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  • Practica 12

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    ADILEN Villa. Flores
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    1) The document calculates the molarity and Ka of acetic acid (CH3COOH) using given mass, molar mass, and volume information. 2) It determines the concentration of hydronium (H3O+) ions produced from the dissociation of acetic acid in water using the Ka expression and molarity. 3) Similar calculations are shown for ammonia (NH3) and benzoic acid (C6H5COOH) determining molarity, Ka expressions, and concentrations.

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    Original Title

    PRACTICA 12

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    1) The document calculates the molarity and Ka of acetic acid (CH3COOH) using given mass, molar mass, and volume information. 2) It determines the concentration of hydronium (H3O+) ions produced from the dissociation of acetic acid in water using the Ka expression and molarity. 3) Similar calculations are shown for ammonia (NH3) and benzoic acid (C6H5COOH) determining molarity, Ka expressions, and concentrations.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pptx, pdf, or txt
    17 views6 pages

    Practica 12

    Uploaded by

    ADILEN Villa. Flores
    1) The document calculates the molarity and Ka of acetic acid (CH3COOH) using given mass, molar mass, and volume information. 2) It determines the concentration of hydronium (H3O+) ions produced from the dissociation of acetic acid in water using the Ka expression and molarity. 3) Similar calculations are shown for ammonia (NH3) and benzoic acid (C6H5COOH) determining molarity, Ka expressions, and concentrations.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    Download as pptx, pdf, or txt
    of 6

     

    𝑔𝑟𝑎𝑚𝑜𝑠 𝑑𝑒 𝑠𝑜𝑙𝑢𝑡𝑜
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =  CH3COOH + H2O CH3COO + H3O
    𝑝𝑒𝑠𝑜 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑥 𝑣𝑜𝑙𝑢𝑚𝑒𝑛( 𝐿)
    0,0124
      −𝑥 𝑥  𝑥 
      0,2219
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    60,05 𝑥 0,295
    𝐾  𝑎 =[ 𝐶𝐻 3𝐶𝑂 𝑂−] ¿¿
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑
      =0,0124 ( 𝑥)( 𝑥)
    1  ,8 𝑥 10 =
    −5
    0,0124 − 𝑥

     𝐶 𝑎 ≥ 1000 𝑥2 −5 −7
      +1 , 8 𝑥 10 𝑥 − 2,232 𝑥 10 = 0
    𝐾𝑎

      0 , 0124 ≥1000 𝑥 −4 𝑥  2 =− 4,63 𝑥 10−4


    1 , 8 𝑥 10
    −5   1 =4,55 𝑥 10

    688.8
      ≥1000
      𝑥 =¿
      𝑔𝑟𝑎𝑚𝑜𝑠 𝑑𝑒 𝑠𝑜𝑙𝑢𝑡𝑜
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =  NH3 + H2O NH4 + OH
    𝑝𝑒𝑠𝑜 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑥 𝑣𝑜𝑙𝑢𝑚𝑒𝑛( 𝐿)
    0,76
      −𝑥 𝑥  𝑥 
      1,89
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    17,03 𝑥 0 ,146   = [ 𝑁𝐻 4 ] [ 𝑂𝐻 ]
    𝐾 𝑎
    [𝑁 𝐻 3]
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑
      =0,76
    ( 𝑥)( 𝑥)
    1  ,8 𝑥 10 =
    −5
    0,76 − 𝑥
     𝐶 𝑎 ≥ 1000 𝑥  2 =1.8 𝑥 10−5 ( 0,76 )
    𝐾𝑎
    −5 −3
      0 ,76 ≥1000   √ 1.8 𝑥 10 ( 0,76 )
    𝑥= 𝑥=
      [ 𝑂𝐻 ] =3.69 𝑥 10
    1 , 8 𝑥 10− 5
    [ 𝐻 3 𝑂 ] [ 𝑂𝐻 ] =10−14
    42222,2
      ≥1000 −14 [ 𝐻 3 𝑂 ] =2.71 𝑥 10− 12
    10
    𝑆𝑖 [ 𝐻 3 𝑂 ] =
      𝑠𝑒 𝑑𝑒𝑠𝑝𝑟𝑒𝑐𝑖𝑎 3.69 𝑥 10
    −3
     NaOH + CH3COOH CH3COONa + H2O
       

    𝑅𝐿=𝐶𝐻
      3𝐶𝑂𝑂𝐻   4,5 mmol 𝑛=3,6
      𝑚𝑚𝑜𝑙 𝑛=3,6
      𝑚𝑚𝑜𝑙

    ¿  𝑚𝑜𝑙𝑒𝑠 sin 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎𝑟 =4,5− 3,6=0,9


