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Woven Fabric Dyeing Procedure
Woven Fabric Dyeing Procedure
Woven Fabric Dyeing Procedure
A Jig Dyeing machine, is an efficient dyeing technique. It is also known by the name of
jigger. Jig Dyeing machine processes fabrics in open width to avoid creasing problems in
fabric dyeing. The Jig Dyeing machine operates by transferring the fabric back and forth.
This happens from roller to roller via the medium of a dye bath, that is located at the base
of the machine. As soon as the second roller gets full, the direction of movement of fabric
can be reversed. In Jig dyeing, the duration of the process is measured on the basis of the
number of passages or ends of the fabric passing through the dye bath from roller to roller.
The end in dyeing parlance is known as the passing of fabric through a dye liquor from
one roller to the other one.
CONTINUOUS DYEING
In continuous dyeing fabrics are bleached, (mercerized), dyed and washed in open width
form on ‘ranges’, which are long, big machines that need to be threaded up with very
long pieces of fabric – It is possible to create modular mega-machines which combine
bleaching, mercerizing, washing, drying, dyeing, fixing, washing and drying into a single
machine several hundred meters long.
Normally dyeing, fixation, wash-off and drying are carried out in a single machine that is
around 150 meters long.
The reason for emphasizing the size of the machine is because the fabric is ‘festooned’ in
the machine – as in the example below – and, even though the best machines can be
extremely efficient, it can take up to 500 m to even thread up the dyeing machine. In
order to avoid permanent creasing the fabrics need to be run under a certain amount of
tension and this means that unless very sophisticated controls are employed continuous
dyeing is only applicable to rigid woven fabrics.
The dyes are applied using a mangle: fabric is dipped in a trough of dye liquor and
fixation chemicals and mangled (this sometimes a two stage process with dyes applied in
one trough and chemicals applied separately – the eliminates the risk of alkali rendering
the dye non-reactive before application to the fabric). The fabric is usually dried and the
dyes are fixed by either the application of steam or dry heat – the diagram below gives a
schematic view of the pad trough and mangle arrangement.
In order to get good dye fixation in the limited time the fabric has in either a steamer or
thermofix unit it is often necessary to add humectants (chemicals that attract moisture), such as
urea, to the dye liquor in addition to the alkali used for dye fixation. Urea in effluent is a major
problem because it is difficult to remediate (it requires specific denitrification techniques) and if
discharged to the environment it acts as unwanted fertilizer and can cause damaging algal
blooms.
Salt and/or thickeners are sometimes added to the dye liquors to enhance dye uptake from the
pad trough. Salt is an environmental challenge and thickeners (such as alginates) can add
considerably to the BOD/COD content of effluent.
WASH OFF
The post-bleach and post-dye wash offs can be either a hugely water intensive processes or
incredibly efficient depending on the type of machinery used.
Modern ‘counter-flow’ wash ranges are very impressive in terms of water consumption – the
concept is that ‘dirty’ fabric enters the machine at one end and clean water enters the machine at
the other. Fabric moves from the front to the back of the machine and gets progressively cleaner
and water moves from the back of the machine and gets progressively dirtier.
By the time the fabric exits the machine it is being washed in clean water and by the time the
water exits the machine it is quite contaminated but still capable of removing a large proportion
of the unfixed dyes and fixation chemicals from the fabric.
Older wash ranges with discrete, sequential wash baths can be very inefficient and use very large
amounts of water.
Fabric in-feed
Open width fabric must be processed under uniform tension, before entering the padder
and during take-up on the beam.
Synchronized cloth guidance systems must be used
Incorrect tension or inadequate cloth guidance, causes
The pad liquor turnover time should be as fast as possible (less than
5 minutes).
The pad liquor should be distributed uniformly across the full
width of the padder through a perforated tube
In through example 1 and example 3, because the time of fabric diving is long, the fabric
becomes wet. The way of diving is a distance from the first point of fabric touching bath to
squeezing padders.
1. Depending on the hydrofility of fabric, the time of diving at each 2-4 is to be
considered.
2. The passing speed changes 25-60 minutes depending on the volume, weight and
hydrofility of fabric.
The covering of both bowls must be of uniform hardness to prevent two sided problems.
Damage to the nip rolls results in poor appearance of the dyed fabric and pick-up variations
(silicate build up, age deterioration)
High affinity dyes migrate slower but unfortunately lead to poor penetration, tailing and
washing-off problems !!
