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Electronic Excitation by UV/Vis Spectros
Electronic Excitation by UV/Vis Spectros
hv
energy
energy
}
= hv
Q: Where do these quantized energy levels come from?
A: The electronic configurations associated with bonding.
hv
H HH
H
H
C C
H max = 135 nm (a high energy transition)
n
The n to pi* transition is at even lower wavelengths but is not
as strong as pi to pi* transitions. It is said to be “forbidden.”
Example:
Acetone: nmax = 188 nm ; = 1860
nmax = 279 nm ; = 15
C C
135 nm
C C 165 nm
H
C O n183 nm weak
C O 150 nm
n188 nm
n279 nm weak
180 nm
C O
A
279 nm
Conjugated systems:
C C
LUMO
HOMO
O
O
max(Actual) = 474.