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    Anation Reactions

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    Zee Shan
    Anation reactions involve the removal of water molecules from an aquo-complex by some anions. For example, [M(H2O)]n + X- → [M(X)]n-1 + H2O. The reaction occurs in two steps - in the first slow step the water ligand leaves the complex, and in the fast second step the anion binds to the metal. The rate of anation depends on the concentration of the complex and the charge density of the metal, with higher charge density metals having stronger bonds to water and slower reaction rates. Anation is the reverse of acid hydrolysis, where an anionic ligand is displaced by water.

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    Anation Reactions

    Uploaded by

    Zee Shan
    3K views10 pages
    Anation reactions involve the removal of water molecules from an aquo-complex by some anions. For example, [M(H2O)]n + X- → [M(X)]n-1 + H2O. The reaction occurs in two steps - in the first slow step the water ligand leaves the complex, and in the fast second step the anion binds to the metal. The rate of anation depends on the concentration of the complex and the charge density of the metal, with higher charge density metals having stronger bonds to water and slower reaction rates. Anation is the reverse of acid hydrolysis, where an anionic ligand is displaced by water.

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    Anation reactions involve the removal of water molecules from an aquo-complex by some anions. For example, [M(H2O)]n + X- → [M(X)]n-1 + H2O. The reaction occurs in two steps - in the first slow step the water ligand leaves the complex, and in the fast second step the anion binds to the metal. The rate of anation depends on the concentration of the complex and the charge density of the metal, with higher charge density metals having stronger bonds to water and slower reaction rates. Anation is the reverse of acid hydrolysis, where an anionic ligand is displaced by water.

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    © All Rights Reserved
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    3K views10 pages

    Anation Reactions

    Uploaded by

    Zee Shan
    Anation reactions involve the removal of water molecules from an aquo-complex by some anions. For example, [M(H2O)]n + X- → [M(X)]n-1 + H2O. The reaction occurs in two steps - in the first slow step the water ligand leaves the complex, and in the fast second step the anion binds to the metal. The rate of anation depends on the concentration of the complex and the charge density of the metal, with higher charge density metals having stronger bonds to water and slower reaction rates. Anation is the reverse of acid hydrolysis, where an anionic ligand is displaced by water.

    Copyright:

    © All Rights Reserved
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    Anation Reactions


    Contents

     Anation Reaction
     Examples
     Mechanism
     Conclusion
    Anation Reactions

     Anation Reactions are those reactions in which water
    molecules from an aquo-complex are removed by
    some anions.
     The reverse reaction, displacement of an anionic ligand by
    water, is called aquation (acid hydrolysis).

    Let us discuss a general reaction
    [M(H2O)]n + X-  [M(X)]n-1 + H2O
    &
    [Co(NH3)5(H2O)]3+ + Br− → [Co(NH3)5Br]2+ + H2O
    Mechanism

     The Reaction is S 1 Reaction.
    N

     It Comprises of Two Steps.(Slow & Fast)


    Explanation:
    [Co(CN)5(H20)]2- + E- ------->[Co(CN)5(E)]3- +H20
    1st & Slow Step
    [Co(CN)5(H20)]2- -------->[Co(CN)5]2- + H20
    2nd & Fast
    [Co(CN)5]2- + E- ------>[Co(CN)5(E)]3-

    Effect of metals charge density

     Charge density=Charge on metal/radius of metal
    (higher the charge density of central metal more
    stronger will be its bond with H2O and slower will be
    the reaction rate
    Cs+ >Rb+>K+>Na+>Li+
    Conclusion

     Since reaction takes place in more than one step so there
    is slow step and rate of reaction depends on slow step
    which is called rate determining step.
     So
     Rate=K[Complex]
     In this way rate only depends on concentration of
    complex.
     It is the reverse of Acid Hydrolysis.
     . Some of the substitutions reactions occur without
    breaking metal-legand bond.

     What is the basic difference between aquation and
    Anation reaction?
     (hint: acid hydrolysis)
     role of water, leavening and entering ligands, Type of
    mechanism,
    Th
    ank
    Yo
    u

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