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CLASSROOM CASE

STUDIES: SAFETY OIL


Course: hydrocarbon process engineering
Members:
• Pamela Paucar Guarníz
• Santiago Verástegui
• Juan Hinostroza
• Jean Pierre Torres
Identification of products
• Products found in the storage and expedition terminal of Callao:

Biodiesel Heavy fuel oil Gasoline

• To identify the risks, we use the safety sheet (MSDS) for similar
products found in the Repsol refinery database
Identification of hazards and risks
BIODIESEL HEAVY FUEL OIL GASOLINE
Comercial Name Diesel B5 Petróleo Industrial 500 Gasolina 98BA
Flash point, °C 52 60 -46
- Extremely flammable liquids - At high temperatures, hydrogen - Extremely flammable liquids and
and vapors. sulfide vapors. vapors.
- Ingestion and aspiration - Ingestion and aspiration - Ingestion and aspiration
- Inhalation - Inhalation - Inhalation
Hazard - Skin contact - Skin contact - Skin contact
- Eyes contact - Eyes contact - Eyes contact

- Skin irritation and dermatitis. - Headache, dizziness, blurred vision, - Irritation of the respiratory tract,
- Eye irritation. fatigue and disturbances in the drowsiness and dizziness.
- Irritation in the throat and central nervous system. - Vomiting, diarrhea, dizziness, and
stomach. - Irritation of the upper respiratory intoxication
- Lung damage. tract. - Pulmonary edema
Risk - Irritation of the respiratory - Gastrointestinal imbalances. - Skin irritation and dermatitis
tract and alterations of the - Pulmonary damage - Eye irritation and conjunctivitis
central nervous system. - Skin irritation and dermatitis
- Chemical pneumonia - Eye irritation and conjunctivitis
Risks related to equipments
Diesel B5 Petroleo Industrial 500 Gasolina 98BA

Similarity: Risks of explosion and fires during the storage process, in this case, storage tanks.

• Environmental pollution • Gas contamination due • Poisoning of personnel


due to leaks in tanks. to contact of an by exposure to vapors
• Explosion due incompatible chemical when they react with
to increase of the substance, in this case, other substances.
pressure in the tank for strong oxidizing • Toxic gas due to
a pressure limiting valve substances. exposure of high
failure. • Fire due to lack of temperatures due to
• Fire due ventilation and a incomplete combustion.
to overexposure to high wrong area • Toxic gas due to contact
temperatures. classification. with strong sxidizing
• Boil over: due to substances.
overexposure of crude
oil  to high
temperatures.
North Peruvian pipeline

History
• 1972-1974 • 25 de enero 2016-Derrame en el
• 1977 kilometro 441 del oleoducto.
• 5 –febrero 2016- Derrame en el
• 854 Km kilometro 206 del oleoducto.
• 16 febrero 2016 Ministerio de Salud
declaro emergencia sanitaria.
• 25,26 junio 2016 Derrame
petrolero del oleoducto.

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