Thesis advance

Name: Pablo Andres Gonzalez Cortes

Jaunary 2022, The Netherlands

1
Synthesis of polymers
O
R-NH2

O
R
Synthesis and characterization of
modified Polyketones with different
amine derivatives at different
O
OH PK50PAMBA conversion degrees
N

Polyketone (PK50)
O
PK50BEA
N

O PK50HAMC
N

OH

N PK50HEXYL
Polymers for removal cations from
N
aqueous solution
N
PK50IM

2
 Rheology
106
5
T=Tg+85°C
10
G"bT (empty symbols) [Pa]

105
G'bT (filled symbols) [Pa]

PK50
HAMC80
Comparing the termal behaviour
HAMC80 (Creep) of the different modified
103 104

h* (stars) [Pas]
HAMC80 (Creep)
Hexyl80
PAMBA80
Polyketones and associated with
the interactions between the
103 chains
101
102
10-1
101

10-3 100
10-3 10-2 10-1 100 101 102 103 104
waT [rad/s]

3
Removal of Ca2+ and Mg2+ cations from water
80
70 PH4 25
PH4
PH5 PH5

Remanent concentration Ca2+ (mg/L)

Remanent concentration Ca2+ (mg/L)

70 PH4

Remanent concentration Ca2+ (mg/L)

60 PH6 PH6
PH7 20 PH7 60
50
50
40 15
40

30
10 30

20 20
5
10 10

0 0 0
PK50PAMBA20 PK50PAMBA50 PK50PAMBA80 PK50HAMC20 PK50HAMC50 PK50HAMC80 PK50IM20 PK50IM50 PK50IM80

Figure. Removal of calcium using the modified Polyketones with PAMBA, HAMC and IM. Initial
concentration of Ca2+ is 100 ppm.

4
 90 70
PH4
PH4 80
80 PH5 PH4
PH5 60
PH6
Remanent concentration of Mg2+

PH6 70

Remanent concentration Mg2+

70 PH7

Remanent concentration Mg2+

PH7 50
60
60

50 40 50

40 40
30

30 30
20
20 20
10
10 10

0 0 0
PK50PAMBA20 PK50PAMBA50 PK50PAMBA80 PK50HAMC20 PK50HAMC50 PK50HAMC80 PK50IM20 PK50IM50 PK50IM80

Figure. Removal of magnesium using the modified Polyketones with PAMBA, HAMC and IM.
Initial concentration of Mg2+ is 100 ppm.

5
Metal uptake of Ca2+ and Mg2+ in ratio
polymer:cation 1:1

Figure. Metal uptake of calcium and magnesium with the modified Polyketones in a ratio 1:1
polymer: cation (Ca,Mg).

6
 pH4 PK50HAMC20
100 PK50HAMC20 100
pH5,5 pH4
Remanent concentration Ca2+(mg/L)

pH7,0 pH5,5

Remanent concentration Mg2+

pH7,0
80 80

60 60

40 40

20 20

0 0
0 200 400 600 800 1000 1200 1400 0 200 400 600 800 1000 1200 1400
Time (min) Time

7
 40 40
PK50HAMC20 Mg
PK50HAMC20 Ca 4
35 35
5,5
7
30 30

25 25
4
q (mg/g)

q(mg/g)
20 5,5 20
7
15 15

10 10

5 5

0 0

-5 -5
0 200 400 600 800 1000 1200 1400 0 200 400 600 800 1000 1200 1400
Time (min) Time (min)

𝑞=
𝑉 ×(𝐶 0 − 𝐶 𝑓 ) 𝑚
𝑀 𝑔 [ ]
8
 110
PK50HAMC50 pH 4 PK50HAMC80 pH 4
100 100
pH 5,5

Remanent concentration Ca2+ (mg/mL)

pH 5,5
Remanent concentration Ca2+ (mg/L)

pH 7 pH 7
90
80
80

70
60
60

50 40

40
20
30

20
0
0 200 400 600 800 1000 1200 1400 1600 0 200 400 600 800 1000 1200 1400 1600
Time (min) Time (min)

9
Possible removal mechanism of the Ca and Mg ions

Increase pH

10
Thesis advances
Chapter Advance grade (%) Observation

Chapter 1 : Synthesis of 80 % -Finish DLS experiment

chemically modified polyketone
with HEXYL and HAMC
Chapter 2: 80% -Finish introduction
Study of hydrogen bonding and
pi-pi stacking interaction
between modified polyketone
Chapter 3:Removal of Ca2+ and 50% - Potentiometric titration of
Mg2+ from aqueous media modified polymers
- Finish the reaction 1:1
polymer:cation
- Finish kinetic experiment
Chapter 4: Develop of 40% - Mechanical properties (tensile
composites membranas using test, DMA)
the modified polyketones - SEM
- Leaching
11
12