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Base Oil for

Lubricants
- Manufacture & classification
Hussam Adeni
What are Lubricants

• Lubricants
• Special materials to
•Reduce friction
•Reduce wear
• In machine elements

Lube.specialist@gmail.com
What are lubricants

• Lubricants come in a variety of


forms
• Liquids – fluids
• Semi solids - grease
• Even solid, at times - graphite

Lube.specialist@gmail.com
What are lubricants

• Lubricants are
• Mineral Oils
• Vegetable oils
• Synthetic

Lube.specialist@gmail.com
What are Lubricants

• Lubricant comprise of
• Base oil or carrier fluid
• Specially formulated
additives

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Flow chart – Lube
manufacture

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What are lubricants

Finished lubricants
- a careful blend of
• Base Oils
• And additives

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Base Oil manufacture

Overview of the process


• A series of steps
• To improve desirable lube properties
• Viscosity Index
• Oxidation
• Heat resistance
• Low temperature fluidity

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Base oil manufacture

Starting with crude oil, typical process


of making lube oil consists of
•Separation
•Removal
•Distillation
•Dewaxing
•Finishing

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Base oil manufacture

• Crude oil distillation


- First the lighter ends removed
Motor spirit
Kerosene
Solvents
- Middle distillates separated
Lube base stocks

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Base Oil manufacture
- Flowchart

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Distillation – Top fraction

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Base oil manufacturing
process

• Middle distillates refined further


•Vacuum distillation
•Propane de asphalting
•Solvent refining
•Solvent dewaxing
•Treating
•Clay filtering

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Base oil manufacturing
process
• Lubes base stocks
- Vacuum distillation
Single stage
Multi stage
required for removal of “balance”
- lighter ends

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Base oil manufacture -
Flowchart

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Distillation – middle fraction

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Base oil manufacturing

• Lubes base stocks


- Dewaxing
- MEK – Toulene
- For Pour Point reduction

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Base oil manufacturing

• Hydrofinishing
- Reduction with hydrogen
- For removal of
Sulphur
Nitrogen
Oxygen
Improves heat & oxidation stability

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Base oil manufacturing

• De asphalting
- Reduction with propane
- For removal of
Asphaltic compounds

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Crude Oil composition

• Composition (weight %)
• Carbon 84%
• Hydrogen 14%
• Sulphur 1.5%
• Others (nitrogen, Oxygen,
Metals, salts) < 2%

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Yield – Base Oil
manufacturing process

• Yield in percentages
• Gasoline 44%
• Diesel 21%
• Kerosene /Jet Fuel 9%
• Others ( Coke , asphalt, residual
fuel oil) 25%
• Lube Oil base stock 1%

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Base Oils types

• Paraffinic 60%
• Naphthenic 28%
• Aromatic 12%

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Base Oil classification

• Pale Oils
• Lighter ends
• Neutrals
• Middle ends
• Bright stock
• Heavy ends

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Typical base oils

• Solvent neutrals
• SN 70
• SN 100
• SN 150
• SN 300
• SN 350
• SN 500
• SN 650
• SN 900

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Typical base oils

• Bright stock
• BS 150

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API classifications – Base Oils

• American Petroleum Institute (API)


• Group I, II, II+
• Mineral Oils

• Group III, IV, V


• Synthetic Oils

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API classifications – Base Oils

• American Petroleum Institute (API)


• Group I,
• Solvent Refined base stocks
• Mineral Oils
• Group II, II+,III
• Solvent refined and Hydro treated
• Group IV, V
• Synthetics
• Polymerized olefins from petrochemical source

Lube.specialist@gmail.com
API Base Oil –
Interchange Guidelines
Base Oil Sulphur Saturates Viscosity
category (%) (%) Index (VI)
Group I > 0.03 < 90 80 to 120
Group II < 0.03 > 90 80 to 120
Group III < 0.03 > 90 > 120
Group IV All polyalphaolefins (PAO)
Group V All others not included in
Group I, II, III or IV
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Typical cost of base oils

• From crude oils - Yield of Lube


stocks is 1%
• If crude price is “X”
• Lube base oil price = “2X”
• In short base oil costs can be upto
“twice” price of crude oil

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What is a lubricant

• Finished lubricants
- Careful blend of
• Base Oils
• additives

Lube.specialist@gmail.com
What is a lubricant

Finished lubricants
=
Base Oils
+
Additives

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What are additives

Lubricant additives
- classified on their
functional capability
1.Enhance existing property
2.Suppress undesirable property
3.Impart new property
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What are additives

1. Enhance existing property


• Anti oxidant
• Corrosion inhibitor
• Anti foam agent
• Demulsifying agent

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What are additives

2. Suppress undesirable base oil


property
• Pour Point depressant
• VI improver

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What are additives

3. Impart new property


• E P additive
• Anti wear agents
• Detergents
• Dispersants
• Metal deactivators
• Tackiness agents

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Base oils – Holly Lubricants &
Specialities Ltd

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Thank you

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