PHYSICAL CHEMISTRY

PHASE DIAGRAM
Outline materi diagram fasa 3 komponen

 Jenis-jenis diagram fasa

 Informasi yang diperoleh
 Aturan fasa
 Aturan Lever
Ternary liquid phase diagram
Typical Phase Diagram of Three-Component Systems

A-B miscible
A-C miscible
A-C miscible
A-B & B-C
B-C partially
partially
miscible
miscible

A-B, A-C &

B-C partially
miscible
 If the curves do
the two not join at the
components are plait points, the
very insoluble in diagram takes
each other the form of

the three
components are
very insoluble in P=3
each other
Ternary solid phase diagram
Graphical representation of a
three-component system at
constant T & p
Informasi yang diperoleh dari diagram
fasa terner

Plait Point, and it is

another example of a
critical point, where
the composition of the
two phases is equal

tie-line
 Determination of the Tie Lines

If the two layers s1′ and s1″ are

separated with a separatory
funnel

their composition can be

determined by titrating the
acetic acid they contain
with standard base

From the weight of the

layer titrated and the
weight of the acetic acid
it contains, the weight
fraction of acetic acid can
be calculated
Effect of temperature on ternary phase diagram
Effect of temperature on ternary phase diagram
 The Common Ion Effect

The presence of a
common ion tends P = 1, L
to decrease the
solubility of a salt

P=2 P=2

L+
L + (NH4)2SO4(s)
NH4Cl(s)

P=3 L + NH4Cl(s) + (NH4)2SO4(s)

 Aturan fasa

FF==CC––PP

FF==degree
degreeofoffreedom
freedom
CC==component
component
PP==phase
phase

komponen = … komponen = …
fasa =… fasa =…
F =… F =…
variabel = … variabel = …
Aturan Lever

W I R = W2 S
WI = fasa kaya benzena
(benzene-rich phase)
W2 = fasa kaya air
(water-rich phase)

R S
Ringkasan aturan Lever
Wkiri R = Wkanan S
𝑊𝑘𝑖𝑟𝑖 𝑆
=
𝑊𝑘𝑎𝑛𝑎𝑛 𝑅

R S
R S

R S
R S
R S
R S
R S
R S