Professional Documents
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Waste Generation
Waste Generation
STORAGE
S Taulo
School of Applied Science
Malawi University of Business and Applied
Science
WASTE GENERATION
The handling, storage and separation of solid waste at the source before they are collected
is a critical step in the management of residential solid waste .
SOURCES OF WASTE
Residential
Commercial
Institutional
Municipal
Industrial
Agricultural
Municipal solid waste (MSW)
Industrial waste
Domestic
Agricultural waste
Construction and demolition waste
The term municipal solid waste (MSW) is generally used to describe most of the non-hazardous solid waste from a city, town
or village that requires routine collection and transport to a processing or disposal site
TYPES OF WASTE/CLASSIFICATION
Waste generated by industry and society needs to be classified in order to apply the correct
form of management.
There are different classifications depending on their origin, composition, danger, etc.
Non-biodegradable
Hazardous wastes
Substances unsafe to use commercially, industrially, agriculturally, or
economically and have any of the following properties- ignitability, corrosivity,
reactivity & toxicity.
Non-hazardous
Substances safe to use commercially, industrially, agriculturally, or economically
and do not have any of those properties mentioned above.
These substances usually create disposal problems.
CATEGORIES OF INDUSTRIAL WASTE
Chemical waste
Is typically generated by factories, processing centers, warehouses, and plants
These waste may include harmful or dangerous chemicals and chemical residue, and waste disposal must adhere to careful guidelines
is typically generated by factories, processing centers, warehouses, and plants
Solid waste
Includes a variety of different materials, including paper, cardboard, plastics, packaging materials, wood, and scrap metal.
Some of these materials can be reused and recycled by a recycling center. .
The information on the nature of wastes, its composition, physical and chemical characteristics
– and the quantities generated are basic needs for the planning of a Solid Waste Management
system.
Composition is the term used to describe the individual components that make up a solid waste
stream and their relative distribution. In this text, ‘composition’ refers to the limited list of
components or constituents, such as paper, glass, metal, plastic and garbage, into which an
aggregate of municipal waste may conveniently be separated.
The composition of waste depends on
Sources of generation.
Also depends on the moisture content, density and relative distribution of municipal wastes
.
Waste composition – Cont’d
Table 2: Typical Composition, Moisture and Density
Waste composition – Cont’d
NB:
• Density of waste changes as it moves from the source of generation to the point of
ultimate disposal, and such factors as storage methods, salvaging activities, exposure to
weather, handling methods and decomposition influence the density.
Physical characteristics
Information and data on the physical characteristics of solid wastes are important for the
selection and operation of equipment and for the analysis and design of disposal facilities.
The major physical characteristics measured in waste are: (1) density, (2) moisture content,
and (3) size distribution of components.
Physical Characteristics
1 Density:
Density of waste, i.e., its mass per unit volume (kg/m), is a critical factor in the design of a SWM system, e.g.
the design of sanitary landfills, storage, types of collection and transport vehicles, etc.
Any normal compaction equipment can achieve reduction in volume of wastes by 75%, which increases an
initial density of 100 kg/m3 to 400 kg/m3.
A waste collection vehicle can haul four times the weight of waste in its compacted state than when it is
uncompacted.
Physical Characteristics
Significant changes in density occur spontaneously as the waste moves from source
to disposal, due to scavenging, handling, wetting and drying by the weather,
vibration in the collection vehicle and decomposition.
Physical Characteristics
2 Moisture content:
Moisture content is defined as the ratio of the weight of water (wet weight - dry
weight) to the total weight of the wet waste.
Moisture increases the weight of solid wastes, and thereby, the cost of collection
and transport.
3 Size:
Measurement of size distribution of particles in waste stream is important because of
its significance in the design of mechanical separators and shredders.
Chemical Characteristics
The products of decomposition and heating values are two examples of chemical
characteristics.
If solid wastes are to be used as fuel, or are used for any other purpose, we must
know their chemical characteristics, which includes the following:
Chemical Characteristics
1 Lipids:
This class of compounds includes fats, oils and grease, and the principal sources of lipids are
garbage, cooking oils and fats.
Lipids have high heating values, about 38,000 kJ/kg (kilojoules per kilogram), which makes
waste with high lipid content suitable for energy recovery.
Although lipids are biodegradable, the rate of biodegradation is relatively slow because
lipids have a low solubility in water.
Chemical Characteristics
2 Carbohydrates:
These are found primarily in food and yard wastes, which encompass sugar and polymer of
sugars (e.g., starch, cellulose, etc.) with general formula (CH2O)x.
Carbohydrates are readily biodegraded to products such as carbon dioxide, water and methane.
Decomposing carbohydrates attract flies and rats, and therefore, should not be left exposed for
long duration.
Chemical Characteristics
3 Proteins:
These are compounds containing carbon, hydrogen, oxygen and nitrogen, and consist of an
organic acid with a substituted amine group (NH2). They are mainly found in food and garden
wastes.