Significant cost and waste reduction as compared to other conventional dyeing processes.
A uniform dye quality is achieved with even color absorbency and color fastness.
As compared to rope dyeing, Pad batch dyeing produces much lower defect levels
In pad batch dyeing, qualities like high shade reliability and repeatability are common.
This is because of high reactivity dyes with rapid fixation rate and stability.
4.Steamer
Here in steamer temperature required for the fixation is given to the fabric. This
temperature is achieved by saturated steam. The purpose of using saturated steam is that
the chemicals used for developing should not dry on the surface of fabric preventing
fabric from stains. Here roof temperature is given to avoid water dropping that causes
spotty dyeing. Here water is not given at the entry of steamer because to prevent
developing chemicals that just applied before going into steamer so water lock is given
at the end of steamer.
Finishing chemical
°c)
5 0
e( 1
r
Cu
Steaming &
Thermofix Dyeing and printing
(102°c-160°c)
Pad-dry Reactive/vat/sulphur/
disperse
Cu
re(
15
0 °c)
Pigment
Pad-Dry-Pad-Chemical-Steam( Reactive- medium strength)
Process flow
Padding dye →Drying →Padding alkali liquor →Steaming fixation
→Washing →Soaping→ Washing →Drying
Condition
Temperature 20 – 25℃
Pick-up 60 – 80 %
Steaming 102 – 105 ℃
Time 40 – 90sec
Process Possible applications
Pad-dry-pad -steam(102-110°C) Medium strength reactive dyes and
Pad-dry-thermofix (160-190°C) Low strength reactive dyes
Cold pad-batch (room temperature) High strength reactive dyes
Pad-dry –thermosol (200-230°C) For disperse dyeing
Pad-dry-curing For pigment dyeing & printing, cross linking
finishing agent
Pad-dry-steam Vat and reactive dye( when color amount is
too high)
Pad-dry(E-control) Stenter machine where drying with 25%
humidity
Pad-steam •Vat, sulphur
•After cold pad batch of reactive dyeing it can
be done.
•Reduction clearing, stripping
Pad-(pad)-steam •Vat and reactive dyes (when alkali is needed)
Procedure:
In this method fabric is dyed in large scale. Two bowls are used here. In the first, Padding
is done on the fabric with urea & dye solution at 60ᵒC – 80ᵒC temperature. Urea is used to
dissolve the dye stuff and to penetrate into the fabric. Na – Alginate is used as a migration
inhibitor . Then the fabric is passed through the drying chamber & again padding is done
with NaOH at 60ᵒC temperature. Then steaming is done at 100ᵒC – 102ᵒC for 30 – 60
seconds. Then after rinsing & soaping, fabric is washed & dried.
Pad- (Pad)-Steam Process
Cotton weaved fabric is generally dyed by continue process. The criteria defining which
of Pad-Steam or Pad-Jig is prepared, is the feature of fabric such as the length type. Long
meters heavy mercerize weaved fabric is dyed by the method of Pad-Steam with distance
drying.
Short meters fabric is dyed by the method of Pad-Jig, however the cost must be cared.
Knitting fabric is not dyed by this method.
Dyeing by Pad-Jig methods without any instance drying supplies much more
penetration and suitable. In bath of methods mentioned is prepared according to the
position and feature of machines, but it is not suggested.
Pad-Steam process has more advantages to supply high production due to it is an easy
process. It requires less investment and energy than Pad-Dry-Pad Steam. It has no
possibility of migration. It includes fewer chemicals. It is the continue dyeing process
used in big amount of fabric and viscose fabric. It includes tailing problem and it has limit
to dye choose.
Pad-Steam( Reactive- medium strength/Vat /Sulphur dyes)
Condition
Temperature 60-80 ℃
Pick-up 60 – 80 %
Steaming 102 – 105 ℃
Time 30-40 Sec
Pad-Steam dyeing is a process of continuous dyeing in which the fabric in open width is
padded with dyestuff and is then steamed. Pad steam is an ideal machine for reactive
dyeing of cotton and its blended fabrics. Light, pale and medium shades can be dyed in
this machine. Continuous roller steamer is used for diffusion of reactive, vat, sulphur and
direct dyes into cellulosic fibers in an atmosphere of heat and moisture that is created by
saturated steam injected into the steamer.
