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13 - Hukum Ke 3 Termodinamika - Masykuri
13 - Hukum Ke 3 Termodinamika - Masykuri
Physical Chemistry 1
Hukum ke-3
Termodinamika
Dr. Mohammad Masykuri, M.Si.
Chemistry Education Study Program
Teacher Training and Education Faculty
Sebelas Maret University (UNS)
Website: http://masykuri.staff.fkip.uns.ac.id,
Teacher email: mmasykuri@yahoo.com
12/14/21Training and Education Faculty 1
M. Masykuri_Physical Chemistry 1
Sebelas Maret University Solo, Peb 2020
Feb 2020
Entropi dan Hukum Ketiga
Pada volume
konstan
Pada
tekanan konstan
Compound So (J/mol-K)
SO3(s) 70.7
SO3(l) 113.8
SO3(g) 256.76
c lic k h e re
Pada reaksi:
aA + bB cC + dD
S 0 S produk
0
S reaktan
0
S 0 (cS C0 dS D0 ) (aS A0 bS B0 )
Contoh:
1 Tentukan So pada reaksi-reaksi berikut pada 25oC:
a. H2(g) + ½O2(g) H2O(l)
b. CH4(g) + ½O2(g) CH3OH(l)
Jawab :
1 0
a S 0
298 S 0
H2O (S 0
H2 S O2 )
2
= 69,92 – (130,57+ (1/2 x 205,3)
= -163,16 JK-1
A p p e n d ix C : T h e r m o d y n a m ic Q u a n titie s
fo r S e le c te d C o m p o u n d s a t 2 9 8 K
o
Com pound S (J /m o l-K )
H 2 O (l) 6 9 .9 3
H 2O 2(g ) 2 3 2 .9
H 2(g ) 1 3 0 .6
Problem set:
1. Calculate the standard free energy change (DG0)
associated with boiling water at 25oC and 1 atm
o o
Com pound H f (k J /m o l) S (J /m o l-K )
H 2 O (l) -2 8 5 .8 6 9 .9 3
H 2O (g ) -2 4 1 .8 1 8 8 .8