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Symmetry and Point Groups: A. Symmetry Is Present in Nature and in Human Culture
Symmetry and Point Groups: A. Symmetry Is Present in Nature and in Human Culture
Symmetry and Point Groups: A. Symmetry Is Present in Nature and in Human Culture
I. Introduction
A. Symmetry is present in nature and in human culture
B. Using Symmetry in Chemistry
1. Understand what orbitals are used in bonding
2. Predict IR spectra or Interpret UV-Vis spectra
3. Predict optical activity of a molecul
C17 axis
3. (Reflection Operation) = exchange of points through a plane to an
opposite and equidistant point
a. Symmetry element is a plane
b. Human Body has an approximate operation
c. Linear objects have infinite ‘s
d. h = plane perpendicular to principle axis
e. v = plane includes the principle axis
f. d = plane includes the principle axis, but not the outer atoms
d
O C O O
H H
h v
4. i (Inversion Operation) = each point moves through a common central
point to a position opposite and equidistant
a. Symmetry element is a point
b. Sometimes difficult to see, sometimes not present when you think
you see it
c. Ethane has i, methane does not
d. Tetrahedra, triangles, pentagons do not have i
e. Squares, parallelograms, rectangular solids, octahedra do
5. Sn (Improper Rotation Operation) = rotation about 360/n axis followed by
reflection through a plane perpendicular to axis of rotation
a. Methane has 3 S4 operations (90 degree rotation, then reflection)
b. 2 Sn operations = Cn/2 (S24 = C2)
c. nSn = E, S2 = I, S1 =
d. Snowflake has S2, S3, S6 axes
C2 d
C. Examples:
1. H2O: E, C2, 2
O
H H
v
Cl Cl
H H
H C C
H H
H
4. Try Ex. 4-1, 4-2
III. Point Groups
A. Definitions:
1. Point Group = the set of symmetry operations for a molecule
2. Group Theory = mathematical treatment of the properties of the group
which can be used to find properties of the molecule
d. Associative property