    100
      % −

      𝑚𝑜𝑙𝑒𝑠  𝑁𝑎𝑂𝐻 →𝑁𝑎 +¿ +𝑂𝐻 ¿


    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    𝑣𝑜𝑙𝑢𝑚𝑒𝑛 𝑀  𝑀  0,06
      𝑀
      4,5
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 = [ 𝐻 3 𝑂 ] [ 𝑂𝐻 ] =10−14
    75
    −14
    10
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑
      =0,06 𝑀 [ 𝐻 3 𝑂 ] = [ 𝐻 3 𝑂 ] =1,66 𝑥 10 −13
    0,06
     
    NH3 + H2O + HCl NH4Cl +H2O
       

    𝑅𝐿=𝑁𝐻
      3   5 mmol 𝑛=6
      𝑚𝑚𝑜𝑙 𝑛=5
      𝑚𝑚𝑜𝑙

    ¿  𝑚𝑜𝑙𝑒𝑠 sin 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎𝑟 =6 − 5=1 𝑚𝑚𝑜𝑙


     NH4 +H20 NH3- +H3O+
    𝑚𝑜𝑙𝑒𝑠

    ¿
     
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =  
    𝑣𝑜𝑙𝑢𝑚𝑒𝑛

      5
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    45

    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑
      =0,1 𝑀
     

    ¿   ¿
     
    C6H5COOH + H2O C6H5COO- + H3O+
      𝐺𝑟𝑎𝑚𝑜𝑠 𝑑𝑒 𝑠𝑜𝑙𝑢𝑡𝑜 0,0099
      −𝑥 𝑥  𝑥 
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    𝑃𝑒𝑠𝑜 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑥 𝑣𝑜𝑙𝑢𝑚𝑒𝑛

     
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    1,22 𝑔𝑟𝑎𝑚𝑜𝑠 𝐾  𝑎 =[ 𝐶 6 𝐻 5𝐶𝑂𝑂− ] ¿¿
    122,12 𝑥 1 𝐿
    ( 𝑥)( 𝑥)
    6  , 30 𝑥 10−5 =
    1,22 𝑔𝑟𝑎𝑚𝑜𝑠 0,0099− 𝑥
     
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    122,12 𝑥 1 𝐿 𝑥  2 +6 , 30 𝑥 10− 5 − 6,24 𝑥 10−7 =0
     𝐶 𝑎 ≥ 1000
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑
      =0,0099 𝑀 𝐾𝑎 −4 𝑥  2 =−8,22 𝑥 10− 4
    𝑥
      1 =7,59 𝑥 10
      0 ,0099 ≥ 1000
    −5
    6 ,30 𝑥 10
      𝑥 =¿
    157.14
      ≥1000
     
    CH3COOH + H2O CH3COO- + H3O+
    𝑥  −1,0 𝑥 10 −4 1,0 −4 1,0
      𝑥 10
    −4
      𝑥 10
    𝐺𝑟𝑎𝑚𝑜𝑠 𝑑𝑒 𝑠𝑜𝑙𝑢𝑡𝑜
     
    𝑀𝑜𝑙𝑎𝑟𝑖𝑑𝑎𝑑 =
    𝑃𝑒𝑠𝑜 𝑚𝑜𝑙𝑒𝑐𝑢𝑙𝑎𝑟 𝑥 𝑣𝑜𝑙𝑢𝑚𝑒𝑛 𝐾  𝑎 =[ 𝐶𝐻 3𝐶𝑂 𝑂−] ¿¿
      𝑥 10− 4= 𝐺𝑟𝑎𝑚𝑜𝑠 𝑑𝑒 𝐶𝐻 3 𝐶𝑂𝑂𝐻
    −4 −4
    6,5  1 ,8 𝑥 10 −5= (1,0 𝑥 10 )(1,0 𝑥 10 )
    60,05 𝑥 1 𝐿 𝑥 − 1,0 𝑥 10
    −4

    −5 −9 −8
    1
      ,8 𝑥 10 𝑥 −1,8 𝑥 10 =1,0 𝑥 10
    𝑃𝑒𝑠𝑜
      𝑑𝑒 𝐶𝐻 3𝐶𝑂𝑂𝐻 =0,039 𝑔 −8 −9
     𝑥= 1,0 𝑥 10 +1,8 𝑥 10
    −5
    1, 8 𝑥 10

      M CH3COOH

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