“COOLING WATER

SYSTEM”

PT. PACIFIC INDOPALM

INDUSTRIES
FACILITY & LOCATION
 PT. EONCHEMICALS PUTRA

 Founded in 1987 (28 years experience)

 100 % Local Investment
 Vision: “The best in Solution, Service and Commitment”
 Specialty Chemicals
 Customer: Oil and Gas, Palm Industry, Mining and Steel Company
 Provide: R&D, Manufacturing and Technical Service
 300 employees distributed through out Indonesia
 ISO certified (9001, 14001 and 18001)
BUSINESS UNIT DIVISIONS

Maintenance Chemicals Division

 Maintenance & Workshop Chemical
 Pipe Coating

Coolant Division
 Metal Cutting Fluids

Oil Production Chemicals Division

 Oil Production Chemicals
 Drilling Chemicals
 Refinery Chemicals
 Boiler Treatment Chemicals
 OUR NETWORKS

Facility & Location

 Head Office: Jakarta
 Plant: Jababeka – Cikarang ( 35 km from Jakarta)

 32 Rep. Offices:
Jawa
Sumatera
Kalimantan
Sulawesi
Papua
Nusa Tenggara

 Research Lab: Cikarang

 QUALITY MANAGEMENT SYSTEM
CERTIFICATIONS

QUALITY – ISO 9001

ENVIRONMENT – ISO 14001

HEALTH & SAFETY– OHSAS 18001

LABORATORY & R&D
 PRODUCTION PROCESS

Kontrol Produksi
kualitas QC Produksi

- Bahan
baku - Bahan baku
- Paking - Paking Paking

Pengiriman
Pemberian
label & paking Inspeksi Penuangan
pengiriman paking

- Info produk
- Info K3 - Kebocoran
- QC label - Kualitas
- Berat/volume
 PRE-TREATMENT PORTFOLIO

pH Adjuster: Flocculant:
1. EONALKALOX B2214 (Liquid) 1. EONTREAT FL 2022 (liquid)
2. EONALKALOX B2014 (Liquid) 2. EONTREAT FL 2077 (powder)
3. EONALKALOX B1717 (Solid) 3. EONTREAT FL 2100 (liquid)
4. EONALKALOX W2099 (Solid) 4. EONTREAT FL 2155 (powder)

Anti Bacteria:
Coagulant:
5.EONCHLOR CL 3707 (liquid)
5. EONTREAT CL 2010 (liquid)
6.EONBAC BC 3190 J (liquid)
6. EONTREAT CL 2019 (Powder)
7.EONBAC BC 3092 (liquid)
7. EONTREAT CL 2218 (powder)
8. EONTREAT CL 2310 (Liquid)
 REVERSE OSMOSIS PORTFOLIO

Cleaner: Reducing Agent:

1. EONROM 3000 1. EONSULFIT 8027
(powder) (powder)
2. EONROM 200 (powder) 2. EONCHLOR DC 8707
(liquid)

Anti-Scale:
3. EONSCALE RO 9100
(liquid)
4. EONSCALE RO 9200
(liquid)

Corrosion Inhibitor:
5. EONCORR RO 8100
(liquid)
 BOILER INTERNAL TREATMENT PORTFOLIO
pH / Alkalinity Control:
1. EONALKALOX B1414 (Caustic
Base - Liquid)
2. EONALKALOX B1717 (Caustic
Base - Solid)
3. EONALKALOX M3501 (Amine
Base - Liquid) – Neutralizing
Amine
4. EONALKALOX B3016 (Ammonia
Base – Liquid)
Multifunctional Treatment:
5. EONSCALE B5110 (Polymer /
Amine Base – Liquid)
Oxygen Scavenger:
1. EONOXY B8100 (Sulfite Base
– Liquid)
2. EONOXY B8155 (Sulfite Base
– Powder)
3. EONOXY B8641 (Amine Base
– Liquid)
Dispersant & Scale Inhibitor:
4. EONSCALE B5100 (Phosphate
Base – Liquid)
5. EONSCALE B5155 (Phosphate
Base – Powder)
6. EONDESCALER B2550
(Polymer Base – Liquid)
 COOLING TOWER & CHILLER TREATMENT
Oxidizing Biocide:
1. EONBAC BC 3107 (Sodium
Hypochlorite Base - Liquid)
Non-oxidizing Biocide:
2. EONLINE T 780
(Gluteraldehyde Base - Liquid)
Corrosion Inhibitor:
3. EONCOR CT 700 (Liquid)
PORTFOLIO
Scale Inhibitor:
1. EONSCALE T 2511
(Polyacrylic Base – Liquid)
Dispersant:
2. EONBIO BD 3291
(Isothiazoline Base – Liquid)
Defoamer:
3. EONFOAMCLEAR 5841(Liquid)
Chiller Treatment:
4. EONCOR CL 1070 (Liquid)
COOLING WATER SYSTEM
 APA ITU COOLING WATER SYSTEM?