E-Control process is short and includes cost. It is usable with hot air drying and
fixation continue dyeing process it includes less procedures and uses less chemicals
so it has advantages. Its feature of reputability is great. Tailing problem is again
encountered in E-Control process like the other process
Pad-Dry-Thermofix(Reactive dyes-low strength &
disperse dyes)
Condition ℃
Temperature 20 – 25
%
Pick-up 60 – 80 ℃
Steaming 140 – 160 Sec
Time 60 – 90
Note:
• Pre-drying by infrared or hot air gradually until the drying percentage 70%.
• Thermofix and washing off should be carried out immediately when the fabric is dried after
padding dyes.
• Pad-dry-thermofix can have reduced fastness properties, pre-trials are necessary.
Recipe:
Dye stuff ---- 2% (According to the wt of mtl)
Soda Ash ---- 1%
Salt ---- 8%
Urea ---- 15%
Na – Alginate ---- Little amount
Procedure:
In this method padding bath continuously dye, alkali, salt, urea and Na – Alginate
liquor. Padding is done in the bath at room temperature. Then fabric is passed through
drying chamber. Then thermo – fixation is done at 160ᵒC for 5 minutes. Finally
rinsing, soaping and again rinsing is done. This method is suitable for moderate
reactive dye.
Pad-Dry-Thermosol(Pigment)
Condition
Temperature 200 – 220
℃
Pick-up 75 – 90 %
Time 60 – 90 sec
Cold Pad Batch(Reactive dyes-high strength)
The Cooling
System Dye
Trough
Cold pad batch dyeing
Cold pad batch dyeing is closely related to continuous dyeing but it only requires the
use of a pad mangle and a means of winding fabric onto a roll .
The fabric is dipped in a trough containing dye and alkali (typically sodium
hydroxide and/or sodium silicate), it is mangled and then wound on a roll without
drying it
The roll is covered in plastic sheets to stop the fabric drying and the batch is slowly
rotated for 12 – 24 hours to allow the dye to fix at room temperature.
There is no need to apply heat* and there is no need to use salt or humectants so it is a
low water dyeing process, it requires little energy and the absence of salt has the dual
benefits of easy dye wash off and no salt in effluent. Additionally there is often a higher %
dye fixation compared to jet dyeing.
*The rate of fixation is dependent on the ambient temperature and in countries where
there are great differences between summer and winter temperatures it is good practice to
carry out dye fixation in a thermo-regulated room.
The contents of the dye pad trough have to be prepared as late as possible before dyeing
commences because, even though the alkali is necessary to fix the reactive dye to the fiber,
it can also permanently deactivate the reactive part of the reactive dye by a process called
hydrolysis – the two reactions (alkali fixing dyes and alkali deactivation dyes) compete in a
reactive dyeing process and dyers must minimize hydrolysis to get good levels of dye
fixation.
The dye solution and alkali solution are typically pumped to the dye trough independently
and mixed immediately prior to dyeing – and there is often the use of a chiller to keep the dye
liquors cool to minimize hydrolysis.
Fabrics have to be bleached and dried prior to dyeing and it is essential that fabrics have
completely uniform moisture content prior to dyeing in order to get uniform dye uptake.
After dyeing the fabrics can be washed off using batch processes (such as a winch or a jet)
or, preferably, on a new efficient counter-flow wash range.
Cold pad batch dyeing can save around 50% of energy and water for the whole process
compared to jet dyeing provided bleaching and post-dye wash off are carried out on efficient
counter-flow wash ranges.
Cold pad batch dyeing can be applied to woven and knitted fabrics (knitted fabrics need
careful low tension processing) and, because there is no abrasive processing, the fabrics are
much smoother than if processed in a jet dyeing machine – this means smooth fabrics can
be obtained without enzyme bio-polishing – resulting in stronger fabrics.
Limitation and disadvantage compared to
Advantages over jet dyeing: jet dyeing
Much reduced water consumption Requires investment in specialist equipment
(if counter-flow washing ranges Best results achieved by continuous
used) bleaching and washing – requiring large
Cold process - Much reduced investment
energy consumption
Difficult to make amendments to off-shade
Slightly higher dye fixation batches so pressure to get things right first time
No salt required Process not viable unless high quality kit is
o Easier post-dye wash off used o Side to side variation results in fabric
o No salt in effluent rejections.
