Mass of CO2, SO2, NO, and H2O are calculated by mass balance as

CO2 = C*44/12
SO2 = S*64/32
H2O = H*18/2
 When calculating CO2 emissions from raw material chemistry, certain assumptions have to be
made. eg you can calculate the CO2 given off by the limestone component if you assume all of
the CaO comes from limestone. (some CO2 is also often associated with MgCO3 but let's
concentrate on the CaCO3 for now)
In your example above this calculation would become;- 48.51 * 44 / 56 = 38.11%
SiO2                9.4
However, if you look at your loss on ignition result you will see that it is significantly less than
Al2O3              3.56
this calculated figure... 35.26% compared to 38.11%
Fe2O3             1.48
Since all of the CO2 from the limestone would be evolved during the ignition test, this means
CaO                 48.51
that not all of the CaO in the raw meal comes from CaCO3. Therefore there may be calcium
MgO                0.62
silicates or other loss-free calcium compounds in your raw mix.
SO3                 0.04
Another explanation could be that the oxidation state of your iron component is lower than 3. 
Na2O              0.43
ie. some FeO is present. This would result in a slight gain on ignition  which would offset the
K2O                0.69
loss of CO2 from the CaCO3 and result in a lower than expected loss on ignition.
TiO2                0
So, you see there are several factors that make a simple CO2 emission calculation from raw-
P2O5               0
meal chemistry very complex indeed.
Mn2O3            0
In your case you need to quantitatively analyse the minerological content of your rawmeal so
P. Ign.              35.26
that you can determine the exact amounts of CaCO3, MgCO3 and the ratio of FeO/Fe2O3.
Cl-                   0
This is the only way you can more accurately calculate the CO2 emissions just  from the
rawmeal chemistry.
An easier and more accurate way would be to directly measure the amount of CO2 evolved
from a given amount of rawmeal using a Schrotter apparatus. (apparatus and methods can be
found on the web)
 Schrotter apparatus

Schrötter decomposition apparatus (Schrötter's alkalimeter) is used to determining the carbonate content in samples of
limestone, gypsum, dolomite, or baking powder by loss of weight. The apparatus is named after the Austrian chemist
Anton Schrötter von Kristelli (1802-1875), who devised it in 1871. The size of the filled apparatus (apparatus is 16 cm
high) is such that it weights less than 75 g, and can be placed on the pan of an analytical balance.

Procedure: Weigh about 0.5 g of the powdered carbonate sample and introduce
it into the decomposition flask C. Pour into the drying tube A 2-3 mL of
concentrated sulphuric acid (H2SO4), and to the dropping funnel B add about 10-
15 mL of hydrochloric acid (w(HCl) = 15 %). Weigh the whole apparatus. Open the
upper taps of both parts and allow the hydrochloric acid from B to run slowly
down on to the powdered sample. The evolved CO2 escapes through the strong
sulphuric acid and is thus thoroughly dried. When further addition of acid
produces no more evolution of CO2, warm the apparatus up to 80 °C so as to
expel the CO2 from the solution. Connect the upper tap of the drying tube A to a
water pump and draw a slow current of air through the apparatus until
completely cool. Open the upper taps for a moment to equalize the internal and
external pressure and weight the apparatus again. The weight loss is equal to the
weight of carbon dioxide liberated from the carbonates