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CDI6-FIRE-TECHNOLOGY-AND-ARSON-INVESTIGATION (Revised by Reyes F)
CDI6-FIRE-TECHNOLOGY-AND-ARSON-INVESTIGATION (Revised by Reyes F)
THE ELEMENTS OF FIRE
FIRE
a rapid, self-sustaining oxidation process accompanied by the evolution
of heat and light of varying intensity an active chemical reaction that
takes place between fuel, heat and oxygen in the form of light and
noticeable heat a chemical reaction; the rapid oxidation of a fuel
producing heat and light an oxidation taking place with a rate rapid
enough to produce heat and light
TECHNOLOGY
the branch of knowledge that deals with industrial arts and sciences
the application of such knowledge that is used to produce the material
necessity of society
ELEMENTS OF FIRE OR TRIANGLE OF FIRE
FUEL
anything that will burn when heated with sufficient oxygen
OXYGEN
aids in combustion; comes from the atmosphere we breath; the
atmosphere contains: 21% oxygen, 78% nitrogen and 1% impurities
HEAT
source of ignition
TRIANGLE OF FIRE
For many years, the fire triangle (oxygen, fuel and heat) was taught as
the components of fire. While this simple example is useful, it is NOT
technically correct.
TETRAHEDRON OF FIRE
a geometric representation of what is required for fire to exist, namely,
fuel, an oxidizing agent, heat, and an uninhibited chemical reaction
FIRE TETRAHEDRON
• Oxygen (oxidizing agent)
• Fuel
• Heat
• Self-sustained chemical reaction
Each component of the tetrahedron must be in place for combustion to
occur. Remove one of the four components and combustion will not
occur. If ignition has already occurred, the fire is extinguished when one
of the components is removed from the reaction.
OXYGEN (Oxidizing Agent)
a colorless, odorless gas and one of the compositions of air which is
approximately 21% percent by volume
Oxygen sources: Oxygen requirements:
1. 21% of normal oxygen 1. 12% no fire
2. 78% nitrogen 2. 14% flash point
3. 1% other gases 3. 21% fire point
FUEL
the material or substance being oxidized or burned in the combustion
process.
Fuel sources
1. Solid
- molecules are closely packed together
2. Liquid
- molecules are loosely packed
3. Gas
- molecules are free to move
HEAT
the energy component of the fire tetrahedron
when heat comes into contact with a fuel, the energy supports the
combustion reaction
heat energy is measured in units of Joules (J), however it can also be
measured in Calories (1 Calorie = 4.184 J) and BTU's (1 BTU = 1055 J)
TEMPERATURE
- a measure of the degree of molecular activity of a material compared
to a reference point
- a measure of the degree of molecular activity of a material compared
to a reference point
- measured in degrees Farenheit or degrees Celsius
º Cº F Response
37 98.6 Normal human oral/body temperature
44 111 Human skin begins to feel pain
48 118 Human skin receives a first degree burn injury
55 131 Human skin receives a second degree burn injury
62 140 A phase where burned human tissue becomes
numb
72 162 Human skin is instantly destroyed
100 212 Water boils and produces steam
140 284 Glass transition temperature of polycarbonate
230 446 Melting temperature of polycarbonate
250 482 Charring of natural cotton begins
300 572 Charring of modern protective clothing fabrics
begins
600 1112 Temperatures inside a post-flashover room
fire
Types of Energy (common sources of heat)
• Chemical Energy
• Electrical Energy
• Nuclear Energy
• Mechanical Energy
1. CHEMICAL ENERGY
the most common source of heat in combustion reactions
When any combustible is in contact with oxygen, oxidation occurs. The
reaction of this process results in the production of heat.
ex. Heat generated from burning match, self-heating (spontaneous
heating)
2. ELECTRICAL ENERGY
- can generate temperature high enough to ignite any combustible
material near the heated area
Examples:
• over current or overload
• arcing
• sparking
• static
• lightning
3. NUCLEAR ENERGY
generated when atoms either split apart (fission) or combine (fusion)
Ex.
1. fission heats water to drive steam turbines and produce electricity
2. solar energy is a product of a fusion reaction
4. MECHANICAL ENERGY
an energy created by friction and compression
Heat of friction - the movement of two surfaces against each other,
thus producing sparks
Heat of compression - heat is generated when a gas is compressed in a
container or cylinder
SELF-SUSTAINED CHEMICAL REACTION
a) Water
b) Water Spray
c) Water Mist (Dry Water Mist)
d) Dry Powder (Multi-Purpose)
e) Dry Powder (Special Powders)
f) Foam (AFFF)
g) Carbon Dioxide
h) Wet Chemical
i) Fire Blanket
j) Hose Reel
k) Fire Bucket
l) Water Extinguisher
m) Signal Red
Best For
Fires involving organic solid materials such as wood, cloth, paper,
plastics, coal etc.
