Progress Lab 10.01.2022

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Progress Lab

10/01/2022 TOPTAP
N-type Semiconductor
• Covalent bond
• Crystal Structure
• Electron more than hole
• Band gap
TiO2 phase
2 week ago
• Aj nick
• Over Dope TiO2 QDs in 0.2 M KCl : 0.1 M Citirc acid (0% 2.5% 7.5% 10%)
ETL
• TTIP 200ul in 2 ml ethanol (1:10)
• Pre spin 2000 rpm 3s spin 5000 rpm 30 s
• Annealing 500⁰C 1 hour
• TiO2 QDs 0.2 M KCl Dope in TTIP
• Pre spin 2000 rpm 3s spin 5000 rpm 30 s
• Annealing 500 ⁰C 1 hour
Perovskite
• PbI2 : MAI (1:1)
• PbI2 461 mg
• MAI 159 mg
• DMF:DMSO (4:1) 1ml
• DMF 800 ul
• DMSO 200 ul
• Stirring at 70 ⁰C Over night
• Spin 5000 rpm 30 s (anti-solvent after 15 s)
• Annealing 100 ⁰C 1 hour
Spiro-OMeTAD
• Spiro-OMeTAD 0.050 g in 700 uL CB
• Stir at room temperature over night
• Dope tBp 20.16 uL and Li-TFSI 12.25 uL
• Spin 4500 rpm 30 s
Complete Cells
1st TTIP
2nd 2.5% dope (44uL)
No DATA
3rd 7.5 % dope (150uL)
4th 10% dope (200uL)
Last week
• Compere 0% 2.5 % 5 % 7.5 %
ETL
• TTIP 200ul in 2 ml ethanol (1:10)
• Pre spin 2000 rpm 3s spin 5000 rpm 30 s
• Annealing 500⁰C 1 hour
• TiO2 QDs 0.2 M KCl Dope in TTIP
• Pre spin 2000 rpm 3s spin 5000 rpm 30 s
• Annealing 500 ⁰C 1 hour
Perovskite
• PbI2 : MAI (1:1)
• PbI2 461 mg (99.999%)
• MAI 111 mg
• FAI 53 mg
• DMF:DMSO (4:1) 1ml
• DMF 800 ul
• DMSO 200 ul
• Stirring at 70 ⁰C Over night
• Spin 5000 rpm 30 s (anti-solvent after 15 s)
• Annealing 100 ⁰C 1 hour
Spiro-OMeTAD
• Spiro-OMeTAD 0.050 g in 700 uL CB
• Stir at room temperature over night
• Dope tBp 20.16 uL and Li-TFSI 12.25 uL
• Spin 4500 rpm 30 s
Complete Cells
Dope 0 %
• No Data
Dope 2.5 %
Dope 5 %
Dope 7.5 %

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