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Energy and Chem Equilibrium
Energy and Chem Equilibrium
EQUILIBRIUM
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6.1 Energy
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6.1 Energy
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6.1 Energy
A. The Units of Energy
•A calorie (cal) is the amount of energy needed to
raise the temperature of 1 g of water by 1 oC.
1 cal = 4.184 J
1 kcal = 4.184 kJ
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6.2 Energy Changes in Reactions
•When molecules come together and react, bonds
are broken in the reactants and new bonds are
formed in the products.
H H H + H H = +104 kcal/mol
H + H H H H = −104 kcal/mol
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6.2 Energy Changes in Reactions
A. Bond Dissociation Energy
•The stronger the bond, the higher its bond
dissociation energy.
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6.2 Energy Changes in Reactions
B. Calculations Involving H Values
When H is negative:
•More energy is released in forming bonds than is
needed to break the bonds.
•The bonds formed in the products are stronger
than the bonds broken in the reactants.
ΔH = +678 kcal/mol
Heat is absorbed
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6.2 Energy Changes in Reactions
B. Calculations Involving H Values
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6.3 Energy Diagrams
For a reaction to occur, two molecules must collide
with enough kinetic energy to break bonds.
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6.3 Energy Diagrams
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6.3 Energy Diagrams
•The difference in energy between the reactants
and the products is the H.
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6.3 Energy Diagrams
•If H is positive, the reaction is endothermic:
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6.4 Reaction Rates
A. How Concentration and Temperature
Affect Reaction Rate
Increasing the concentration of the reactants:
aA + bB cC + dD
equilibrium [NO]2
= K =
constant [N2] [O2]
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6.5 Equilibrium
C. Calculating the Equilibrium Constant
HOW TO Calculate the Equilibrium Constant for a Reaction
A2 + B2 2 AB
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6.5 Equilibrium
C. Calculating the Equilibrium Constant
HOW TO Calculate the Equilibrium Constant for a Reaction
A2 + B2 2 AB
[AB]2
K =
[A2][B2]
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6.5 Equilibrium
C. Calculating the Equilibrium Constant
HOW TO Calculate the Equilibrium Constant for a Reaction
[AB]2 [0.50]2
K = =
[A2][B2] [0.25][0.25]
0.25
= = 4.0
0.0625
1) Concentration changes
2) Temperature changes
3) Pressure changes
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6.6 Le Châtelier’s Principle
A. Concentration Changes
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6.6 Le Châtelier’s Principle
C. Pressure Changes
•When pressure decreases, equilibrium shifts in the
direction that increases the number of moles in
order to increase pressure.
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6.6 Le Châtelier’s Principle
Summary
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What are photochromic
lenses?
• Photochromic lenses darken on exposure
to sunlight and protect the eyes from
ultraviolet radiation. Excessive exposure
can cause permanent damage to the
cornea and conjunctiva. Good
photochromic lenses block out 100% of
the most harmful rays of the sun, 100% of
the time, adapting to changes in light and
darkening in seconds.
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