Danger
Do not use on burning fat or oil or on electrical appliances.
How to Use
Point the jet at the base of the flames and keep it moving across the
area of the fire. Ensure that all areas of the fire are out.
How it Works
Water has a great cooling effect on the fuel’s surface and thereby
reduces the pyrolysis rate of the fuel.
Water Spray Extinguisher (Water with additive)
Water Extinguisher Signal Red
Best For
Fires involving organic solid materials such as wood, cloth, paper, plastics, coal etc. These
offer significantly improved firefighting capability compared to traditional jet type water
fire extinguishers. Available in 3 and 6 liters.
Danger
Do not use on burning fat or oil or on electrical appliances.
How to Use
Point the jet at the base of the flames and keep it moving across the area of the fire.
Ensure that all areas of the fire are out.
How it Works
Water has a great cooling effect on the fuel’s surface and thereby
reduces the pyrolysis rate of the fuel. Instead of a jet nozzle, a spray
nozzle is used, with a higher pressure, which creates a fine spray. This
allows for a given quantity of water to have a considerable increase in
the surface area presented to the fire. This makes extinguishing more
efficient by more rapid extraction of heat, the formation of steam etc.
They can also contain surfactants which help the water penetrate deep
into the burning material which increases the effectiveness of the
extinguisher.
Water Mist Extinguisher (‘Dry’ Water Mist)
Signal Red on a White Background
Best For
The first broad-spectrum extinguisher to tackle A, B, C rated risks as well as fats
and deep fat fryers (Class F). Models with a dielectric test to 35k Volts can be
safely used on electrical fires (up to 1000 Volt) if a safety distance of 1m is
adhered to, as their mist (de-ionized water) does not conduct electricity and the
extinguisher does not normally form puddles, which could conduct electricity.
The Ultra Fire water mist extinguishers also contain only de-ionized water which
cannot carry an electric current.
Danger
Water mist extinguishers are safe for discharge on all fire classifications bar Class
D blazes.
How to Use
Point the jet at the base of the flames and keep it moving across the area of the
fire. Ensure that all areas of the fire are out. The fire draws the microscopic water
particles into the fire.
How it Works
Water is turned into microscopic particles in the supersonic nozzle. The water
mist is drawn to the fire where it cools and suffocates the fire. The mist also
forms a safety barrier between user and fire, which keeps some of the heat back.
• Powder Extinguisher (Multi-Purpose)
• Dry Powder Extinguisher Blue
•
• Best For
• Can be used on fires involving organic solids, liquids such as grease, fats, oil, paint, petrol, etc , but
not on-chip or fat pan fires. Can also be used on gas fires.
•
• Danger
• Safe on live electrical equipment, although does not penetrate the spaces in equipment easily
and the fire may re-ignite. This type of extinguisher does not cool the fire very well and care should
be taken that the fire does not flare up again.
•
• The smoldering material in deep-seated fires such as upholstery or bedding can cause the fire
to start up again. Do not use on a domestic chip or fat pan fires. There is a danger of inhalation if
powder extinguishers are used within buildings. Due to this, and the potential for the powder to
impair vision, powder extinguishers are no longer recommended for use within enclosed spaces.
•
• How to Use
•
•Point the jet or discharge horn at the base of the flames and, with a rapid sweeping motion,
drive the fire towards the far edge until all the flames are out. If the extinguisher has a hand control,
wait until the air clears and if you can still see the flames, attack the fire again.
•
• How it Works
•Similarly, to almost all extinguishing agents the powder acts as a thermal ballast making the
flames too cool for the chemical reactions to continue. Some powders also provide a minor
chemical inhibition, although this effect is relatively weak. These powders thus provide rapid
knockdown of flame fronts, but may not keep the fire suppressed.
•
• Dry Powder Extinguisher (Special Powders)
• Extinguishers Blue
•
• Best For
•These specialist powder extinguishers are designed to tackle fires
involving combustible metals such as lithium, magnesium, sodium or
aluminum when in the form of swarf or powder.
• There are three special powders based on graphite, copper and sodium
chloride.
•
• Danger
•Do not allow water to come in contact with the burning metal and the
powder must be gently applied. Sodium Chloride is not recommended for
Lithium.
