Rate Processes: MSE 202 IIT Kanpur

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MSE 202 IIT Kanpur

Rate Processes
Instructor: Dr. Shobit Omar

Materials Science & Engineering Department

Venue: Online Video


Date: Week 5, Lecture 15
MSE 202 Radiation Law IIT Kanpur
The spectral emissive power of a black body is given by

Planck’s Radiation Law

This law governs the intensity of radiation emitted by unit surface area
into a fixed direction from the blackbody as a function of wavelength for
a fixed temperature

The maximum emissive power at a given temperature is the black body


emissive power

Stefan- Boltzmann Law

Stefan-Boltzmann constant
5.67 X 10-8 W/m2K4
Rate Processes Week 5 Lecture 15
MSE 202 Total Energy Emitted by a Body IIT Kanpur

A =surface area
ε = Emissivity

Remember

Emissivity is a material’s property , ranging from 0 to 1, which measures how


much energy a surface can emit with respect to an ideal emitter at the same
temperature

Surface for which emissivity is


independent of wavelength is
called “gray surface”

Rate Processes Week 5 Lecture 15


MSE 202 Black & Gray Bodies IIT Kanpur
• A black body is an ideal emitter
• At a defined temperature, black body has the highest monochromatic
emissive power at all wavelengths

Black Body
– absorptivity = α =1
– emissivity = ε =1
– ideal emissive power = Eλ,b

Gray Body
– absorptivity < 1
– emissivity < 1
– emissive power < Eb

Rate Processes Week 5 Lecture 15


MSE 202 Kirchoff’s Law IIT Kanpur
At thermal equilibrium, the power radiated by an object must be equal to the
power absorbed.
Black body
Heat given to the surrounding =

In order to maintain thermal equilibrium,


rate of heat flow should be zero

• Gray body will also reflect the incident radiation


• True for Gray bodies where α and ε are independent of λ

Rate Processes Week 5 Lecture 15


MSE 202 Intensity IIT Kanpur
Monochromatic spectral intensity =
= Rate at which radiant energy is emitted at λ in direction φ and θ per unit
area normal to φ and θ, per unit solid angle per unit wavelength dλ about λ

rsinθdφ

rdθ
θ


dA2 = r2sinθdφdθ

Rate Processes Week 5 Lecture 15


MSE 202 Radiation Exchange Between Surfaces IIT Kanpur
Assumption: Surfaces are diffused

dA2
R

A2
dA1

A1

Rate Processes Week 5 Lecture 15


MSE 202 Radiation Exchange Between Surfaces IIT Kanpur
Assumption: Surfaces are diffused

dA2
R

A2
dA1

A1

In terms of spectral emissive power, Remember:

Rate Processes Week 5 Lecture 15


MSE 202 Concept of View Factor IIT Kanpur
F12 = Fraction of energy emitted
by surface 1 is incident to
surface 2
F21 = Fraction of energy emitted
by surface 2 is incident to
surface 1

Reciprocity Relations

View factors can be determined by graph available in literature

Summation Rule

Rate Processes Week 5 Lecture 15


MSE 202 Concept of View Factor IIT Kanpur
For 3 surfaces For N surfaces

Number of view factors = N2

Reciprocity Relations Number of reciprocity relations =

Number of summation relations = N

Summation Rule
Number of view factors required =

Rate Processes Week 5 Lecture 15


MSE 202 Example IIT Kanpur

Two concentric shells Calculate the view factors for the heat
transfer for two concentric shells

A1
1
2

A2

Rate Processes Week 5 Lecture 15


MSE 202 Example IIT Kanpur

Two concentric shells Calculate the view factors for the heat
transfer for two concentric shells

A1
1 F11 =0
2
A1F12 = A2F21
A2
F12 + F11 = 1

F12 = 1

Rate Processes Week 5 Lecture 15


MSE 202 View Factor Algebra IIT Kanpur

Superposition Rule

The view factor from the surface to a composite surface is equal to the sum
of the view factors from the surface to the parts of the composite surface

Rate Processes Week 5 Lecture 15


MSE 202 View Factor Algebra IIT Kanpur
Symmetry Rule
Two or more surfaces that possess symmetry about a third surface then both
the surfaces will have identical view factors from that third surface

Example

Determine the view factor from the base of


the pyramid to each of it four sides.

Rate Processes Week 5 Lecture 15


MSE 202 View Factor IIT Kanpur

View factor between two aligned parallel rectangles of equal size.


Rate Processes Week 5 Lecture 15
MSE 202 View Factor IIT Kanpur

View factor between two perpendicular rectangles with common edge.


Rate Processes Week 5 Lecture 15
MSE 202 View Factor IIT Kanpur

View factor between two coaxial parallel disks.


Rate Processes Week 5 Lecture 15
MSE 202 View Factor IIT Kanpur

(1) (2)
View factor for two concentric cylinders of finite length (1) outer cylinder to inner
cylinder (2) outer cylinder to itself
Rate Processes Week 5 Lecture 15
MSE 202 Net Radiation Leaving IIT Kanpur
Diffuse-Gray Surface

Rate Processes Week 5 Lecture 15


MSE 202 Net Radiation Leaving IIT Kanpur
Diffuse-Gray Surface

Applying Kirchoff’s Law

Driving
Force

Rate Processes Week 5 Lecture 15


MSE 202 Circuit Analog IIT Kanpur

• Eb and J can be viewed


as potentials
• Heat transfer from
surface is flow
• Resistance can be
given as

Surface Radiation Resistance

Rate Processes Week 5 Lecture 15


MSE 202 Net Radiation Heat Transfer between IIT Kanpur
Any Two Diffuse-Gray Surfaces

dAi
dAj

Radiation that leaves the entire surface i and strikes surface j =

Radiation that leaves the entire surface j and strikes surface i =

Net Rate of heat flow,

Applying reciprocity relations, Driving


Force

Rate Processes Week 5 Lecture 15


MSE 202 Circuit Analog IIT Kanpur
Driving
Force

• Ji and Jj can be viewed as potentials


• Heat transfer from surface is flow
• Resistance can be given as

View Resistance

Rate Processes Week 5 Lecture 15


MSE 202 IIT Kanpur

Rate Processes
Instructor: Dr. Shobit Omar

Materials Science & Engineering Department

Venue: Online Video


Date: Week 5, Lecture 15

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