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  • 2018 FM P4

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    丁周辰
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    This document discusses various chemistry concepts including: 1) Positive and negative electrodes in electrochemical cells and how their potentials relate to being more or less positive. 2) Four-coordinate complexes and their geometry including square planar complexes. 3) The ratio of concentrations of a solute in two immiscible solvents at equilibrium known as the partition coefficient (Kpc). 4) That butylamine is more soluble in the non-polar solvent trichloromethane than water due to its non-polar nature. 5) Mass spectrometry data can be used to determine molecular formulas and whether a compound is an alcohol or aldehyde.

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    2018-FM-P4

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    This document discusses various chemistry concepts including: 1) Positive and negative electrodes in electrochemical cells and how their potentials relate to being more or less positive. 2) Four-coordinate complexes and their geometry including square planar complexes. 3) The ratio of concentrations of a solute in two immiscible solvents at equilibrium known as the partition coefficient (Kpc). 4) That butylamine is more soluble in the non-polar solvent trichloromethane than water due to its non-polar nature. 5) Mass spectrometry data can be used to determine molecular formulas and whether a compound is an alcohol or aldehyde.

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    16 views28 pages

    2018 FM P4

    Uploaded by

    丁周辰
    This document discusses various chemistry concepts including: 1) Positive and negative electrodes in electrochemical cells and how their potentials relate to being more or less positive. 2) Four-coordinate complexes and their geometry including square planar complexes. 3) The ratio of concentrations of a solute in two immiscible solvents at equilibrium known as the partition coefficient (Kpc). 4) That butylamine is more soluble in the non-polar solvent trichloromethane than water due to its non-polar nature. 5) Mass spectrometry data can be used to determine molecular formulas and whether a compound is an alcohol or aldehyde.

    Copyright:

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    of 28

    2018-F/M-P4

    2
    (b)

    equation
    Positive electrode

    Negative electrode

    √
    less positive

    More positive
    3 Four-coordinate complex

    Square planar
    Reduction

    Hydrolysis of nitrile
    Square planar

    cis trans
    Ni(CN)2 K2[Ni(CN)4] K3[Ni(CN)5]

    Two K+ ions, the anion with 2- charge.


    Three K+ ions, the anion with 3- charge.
    4
    The ratio of the concentrations of a solute in two immiscible solvents at equilibrium.
    Kpc of ammonia between trichloromethane and
    water

    Butylamine is more soluble in


    trichloromethane (more non-polar)

    Tend to repel or fail to mix with


    water. 憎水的
    5
    7(a)
    Abundance of [M+1] peak/abundance of [M] peak= 8/100
    Is F an alcohol?

    F 比 phenylmethanol 少 2H, F is
    phenylmethanal.
    F is an aldehyde.

    hydrolysis

    F contains 7 carbon atoms. C7H8O

    Mr=108

    G
    进一步证明 F
    is an aldehyde.
    C6H5CH2+: 77+14=91
    77

    91-77=14

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