• How to Use
•The lance enables the user to tackle fires at a safe distance. The low-
velocity applicator reduces the energy of the jet allowing the powder to
gently smother the surface of the burning material thus avoiding scattering
the high-temperature particles and stimulating the formation of a crust. The
method of application is completely different from a standard extinguisher
and user training is required. They are not suitable for use on live electrical
fires.
•
• How it Works
•This extinguisher works by forming a crust which insulates the metal to
prevent access to other combustible material nearby and smothering the
fire to prevent oxygen from the atmosphere reacting with the metal
• Foam Extinguisher (AFFF)
• Fire Extinguishers Cream
•
• Best For
• Fires involving solids and burning liquids, such as paint and petrol but not suitable for chip or fat pan
fires. Safe on fires caused by electricity if tested to 35kV (dielectric test) and a 1m safety distance is
adhered to.
•
• Danger
• Do not use on-chip or fat pan fires.
•
• How to Use
• For fires involving solids, point the jet at the base of the flames and keep it moving across the area of
the fire. Ensure that all areas of the fire are out. For fires involving liquids, do not aim the jet straight
into the liquid. Where the liquid on fire is in a container, point the jet at the inside edge of the
container or on a nearby surface above the burning liquid. Allow the foam to build up and flow across
the liquid.
•
• How it Works
•They are mainly water based, with a foaming
agent so that the foam can float on top of the
burning liquid and break the interaction between
the flames and the fuel surface.
• Carbon Dioxide Extinguisher
• CO2 Fire Extinguishers Black
•
• Best For
• Live electrical equipment, although it allows re-ignition of hot plastics. Now
mainly used on large computer servers, although care has to be taken not to
asphyxiate people when using the extinguisher in small server rooms.
•
• Danger
• Do not use on-chip or fat pan fires, as it can carry burning fat out of the
container. This type of extinguisher does not cool the fire very well and you need
to ensure that the fire does not start up again. Fumes from CO2 extinguishers can
asphyxiate if used in confined spaces: ventilate the area as soon as the fire has
been controlled. Only use CO2 extinguishers with frost-free horns, as the hand
holding the horn can otherwise be frozen to the horn, as the gas gets very cold
during the discharge.
• How to Use
• The discharge horn should be directed at the base of
the flames and the jet kept moving across the area of the
fire.
•
• How it Works
• Carbon dioxide extinguishers work by suffocating the
fire. Carbon dioxide displaces oxygen in the air. However,
once discharged, the CO2 will dissipate quickly and allow
access for oxygen again, which can re-ignite the fire.
•
• Wet Chemical Extinguisher
• Canary Yellow
•
• Best For
•Wet chemical fire extinguishers are ideal for Class F fires, involving
cooking oils and fats, such as lard, olive oil, sunflower oil, maize oil, and
butter.
•
• Danger
•Check manufacturer’s instructions for suitability of use. These
extinguishers are usually not recommended for class B fires such as
petrol, although Gloria has produced a 3 ltr wet chemical extinguisher with
B rating.
•
• How to Use
•Apply the wet chemical using the extended applicator in slow circular movements, which gives
a gentle, yet highly effective application. Apply the fine spray onto the burning fat until the surface of
the burning cooking oil changes into a soapy-like substance which prevents re-ignition. The gentle
application helps to prevent burning oil splashing out of the container. Make sure that you empty the
entire content of the wet chemical extinguisher onto the oil/fat, as the fire can re-ignite otherwise.
•
• How it Works
• Most class F extinguishers contain a solution of potassium acetate, sometimes with some
potassium citrate or potassium bicarbonate. The extinguishers spray the agent out as a fine mist.
The mist acts to cool the flame front, while the potassium salts saponify the surface of the burning
cooking oil, producing a layer of foam over the surface. This solution thus provides a similar
blanketing effect to a foam extinguisher, but with a greater cooling effect. The saponification only
works on animal fats and vegetable oils so most class F extinguishers cannot be used for class B
fires. The misting also helps to prevent splashing the blazing oil.
•
•Tests have established that a 6-liter wet chemical fire extinguisher with a 75F rating can deal
with a fat fire of maximum 0.11 m2 surface area.
• Fire Blanket
. smothering
•Fire Blankets Fire blankets are made of fire-resistant materials. They are useful for
small pan fires or for wrapping around a person whose clothing is on fire. Fire
blankets conforming to British Standard BS EN 1869: 1997 are suitable for use in the
home. BS 7944: 1999 is the specification for specialist heavy duty industrial use. Fire
blankets should generally be disposed of after use.
•
• Best For
• Small pan fires where oil or fat has caught fire and clothing fires.
