Hasil penelitian

SYNTHESIS OF COMPOSITE S-TIO2/TI AS DEGRADATION

OF REACTIVE BLUE 160 ORGANIC COMPOUND BY
PHOTOELECTROCATALYSIS

Presented by :
NI PUTU ARI URANI
F1C1 14 084
SUPERVISIOR I: SUPERVISIOR II:
Drs. H. Muh. Zakir Muzakar, M.Si., Ph.D Prof. Dr. H. Muh. Nurdin, M.Sc

CHEMISTRY DEPARTMENT
FACULTY OF MATHEMATIC AND NATURAL SCIENCES
UNIVERSITAS HALU OLEO
KENDARI
2018
I. Introduction
A. Introduction

Blue HE
RD 160

utilization of textile dyes

Nugroho dan ikbal,
( Naimah et al., 2014) 2005)

The blue HE RD (reactive blue 160)
a molecular formula
C38H23Cl2N14Na5O18S5 with a relatif
molecular mass 1309,86 gram/mol.
Reactive dye 160 kinds of azo dye
color with carcinogenic nature and
is an organic dye with long chain so
difficult to be processed
(Dhanesvar et al., 2007)
A. Introduction

Non-Toxic

photoelectrocatalysis
High photocatalytic
activity

Photoelectrocatalysis is a method
photodegradation
that combines electrochemical
processes and photocatalytic High Chemical
Blue HE RD waste in
processes to improve the and Biological
Aquatic Environment
performance of photocatalysts Inertness
(Nurdin et al., 2009). Low Cost

Anh Tuan et al., 2008.

A. Introduction
TiO2 is a semiconductor material that is
preferred in many photochemical and
photoelectrochemical applications (Riyani
dkk., 2015).

Coprecipitation

Anodizing

Sonochemistry
This method can form a
nano tube structure on a
thin layer of titanium metal
Hydrotermal
(Nurdin dan Maulidyah,
2014).
A. Introduction
Doped

C Cr
S the dopied method is a
sulphure
peroses to includecompounds,
other Cu
is one of the chologenic
it can be used as dopant
atoms to modify which
TiO2 can decrease the energy of TiO2
F Nonmetal
Nonmetal Metal
Metal
capable of changing gapthetire in visible light rays so it can be
activated
electronic structure of using UV (Widiyandari et al.,
2012)
TiO2 so as to decrease Fe
N band gap energy (Effendi
B et al., 2012). Ni
A. Introduction

Weakness
(Fujishima dkk., 2008).
A. Introduction

Alternative Formation electricity

on electron region
( Rekombination)

Photoelectrocatalyst (Nurdin et al., 2009)


1. How to synthesize a sulphure-
doped TiO2/Ti composite?
2. How does the resultant
characterization of TiO2/Ti
composite doped Sulphure?
3. How does the electrode activity
test of the synthesis composite of
TiO2/Ti composite doped with
Sulphure (S) as a degradation of
Blue HE RD (Reactive blue 160)
organic compound by
photoelectrocatalysis?
B. Problems Statement
1. knowing the result of sulphure
doped TiO2 composite synthesis
2. Knowing the results of the
characterization of the Sulphure-
doped TiO2/Ti composite (S)
3. To know the electrode activity test
of the synthesis of TiO2/Ti
composite cmposite doped with
Sulphure (S) as a degradation of
Blue HE RD (Reactive blue 160)
organic compound by
photoelectrocatalysis.
C. The Purpose
1. Giving information on the results of
the doped TiO2/Ti composite with
Sulphure (S).
2. Giving information on the result of
the characterization of Sulphure (S)
TiO2/Ti composite composite.
3. Giving information on the success of
electrode activity test of the
synthesis of TiO2/Ti composites
doped with Sulphure (S) as a
degradation of Blue HE RD
(Reactive blue 160) organic
compound by photoelectrocatalysis.
D. The Benefits
III. Methods
A. Research Flow Chart
Titanium Plate
Preparation
Synthesis of TiO2/Ti film with anodizing
XRD
method
Doping Sulphure(S) with Sol Gel method SEM-
FTIR
and dipcoating EDX
Preparation of Sel
photoelectroktalisis cells