Fabrics are smoother
o No need for biopolish Requires off-line bleaching and wash off
o Fabrics are stronger than which makes planning more complex.
biopolished equivalent Requires an intermediate drying process
after bleaching.
Opportunity to do pre-dye checks
to improve right first time. Requires fabrics to have completely uniform
moisture and temperature throughout to
Productivity – one machine can achieve optimum results
dye far more fabric than a jet Ideally requires a chiller for dyes and
machine thermo-regulated room for dye fixation
Advantage over continuous dyeing
No humectants needed, salt should never be used on Lower effluent loading
Cold dye fixation – energy savings
Can be applied to small batches of a few hundred meters
Turn round times between colors is very low
No energy being wasted when the machine is not dyeing fabric
Better suited to stretch fabrics and knits because it’s easier to manage tension
control in a small machine
Cold pad batch dyeing should be promoted over jet dyeing in most instances where it
is a suitable method for the cellulosic fabric in question.
It may not be suitable for some very lightweight, stretch fabrics that can distort easily
and these may be better suited to a horizontal jet dyeing machine.
Cold pad batch may only be the appropriate choice from a water and energy
perspective where efficient counter-flow wash ranges are used for post-bleach and post-
dye wash off.
Where salt in effluent is an issue (unless the receiving waters for treated effluent
discharge can adequately dilute salt) cold pad batch dyeing should be the method of
choice.
Some jet dye mills can remove salt from effluent using reverse osmosis and vacuum
distillation but this is incredibly energy intensive.
It should be ensured that dyers have good quality equipment (and carry out weekly
pad mangle checks) and have chillers for dye liquors and thermo regulated rooms for
dye fixation where appropriate.
Finally it should be noted that fabrics produced by cold pad batch are smooth and
strong but they are susceptible to surfacing on consumer washing and tumbling if poor
quality, hairy yarns are used. If low quality yarns are used and require biopolishing
Continuous PAD-STEAM process
This example shows a small PAD-STEAM dyeing range. The advantages of the
continuous dyeing process and the flexibility of a small size range are here combined!
Possible applications
PAD-STEAM process for vat and reactive dyestuff (PAD-DRY is carried
out in a separate range)
1-bath (all in) PAD-STEAM process with sulfur dyestuff (cotton)
2-bath (wet/wet) PAD-STEAM process vat dyestuff (cotton)
1-bath (all-in) PAD-STEAM process with reactive dyestuff (cotton)
2-bath (wet/wet) process with direct dyestuff (cotton)
7. Roof heating
9.fresh
water
8 Water seal
with small
liquor content
4. Lifetime lubricated 12 Automatic cleaning system (option)
bearings
2. Section with 25 m fabric content
11. Probe to measure the steam condition 6 Load cell to measure fabric tension
Steam Fixation: Process requirements
Equilibrium setting up time
An air free atmosphere of saturated steam
Sufficient steam pressure and supply
Measurement of wet & dry bulb temperatures
Prevention of condensation drops ( heating of steamer entrance & roof)
Fabric cooling before padding
Chemical pad recipe and pick up
Fabric tension and steaming time
Water seal
Cylinder driers
Infrared pre-drying
Sized yarn
Curing ? Steaming ?Drying ?
Dyed knitted
t er fabric
e n
r/st
RF
ry e
/In
a t d
Fl
fra
-re
RF Dyed yarn
d
RF/Infra-red
Curing
Drying Hot fl
ue /drum
dryer Dyed woven
r fabric
le
r ol
d RF
a te
/ He
m
ea Flat dryer/stenter Dyed
St
Calendaring Garments
Steam/Heated roller
Heat setting
Perforated Sanforizing/compating
drum dryer
Air suction to remove moisture
Air passing through fabric to
outside
Tailing and listing
Tailing is shade variation along the length of the fabric and is determined by a series of
comparisons of the color from the first meter to the last, checked and measured during the
dyeing process. For example, if 10000 m of fabric is to be dyed in a continuous dyeing range,
the dyeing is started and the shade being matched is sampled and agreed and this sampling is
continued up to the end of the 10 000 m at intervals. These intervals depend on past history of
the dyes and fabric being dyed. The term ‘ending’ has also been used as well as listing.
Listing is shade variation across the width of the fabric and it is also checked during
dyeing. Variation can be from side-to-side or side-to-centre. When the fabric runs in open
width this parameter should not be ignored and must be checked in a similar manner as the
tailing. When dyeing in jet machines where the fabric is in a rope form, listing is rarely a
dyeing machine problem.
