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Wilson Equation
f iV f i L
Pi S
Raoult’s Law yi P xi Pi S log10 K i log10 log10 Pi S log10 P
P
yi Pi S Critical Point
Ki Bi
xi P log10 Pri 1 Ai 0 Ai Bi Ai Bi
Tri 1
Tr=0.7 Bi
i log10 Pri Tri 0.7 1 log10 Pri Tri 0.7 Ai
0.7
B
log10 Pr A Bi
Tr log10 Pri Tri 0.7 1 i 1 i Ai
0 .7
1 i Ai
Ai
Ai
1 i Bi
1 i
0.7 0.42857 0.42857
Pi S
log10 K i log10 log10 Pi S log10 P
P 1 i 1 i . 1
log10 Pi S log10 PCi
0.42857 0.42857 Tri
Wilson Equation
Raoult’s Law
Pi S
log10 K i log10 log10 Pi S log10 P
P
1 i 1 i 1
log10 Pi S log10 PCi
0.42857 0.42857 Tri
1 i 1 i 1 log P
log10 K i log10 PCi 10
0 .42857 0 .42857 Tri
P T
log10 K i log10 Ci 2.3333411 i 1 Ci
P T
P T
ln K i ln Ci 5.37271 i 1 Ci
P T Wilson Equation
P T
Ki Ci exp 5.37271 i 1 Ci
P T
B C
log10 Pr A
Tr Tr2
Bi Ci 0 Ai Bi Ci (1)
Critical point log10 1 Ai
1 12
1 BiTci CiTci2
1 BT K C T K 2
log10 Ai 2 (2)
boiling point log10 Ai i ci i ci
2 Pci Tb Tb
Pci (atm) Tb ( K ) T (K )
b
Bi Ci
Tr=0.7 i log10 Pri Tri 0.7 1 1 i Ai
0.7 0.7 2 1 i Ai 1.428571Bi 2.040816Ci (3)
1 Tci2
log10 2 1
Pci T
1 Tci Tci2 Bi Ci b
log10 Bi 1 Ci 2 1 Tci Tci
Pci Tb Tb 1 1
T
b Tb
1 Tci2
log10
2 1
Pci Tb
2.33331 i Ci 2.428571
Tci Tci 1
1
Tb Tb
1
log10
Pci
2.3333 1 i
Tci
1
T
Ci b 2 Bi 2.428571Ci 2.3333 1 i Ai Bi Ci
Tci
2 1
Tb 2.428571
Tci 1
Tb
Twu Method
yi Pi S
Ki
xi P
Pi S Pci exp ln Pri 0 Tri i ln Pri 1 Tri
ln Pri 0 Tri
1
Tri
5.963461 Tri 1.176391 Tri 0.559607 1 Tri 1.319011 Tri
1.5 3 6
ln Pri 1 Tri
1
Tri
4.78522 1 Tri 0.413999 1 Tri 8.912391 Tri 4.986621 Tri
1.5 3 6
Ki
Pci
P
exp ln Pri 0 Tri i ln Pri 1 Tri
* “A generalized vapor pressure equation for heavy hydrocarbons,” Chorng H. Twu , John E. Coon, John R. Cunningham, Fluid Phase Equilibria, 96 ( 1994) 19-31
Twu et al. (1994) Generalized Vapor Pressure Equation
ln Pr ln Pr 0 Tr ln Pr 1 Tr
ln Pr 0 Tr
1
Tr
5.963461 Tr 1.176391 Tr 0.5596071 Tr 1.319011 Tr
1.5 3 6
ln Pr 1 Tr
1
Tr
4.785221 Tr 0.4139991 Tr 8.912391 Tr 4.986621 Tr
1.5 3 6
Constants determined from DIPPR vapor pressure equations for . The equations were used to
calculate the slope (1) and constants (1) of many substances at 36 different temperatures
between a reduced temperature of 0.7 and 1.
* “A generalized vapor pressure equation for heavy hydrocarbons,” Chorng H. Twu , John E. Coon, John R. Cunningham, Fluid Phase Equilibria, 96 ( 1994) 19-31