WELCOME TO

KNOWLEDGE SHARING SESSION -3

ADVANCED OXIDATION PROCESS
SYSTEMS
26th June,2020
Tajuddin Shaik
 COD FRACTIONS
Total COD

BIODEGRADABLE
NON BIOD COD
COD

Readily Bio D SLOWLY BIO D NON BIO D NON BIO

(SOLUBLE) (PARTICULATE) (SOLUBLE) PARTICULATE

PARTICULATE COLLOIDAL

VFA COMPLEX
TECHNOLOGY AVALIABLE FOR AOP
 TECHNOLOGY THAT ARE VIABLE
• Ozonation
• Chlorination
• Fentons
• Electro Coagulation
 CHLORINATION
• Chlorination for removal of COD can be by Gas
Chlorine, Sodium Hypo Chlorite, Calcium Hypo
Chlorite solution
• Chlorination is always done after secondary
clarifier and followed by ACF for removal of
chlorine
 How Chlorination Works
• Calcium Hypo Chlorite
• Ca(OCL)2 +2H2O HOCL +Ca(OH)2
• Sodium Hypo Chlorite
• NaOCL+ H2O HOCL + NaOH
• CL2 Gas
• CL2 +H2O HOCL + CL- + H +
• HOCL OCL- + H +
• OCL- -> CL - + O
 GENERAL ARRANGMENT
Dosing
System

Chlorine Filter
Secondary MGF+
Contact Feed
Clarifier ACF
Tank Tank
 OZONATION
• Ozonation is also polishing operation after
clarification or filter
• Post Ozonation UV is used to destroy the
excess Ozone in water
• UV is used in removal of excess ozone
 Ozonation Reactions
• O3 + OH- O2- + HO2*
• O3 + O2* O3*- + O2
• O3*- HO3*-
• HO3* OH* +O2
• * indicates radicals, this react indirectly and have
reaction rates constant higher than O3 itself

•
 GENERAL ARRANGMENT

Ozone
Dosing

Secondary Ozonation
Tank UV
Clarifier
 FENTONS REACTION
• Fentons is also used as polishing operation
• It uses H2O2 as oxidizer and Ferric salt as
catalyst
• Its produces sludge that needs clarification
depending upon load
 FENTONS REACTION
• Fe2+ + H2O2 3+ -
Fe + OH + OH*
• Fe + H2O2
3+ 2+ -
Fe + O2* +2H
+

• O2* + Fe3+ 2+
Fe + O2
 GENERAL ARRANGMENT
Fe2+ & Poly
Acid H2O2 Alkali Dosing
Dosing Dosing Dosing

Ph pH
Oxidation
Correction Correction Clarifier
Tank
Tank
 ELECTRO COAGULATION
• It is used as pre treatment operation
preferably before DAF
• Flocs from electro coagulation unit float due
to H2 gas produced as cathode
• It uses direct current
PROCESS
 REACTIONS
• At the Anode
• Ms Mqn+ + ne-
• 2H2O 4 H2 +O2 +4e-
• At Cathode
• Mqn+ + ne- Ms
• 2H2O 2e- H2 + OH-