Testing staff should be made aware of the phenomena of thermo chromic effects as certain
chromophores can exhibit vast temporary color changes. The effect of moisture on shade
should be considered especially when urgent orders are being processed. Shade variations can
occur in finishing but these effects should have been checked in the laboratory.
General factors influencing listing and tailing
An assumption has to be made that for large dyeing orders the fabric is fully suitable
for purpose and has consistent properties. Factors influencing tailing and listing
include variation in yarn count, yarn twist, fabric density and width GSM of the
grey fabric. Sizing agents should be water soluble. Uneven size application affects
the degree of desizing.
Tailing and listing problems can be caused by two controlling factors, namely:
•Equipment parameter changes or variations or
•Eye properties.
Dyeing properties and the effect on
tailing and listing
Different dyes can have vastly different dyeing properties and it is of paramount concern
that the dye manufacturers’ recommendations be followed. Dyes that have been matched
with other dyes are more likely to give similar dyeing characteristics. Colors have different
substantivity and affinities, often at different temperatures and in the presence of added
electrolytes commonly used in dyeing procedures. For example, a mixture of three dyes in
a padding bath might have differing substantivities. If the pad bath is large or the liquor
feed control poor and the machine is running more slowly because of a heavy fabric, one of
the dyes might be removed from the bath more quickly – hence the start of a tailing
situation. This problem was given a name in the very early days of dyeing, the problem of
‘strike’.
It is essential that good records of dyeing problems be kept so that certain mixtures of dyes
for certain fabrics can be avoided if possible or special care taken.
The dye manufacturers have spent time and money on developing efficient dyeing systems
and their efforts should be used to create a viable and prosperous industry.
Shade evaluation and quantifying listing and tailing
Visual assessment is carried out in a standard light bo x. For listing, width-wise fabric
is stitched to accommodate three areas marked as left, centre and right; this article is
then assessed in a standard light box with specified light such as D65, TL84, Inca or
CWF. For tailing, a number of fabric samples are collected at 500 m intervals and
assessed against the customer’s standard in a light box. The number of samples and
intervals vary according to the total length being dyed in bulk.
Spectrophotometric and computer color matching systems can be used instead of the
visual assessment procedure, but this needs to be done against defined standards. The
customer standard is taken as a reference for measurement in a spectrophotometer and
then compared to the production run. All of these factors have different impacts
depending on the fabric, the fiber and the dyeing system. Herein lies the skill of the
colorist.
Equipment control parameters
•Uneven padder pressure at any stage in desizing, washing, scouring, bleaching, dye
application and washing off can cause variations and thus listing can occur.
• Faulty padder equipment is the most likely cause of listing.
•The individual padder pressures from left, centre and right play a dominant role and
have a direct effect on listing and tailing.
•Padder diameter variation across the width may also producing listing.
• Variation of air of hydraulic pressures can lead to variable padding expression.
• A long run of smaller width fabric will leave an impression across the width on the
padder, which will leave an impression on wider fabric that will show up during
dyeing.
Some companies invest in keeping two dyeing padders operative in one dyeing range
where wider and small width changeover is frequent, one for narrow fabric width
and the second for wider width fabric, in order to avoid any variation caused by the
padder and also to increase the life of the padder
Mercerising: variations in the degree of mercerizing across the width cause listing
and should be controlled. The washing process needs careful control
The drying or dye fixation of fabric must be controlled and even, in order to ensure a
consistent moisture content. A stenter must be fully controlled in terms of temperature
and recycling. Even temperature is needed when there are different temperature zones.
Over- or under-drying can cause listing later in the dyeing process where there is steam
injection for thermosol processes; control is paramount.
A major control problem that is caused by dye properties can be corrected by good
padder design.
Control of washing off: this is vital for both quality and effluent and environmental
considerations. Water flow in each tank must be controlled throughout the production
run; the padder pressures and the condition of the padders in each washing chamber
should regularly be checked. Variation in washing temperature, feeding rate of soap
and neutralizing acid can also account for listing and tailing.
The volume of dye liquor for long runs has to be established and mixing tanks provided
for shade continuity. The padding expressions for the fabric to be padded have to be
decided. The padding trough volume has to be sufficient to stop tailing due to variable
‘strike’ in a bath containing a mixture of dyes of differeing dye properties