DIETHYL THIO PHOSPHORIC ACID (DETA)

                 
  DETA RACTION:              
          NAME DENSITY PURITY  
      C2H50          
      I   C2H5OH 0.72 99.8 
                 
               
  P2S5+ 4C2H5OH => 2 SH- P=S +H2S        
      I   DETA 1.177 94.5 
      C2H5O          
M.W. 222 + 34 186 + 34 PHY.QTY    
                 
          DETA AS HEEL - 1200KG  
  NAOH +H2S => NASH + H2O   P2S5 (BULK) - 2100KG  
          C2H5OH - 1831KG  
M.W 32 + 34 56 + 18   TRI ETHYL AMINE- 05KG  
          (AS A CATALYST)    
M.B OF ETHANOL              
                 
BASIS OF P2S5 =(4*ETHNOL M.W/P2S5 M.W)*P2S5 PHYSICAL WT. =( 4*46/222)*2210=1831 KG
                 
                 
M.B OF DETA = (2*186.23/222)*2210 =3703KG          
                 
                 
M.B. OF H2S = (34/222)*2210=338KG          
                 
M.B. OF NAOH = (40/34)*338 =398KG AS PER 100 PERCENT BASIS      
SO AS PER 32 PERCENT BASIS =398/0.32=1244 KG OF NAOH      
                 
M.B. OF NASH = ( 56/34 )*338 /0.32=1739 KG NASH AS SUCH      

                 
 

PHORATE REACTION:

C2H5O OC2H5 S H H

I I II I I

SH-P=S +C2H5SH+ HCHO => P -- S -C=S-C2H5 + H2O

I I

C2H5O C2H5O

DETA + EM + FM => PHORATE + WATER

186.23 + 62 + 30 => 260 + 18

M.B. OF EM

BASIS AS PER DETA QUANTITY = ( M.W OF EM/DETA M,W) *PHY.QTY. OF DETA*DETA PURUTY* % EXCESS OF EM

SO EM QUANTITY 15% EXCESS=> (62/186.23)*3100*0.945*1.15=1158 KG OF EM

SO FM QUANTITY 7% EXCESS => ( M.W OF FM/FM PURITY) *(PHY.QTY. OF DETA/DETA M.W)*DETA PURUTY)* % EXCESS OF FM

SO FM QUANTITY 7% EXCESS=> (30/0.37)*3100/186.23*0.945*1.07=1364 KG OF FM

SO PHORATE QUANTITY => (M.W. OF PHORATE)* (PHY.QTY OF DETA/M.W OF DETA).DETA PURITY

SO PHORATE QUANTITY => ( 260 )*(3100/186.23)*.945 =>4089 KG AS 100%

SO PHORATE YIELD => (PHORATE PHY.QTY/ PHORATE M.W)* ( PHORATE PURITY)/(DETA PHY.QTY/DETA M.W). DETA PURITY

: (4089/260)*0.95/(3100/186.23)*0.945

SO PHORATE YIELD : 84.81%

          TERBUFOS            

                         

    TERBUFOS REACTON         PHYSICAL QTY. OF TERBUFOS  

                         

  OC2H5 S CH3 OC2H5 S H CH3   DETA -2400 KG      

    I II I   I II I I     WATER:2100KG      

                         

                         

    P-S + CH3 ---C---CH3 == > P-S-C=S-C--CH3 +H2O TBM QTY: 1041KG      

    I I   I I I     FM QTY. : 1036KG      

  OC2H5 SH   OC2H5 H CH3   TBF PH QTY :2951 KG      

                  AQ.QTY. :2983KG      

                         

  DETA + TBM =>> TERBUFOS + WATER        

                         

                         

M.W 186.23 90 280            

                         

  MATERIAL BALANCE:                  

                         

  MATERIAL BALANCE OF TBM:                

      :                

  BASIS AS PER DETA : (TBM M.W./DETA M.W.)*DETA PHY.WT.*DETA PURITY* 05% LESS OF TBM  

      : (90/186.23)*2400*0.945 *.95            

        :1041KG                

                         

  M.B. OF F.M. :(F.M. M.W/DETA M.W)/FM PURITY*DETA PHY.WT.DETA PURITY.05% EXCESS OF FM

      : (30/186.23)/0.37*2400*0.945*1.05          

      : 1036 KG                

                     

      FM QTY.= 84.58 * DETA MOLE (FM M.W./PURITY)*1.05 (5% EXCESS FM)    

      TBM QTY.=85.5 * DETA MOLE (TBM M.W.)*0.95(05% LESS TBM)      

                         

  M.B,. OF TERBUPHOS :(M.W OF TBF/DETA M.W)*DETA PHY QTY.*DETA PURITY      

      : (280/186.23)*2400*0.945            

      : 3403 KG AS 100 % STOICHIO MATRIC CALULATION      

      : BUT ACTUAL TBF PURITY 86% SO PHY. QTY :2927 KG      

                         

                         

  TERBUFOS YIELD : (TERBUFOS PHY QTY/TBF M.W)*TBF PURITY /( DETA PHY. QTY/DETA M.W.)*DETA PURITY
NAME M.W, DENSITY PURITY
EM 62 0.8410 0
FM 30 1.1137

PHORATE 260 1.1593TO 95

TBM 90 0.8100

TERBUFOS 280 1.1584 TO 86

NaSH 561.22-1.24 30-32%
NaSH Cp   0.59 KJ/KG/C

PHYSICAL QTY OF PHORATE REACTION

DETA - 3100KG      

WATER-1200KG      

FM (FORMALDEHYDE)-1364 KG      

ETHYL MERCAPTANE- 1158KG      

AQ. QTY - 2400KG    

ACIDITY CAL. OF PHORATE & TERBUFOS
       
A/C FOR TBF:    
DETA+TBM+FM+WATER-AQ. QTY.
2400+1041+1036+2100-2983=3594KG

CAUSTIC CAL.=(ORG.X A/C XMW.NAOH)/(MW OF DETA)X1/CAUSTIC PURITY

  : (3594*5*40) /(186.23 )* 1/32
  : 120.5KG OF CAUSTIC 32%
       
A/C FOR PHORATE:    
DETA+EM+FM+WATER-AQ. QTY.
3100+1158+1364+1200-2400=4422KG

CAUSTIC CAL.=(ORG.X A/C XMW.NAOH)/(MW OF DETA)X1/CAUSTIC PURITY

  : (4422*5*40) /(186.23 )* 1/32
  : 148.5KG OF CAUSTIC 32%