The partial decomposition of these compounds can result in the production of amines that
have unpleasant odours.
Chemical Characteristics
4 Natural fibres:
These are found in paper products, food and yard wastes and include the natural compounds, cellulose and
lignin, that are resistant to biodegradation. (Note that paper is almost 100% cellulose, cotton over 95% and
wood products over 40%.)
Because they are a highly combustible solid waste, having a high proportion of paper and wood products,
they are suitable for incineration.
Calorific values of oven-dried paper products are in the range of 12,000 -18,000 kJ/kg and of wood about
20,000 kJ/kg, i.e., about half that for fuel oil, which is 44,200 kJ/kg.
Chemical Characteristics
Hence the increasing attention being paid to the recycling of plastics to reduce the
proportion of this waste component at disposal sites.
Plastics have a high heating value, about 32,000 kJ/kg, which makes them very suitable for
incineration. But, you must note that polyvinyl chloride (PVC), when burnt, produces
dioxins and acid gas. The latter increases corrosion in the combustion system and is
responsible for acid rain
Chemical Characteristics
6 Non-combustibles:
This class includes glass, ceramics, metals, dust and ashes, and accounts for 12 – 25% of dry solids.
Heating values:
An evaluation of the potential of a waste material for use as fuel for incineration requires a determination of its
heating value, expressed as kilojoules per kilogram (kJ/kg).
The heating value is determined experimentally using the Bomb calorimeter test, in which the heat generated, at a
constant temperature of 25oC from the combustion of a dry sample is measured.
Chemical Characteristics
Heating values:
NB:
While evaluating incineration as a means of disposal or energy recovery, we need to consider the heating
values of respective constituents of the wastes.
For example:
• Organic material yields energy only when dry.
• The moisture content in the waste reduces the dry organic material per kilogram of waste and requires a significant
amount of energy for drying.
• The ash content of the waste reduces the proportion of dry organic material per kilogram of waste and retains
some heat when removed from the furnace
Chemical Characteristics analysis
Ultimate analysis:
This refers to an analysis of waste to determine the proportion of
carbon, hydrogen, oxygen, nitrogen and sulphur, and the
analysis is done to make mass balance calculation for a chemical
or thermal process.
Besides, it is necessary to determine ash fraction because of its
potentially harmful environmental effects, brought about by the
presence of toxic metals such as cadmium, chromium, mercury,
nickel, lead, tin and zinc.
Note that other metals (e.g., iron, magnesium, etc.) may also be
present but they are non-toxic.
Chemical Characteristics
Proximate analysis:
This is important in evaluating the combustion properties of wastes or a waste or refuse derived fuel.
The fractions of interest are:
moisture content, which adds weight to the waste without increasing its heating value, and the
evaporation of water reduces the heat released from the fuel;
ash, which adds weight without generating any heat during combustion;
volatile matter, i.e., that portion of the waste that is converted to gases before and during
combustion
Chemical Characteristics
Proximate analysis:
fixed carbon, which represents the carbon remaining on the
surface grates as charcoal.
A waste or fuel with a high proportion of fixed carbon
requires a longer retention time on the furnace grates to
achieve complete combustion than a waste or fuel with a low
proportion of fixed carbon.
.
Compilation and comparison of solid waste generation in large cities of various countries show that waste
is generated at the rate of
Estimated waste generation is approximately 8,500 tons/day for the whole country
FACTORS THAT INFLUENCE WASTE GENERATION
Geographic Location
Population characteristics
Public Attitudes
Season of the year
________________________
Legislation
Duty of Care
Polluter Pays Principle
Pay as You Throw
GEOGRAPHIC LOCATION
It follows that the most industrialised countries produce more wastes than non-
industrialised (developing) countries.
SEASON OF THE YEAR
The first phase to manage solid waste is at home level (Industrial site).
For industries, and other commercial centers, proper on-site storage of solid waste is the
beginning of proper disposal, because unkept solid waste or simple dumps are sources of
nuisance, flies, smells and other hazards.
HOW TO DETERMINE GENERATION RATES
Weight-Volume Analysis
Material-Balance Analysis
LOAD COUNT ANALYSIS
The only way to determine the generation and movement of solid wastes with some degree
of reliability is to perform a detailed materials balance analysis for each generation source,
such as an individual home or a commercial or individual activity.
Consider a small enterprise company that generates a certain amount of wastes per day. Of this
amount, bottles and cans represent 20 per cent (by weight) and are recycled by the company.
The paper wastes (32 per cent) are burnt in the backyard incinerator. The rest of the wastes are
put into containers for collection by the City Council. On a given day, 9 kg of raw materials is
brought into the company. The company uses 3.2 kg of raw materials that day and 2.3 kg of raw
materials is stored for another day’s use. The magazines received represent 5 per cent of paper
wastes of the day and they are not thrown away.
Draw a materials flow diagram of this enterprise company and calculate the amount of wastes
disposed of during this day.
THE END