•
• Danger
•If the blanket does not completely cover the fire, it will not be able to extinguish the
fire.
• While kite marked fire blankets have been successfully tested on deep fat fryers, modern
frying fats are difficult to extinguish with a fire blanket. We, therefore, recommend wet
chemicals for deep fat fryers.
• How to Use
. •Place carefully over the fire. Keep your hands
shielded from the fire. Do not waft the fire towards
you.
•
• How it Works
•Smothers the fire and prevents oxygen getting
to the fire.
• Hose Reel
.• Best for
•
•Fires involving organic solid materials such as wood, cloth, paper, plastics, coal etc.
• Danger
•Do not use on burning fat or oil or on electrical appliances before the electric supply
has been isolated.
•
• How to Use
•Point the jet at the base of the flames and keep it moving across the area of the fire.
Ensure that all areas of the fire are out.
•
• How it Works
•Water has a great effect on cooling the fuel surfaces and thereby reducing the
pyrolysis rate of the fuel.
• Fire Buckets
. • Fire Buckets A simple bucket of water can be used on Class A type of fires
either to supplement a water extinguisher or as a first attack if an extinguisher is not
immediately available.
•
• It also can be filled with dry sand and used as an absorbing agent or to dam a
flow of flammable liquid. They do have serious disadvantages as they are often
misused, left empty or allowed to be used as a refuse container.
•
• Best For
• Wood, Cloth, Paper, Plastics, Coal (if filled with water). Spilled flammable liquids
(if filled with sand)
•
• Danger
• Do not use on burning fat or oil or on electrical appliances before the electric
supply has been isolated.
• How to Use
.• Throw at the base of the flames. Ensure that all areas of
the fire are out.
•
• How it Works
•Water has a great effect on cooling the fuel surfaces
and thereby reducing the pyrolysis rate of the fuel.
.
CHAPTER 4
FIREMAN LADDER
•
.•Pyromania
– is the uncontrollable impulse of a
person to burn anything without
motivation. Pyromaniacs usually do
not run away from the scene of the
crime, usually alone and feel satisfied
watching the flame
• Types of Pyromaniacs:
.1.Abnormal Youth – Epileptics, imbeciles and
morons may set fire without knowing the
seriousness of the act.
2.The Hero Type – a person may set fire on a
building, subsequently pretends to discover it
and turn in the alarm so that he will appear a
hero to the public. A person may burn a building
and endeavor to achieve spectacular rescue in
order to attract the attention of spectators.
3. Alcoholics and Drug Addicts – persons who
.subject themselves to intense artificial
stimulants such as narcotics sometimes
develop a strong urge toward incendiaries.
4. Sexual Deviates – some sex perverts
derive sexual stimulation from setting a fire
and watching the flame. Frequently, he is
chronic masturbator who stimulates and
enhances his sexual gratification by means of
arson.
•
.• Public Disturbance
• - an offender may resort to arson as a means of a
public disturbance because a fire attracts people and
destruction causes confusion that gives rise to
attendant problems that divert police attention.
•
• Vandalism
– is a general term denoting intentional burning to
destroy properties?
• In determining motive, a fire
.
investigator concentrates on three
major factors:
1.Points of origin of the fire
2.Modus operandi of the arsonist
3.Identify of persons who might benefits
from the fire.
•
• Incendiary Materials
. • -Materials used to start a fire; combustible fuels
•
1. Arson Chemicals (liquids) – are incendiary materials often used by
arsonists as accelerants. Possess excellent properties. Examples:
alcohol, benzene, petroleum ether, gasoline, kerosene, naptha,
turpentine.
2. Gases as acetylene, butane, CO, ethylene, hydrogen, natural gas,
propane, these are common gases resulting in fires from explosion.
These when mix with air possess excellent in ignition properties and when
present in an enclosed area can lead to explosion.
3. Solids as chlorates, perchlorates, chromates, bichromates, nitrates,
permanganates – are typical families of oxidizing agents which give off
oxygen on decomposition thus aiding in combustion.
• FIRE CODE OF THE PHILIPPINES
.
• Republic Act No. 9514
- Approved on December 19, 2008
- Repealed PD 1185
- known as the "Revised Fire Code of the
Philippines of 2008".
DEFINITION OF TERMS
• Abatement - Any act that would remove or neutralize a
fire hazard.
• Damper - A normally open device installed inside an air duct system which
automatically closes to restrict the passage of smoke or fire.
.
• Distillation - The process of first raising the temperature in
separate the more volatile from the less volatile parts and then
cooling and condensing the resulting vapor so as to produce a
nearly purified substance.
