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WORKING AND APPLICATION FOR AR

DETERMINATION OF CHLORINE AND BROMINE


• For chlorine
Final graph
• Bromine

the bromine molecule may be composed of two 79Br atoms (mass 158 ), two 81Br atoms (mass
162 ) or the more probable combination of 79Br-81Br (mass 160 ). Fragmentation of Br2 to a
bromine cation then gives rise to equal sized ion peaks at 79 and 81 .

The ratio of peak heights expected for m/z


values of 158 : 160 : 162 would be 1:2:1

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