed” every day or so.
• Gas and sludge production continuous
• Best when raw material is uniform and
easily digestible. Feed examples include
algae, manure, seaweed, etc.
Continuous feed / vertical mixing
• Feed placed into vertical chambers and
slurry rises to top and overflows in the
single chamber design or can be shunted to
a second chamber for further digestion in
the double chamber design.
Outlet
Inlet
Inlet
Producer Gas
History
Producer gas, also called wood gas, has
been available ever since production of
steel.
1884 suction gas engines started being
seen and were common by 1890
around England and Germany.
Principle of operation
Hot, combustible gasses from iron
smelting could be scrubbed of soot and
impurities then fed into engines for
additional work.
Germans (Nazi party) used producer
gas and other alternative fuels during
their quest for world dominance.
A drive in the Alps
1935 Nazi’s promoted a “national test
drive” to demonstrate practicality of
producer gas.
38 trucks weighing 5 and 13 tons were
equipped with P-gas from charcoal,
coal, lignite, wood and peat were tested
14,000 km
Alps drive results
Wood and charcoal worked well but not
so with coal.
The war machine was geared up to use
wood gas and ethanol for trucks so
scarce petroleum could be used for
aircraft and military vehicles.
Japanese used these fuels too.
Danish experiments
Tested wood gas and other fuels in
1940’s.
Measured success in tons of wood
consumed to drive a one ton truck for
one km (tons/km) instead of mpg.
Winner used 48 grams per ton/km Avg
100 g/ton/km
In other words, you could get 3 ton
miles per pound of wood. A 3 ton truck
could travel a mile on a pound of wood
(a six inch piece of 2x4)
Problems with wood gas
Carbon monoxide poisoning from leaks is not
healthy and seemed to be problem in Danish
experiments.
Somewhat quirky in operation with clogging
problems, safety regulations and handling
practices.
However, it was proven that a renewable
resource could replace fossil fuel!!!
Nuts and Bolts of P-gas
Operation
All engines run on gasses. Diesel and
gasoline are atomized prior to
combustion.
Solid wood must be partially combusted
without full oxygen present for
incineration. The resultant gas is carbon
monoxide C + ½O2 = CO
Temperatures for CO production are
about 400 deg. F for initiation of
process called dissociation. At 600
degrees 25% dissociation occurs with
complete dissociation of carbon dioxide
to carbon monoxide at 1000 degrees.
Success of process depends on feed’s
ability to react quickly, hearth
temperature for gassification, and
moisture content of feed.
This material is based upon work
supported by the National Science
Foundation under award DUE-0434405