• Fire Lae - The portion of a roadway or public way that should be kept
opened and unobstructed at all times for the expedient operation of fire
fighting units
.
•Fire Protective And Fire Safety Device - Any device intended for the protection of buildings or
persons to include but not limited to built-in protection system such as sprinklers and other
automatic extinguishing system, detectors for heat, smoke and combustion products and other
warning system components, personal protective equipment such as fire blankets, helmets, fire
suits, gloves and other garments that may be put on or worn by persons to protect themselves
during fire.
•Fire Safety Constructions - Refers to design and installation of walls, barriers, doors, windows,
vents, means of egress, etc. integral to and incorporated into a building or structure in order to
minimize danger to life from fire, smoke, fumes or panic before the building is evacuated.
These features are also designed to achieve, among others, safe and rapid evacuation of
people through means of egress sealed from smoke or fire, the confinement of fire or smoke in
the room or floor of origin and delay their spread to other parts of the building by means of
smoke sealed and fire resistant doors, walls and floors. It shall also mean to include the
treatment of buildings components or contents with flame retardant chemicals.
.
• Flash Point - The minimum temperature at which any material gives off vapor in
sufficient concentration to form an ignitable mixture with air.
• Forcing -A process where a piece of metal is heated prior to changing its shape
or dimensions.
• Owner - The person who holds the legal right of possession or title to a
building or real property.
.
• Oxidizing Material - A material that readily yields oxygen in quantities
sufficient to stimulate or support combustion.
• The act of arson has been described as a stealthy, cowardly crime that, by
its very nature, leaves very little direct evidence as to the identity of the
arsonist. Many arsonists fail to cover their tracks adequately and may
therefore leave some type of evidence behind. For example, in much
commercial arson, the suspect leaves the paper trail that investigator can
follow. This includes financial records, inflated insurance coverage, little or
no inventory, and excessive debts. In an ideal situation, the arsonist will
either be convicted, through the use of well-documented motives and
opportunity, or might be willing to cooperate with authorities in identifying
accomplices, motives, and prior victims.
.THE PRELIMINARY INVESTIGATION
•The preliminary investigation of arson begins basically like many other
crimes, with a thorough examination of the crime scene. Arson does not
have been immediate corpus delecti. It is, therefore, the responsibility of the
investigator to prove that a specific fire did occur and that it was ignited
deliberately. To accomplish this, both direct and circumstantial evidence can
be used to show that the fire was ignited. Such evidence, however, may not
reveal the opportunity or motive of the fire setter. As with most crimes,
motive is important, but the key responsibility of the arson investigator it to
connect the suspect with the crime scene regardless of motive.
•Note: the first step in the arson investigation is to determine the origin of the
fire.
IDENTIFY THE POINT OF ORIGIN
.
• The first step in the investigation is to determine the fire’s point
of origin. This may be the most critical phase of the investigation,
which includes the ruling out of natural or accidental causes. The
materials used in the setting of the fire along with the type of
material being burned, may show a distinct burn pattern. Hence
it is important to identify the point at which the fire originated, for
it is here that most of the physical evidence can be located
indicating a fire of incendiary nature. The fire’s point of origin
may be determined in several ways. The questioning of
witnesses could reveal the necessary information. In addition, an
inspection of the ruins at the fire scene might reveal valuable
evidence.
SEARCH FOR FLAMMABLE LIQUIDS
.
• A search for liquid accelerants should be conducted at all
arson crime scenes. The identification of liquid accelerants
can generally be used to trace the fire’s point of origin
successfully. Detecting the odor of such accelerants may be
the investigator’s first clue. It is important, therefore, for
investigators to be timely in their arrival at the crime scene
because such odors dissipate quickly. One technique to detect
the presence of flammable liquids is to place suspected
residue in water and look for a thin film to float in the surface
of the water. The formation of this film is reasonable grounds
for suspecting that flammable liquids are present.
OBSERVE THE SPAN OF THE FIRE
.
• Determining the time span of the fire is also the paramount
importance. Although the majority of evidence collection is
conducted at the crime scene, much can be learned simply
by observing the fire. Specifically, physical characteristics of
the fire such as smoke, direction, flames, and distance of
travel are important. Immediately after the fire is
extinguished, samples of debris should be collected that
might have been the material used for starting the fire.
When the rubble is being cleaned up, investigators should
be present to observe any additional evidence that might be
uncovered.
.PHOTOGRAPH THE SCENE
•Who are you, and why were you present at the fire?
•What attracted your attention at the fire?