Performancs
test

Linear Sweep Voltammery Multi pulse Amperometry

(LSV) (MPA)
Spektrofotometer UV-
Visible
Result And Discussion
 A. TiO2 Thin Layer
Plate Ti Mechanism in anodizing process :

Ti → Ti4+ + 4e-

Ti4+ + 2O2- → TiO2

Layer TiO2/Ti

Ti(OH)4 → TiO2 + 2H2O

B. Doping S-TiO2 by Sol-Gel Method

TiO2/Ti
Film S-TiO2

Koloid
S-TiO2
Ti Plate

Film S-TiO2/Ti
C. Working Electrode S- TiO2 Characterization

1. X-Ray Diffraction (XRD)

XRD patterns of TiO2/Ti at Ti plate surface

2. FTIR (Fourier Trannsform Infra
Red)

Spektrum FTIR Fe-N-TiO2

3. Scanning Electron Microscopy
(SEM)

a b c d

SEM figure of Film TiO2 at 3000 times (A), 5000 times (B), , 10.
000 times (C), and 40.000 times magnification (D)
 
3. Scanning Electron Microscopy
(SEM)

A B C

SEM figure of Film S-TiO2 at 10.000 times (A) , 30.000 times

(A) and 50.000 times magnification (B)
 
3. Scanning Electron Microscopy -Energy
Dispensive Xray (SEM -EDX )

cps/eV
1.2

Unsure KeV Photocatalyst

1.0 composition (%)

0.8 Ti 0,4., 4,5 dan 4,9 51,44

0.6 S O 0,5 43,46

Ti
O S Ti

0.4 S 0,392 dan 2,05 5,11

0.2 Jumlah 100,00

0.0
2 4 6 8 10 12 14 16 18 20
keV
5. Photoelectrochemical Activity Test using
Linear Sweep Voltammetry (LSV)

A B

Voltammogram of TiO2/Ti electrode (A) and

S-TiO2/Ti electrode (B)
5. Determination of maximum wave lenght (λmax)
toward Reaktif Blue compound by using
Spectrophotometer UV-VIS

599,5 nm
566 nm
6. Degradation test toward Reaktif Blue
compound by using TiO2/Ti Electrode and S-
TiO2/Ti

B
aA

Grap. Degradation tets of Reaktif Blue compound on 0,5 ppm

consentration; (a) decreasing concentration curve, (b) % of Degradation
 B
A

Grap. Degradation tets of Reaktif Blue compound on 1 ppm consentration :

(a) decreasing concentration curve (b) % of degradation
 A B

Grap. Degradation tets of Reaktif Blue compound on 2 ppm consentration

(a) decreasing concentration curve, (b) % of degradation
 A
B

Grap. Degradation tets of Reaktif Blue compound on 3 ppm consentration :

(a) decreasing concentration curve, (b) % of degradation
V. CLOSING
A. Conclusion
1. Composite TiO2 on Ti plate surface can be obtained using anodizing method for 4 hours to obtain TiO 2 nano tube
layer. Then proceed with the synthesis of S-doped TiO 2 can be done using the sol-gel method by adding H 2SO4 as
a source of sulfur. S-TiO2 is formed by immobilization on Ti plate with dip coating method.
2. Anatase TiO2/Ti electrodes doped S were prepared through anodizing and Dip-coating methods in sol-gel
containing S. TiO2/Ti electrodes doped S experienced a decrease in band gap energy which indicated that
electrons were more easily excited from the valence band to the conduction band.
3. The performance of TiO2/Ti electrodes doped S as photoelectroacalytic degradation of Blue Reactive dyes better
than TiO2/Ti electrodes by photolysis and photocatalyst which can be obtained from% degradation of each
concentration. The degradation rate constant for TiO 2/Ti electrodes when light irradiated was 0.018 minutes-1 and
when UV light was irradiated at 0.043 minutes-1. While for S-TiO 2/Ti has a good activity in degrading reactive blue
dyes when irradiated by visible light, the value of the rate of degradation when irradiated by visible light is 0.033
minutes-1 and UV light is 0.057 minutes-1.

B. Saran
It is necessary to develop the use of metal and non-metal dopants on TiO2/Ti to
obtain more effective results for photoelectro-catalytic activity in degrading Reactive
Blue.
THANK YOU