TYPE :
1. CLOSED C/W SYSTEM
2. ONCE-THROUGH C/W SYSTEM
3. OPEN C/W SYSTEM

Sumber air yang tersedia akan menentukan pemilihan TYPE C/W system.

1. CLOSED C/W SYSTEM ( Biasa dipakai Demin Water, atau Softened Water )
 APA ITU COOLING WATER SYSTEM?

2. ONCE THROUGH C/W SYSTEM ( Biasa dipakai Air Laut )

Pemakaian air : Sangat banyak.

Biasanya dipakai oleh Power Plant yg terletak di tepi laut, khususnya air laut
dipakai sebagai media pendingin di Condenser.
 APA ITU COOLING WATER SYSTEM?

3. OPEN C/W SYSTEM ( Biasa dipakai Air Sungai atau Air Sumur yang telah
ditreatment terlebih dahulu, Minimal turbidity < 10 NTU )

Evaporasi : Yang menguap hanya AIR saja, mineral tetap di C/W.

Akibat : Konsentrasi TDS / Mineral di C/W >> konsentrasi TDS / Mineral di Makeup
Water.

Untuk menjaga kestabilan konsentrasi TDS / Mineral di C/W, maka perlu blowdown.

Makeup water untuk mengganti air yang hilang karena evaporasi & blowdown.
Sehingga level C/W di basin menjadi stabil.
 PROBLEM DI OPEN C/W SYSTEM

N
IO

SC
OS

AL
RR

E
CO

MICROBIOLOGICAL
FOULING
 OPEN C/W SYSTEM PROBLEM – KOROSI

Faktor yang mempengaruhi laju korosi :

• PH
• Temperatur (2x setiap peningkatan 10 0C)
• Oksidator (chlorine; etc)
• Laju alir air
• Ion-ion agresif (Cl-, SO4 ; dll)
• Jenis logam
• Bakteri
 OPEN C/W SYSTEM PROBLEM – SCALE

Faktor yang mempengaruhi pertumbuhan scale :

• PH
• Konsentrasi ion-ion (Ca, Mg, SiO2, CO3, PO4)
• Temperature
• Waktu Kontak
 OPEN C/W SYSTEM PROBLEM – FOULING

Faktor yang mempengaruhi terjadinya fouling:

• Angin
• Konsentrasi suspended solids yang berlebih dari makeup water
• Kontaminasi proses
• Micro-organisme
 OPEN C/W SYSTEM PROBLEM – BIOLOGICAL

Faktor yang mempengaruhi :

• Udara (O2) – Sebagai nutrisi bagi micro-organisme
• Pertumbuhan mikro-organisme tidak terkontrol :
 Bakteri
Bakteri aerobik: slime forming bacteria – menghambat perpindahan panas dan
memberikan “rumah” bagi bakteri anaerobik.
Bakteri anaerobik: SRB, clostridia – under deposit corrosion/ pitting.
 Algae
Menghambat distribusi air pendingin dan proses perpindahan massa/ panas di
cooling tower memberikan “rumah” dan “makanan” bagi bakteri.
 Fungi / Jamur
Mengurangi umur peralatan dari kayu (cooling Tower).
 PENCEGAHAN MASALAH - EKSTERNAL

1. EKSTERNAL TREATMENT
a) Pengolahan makeup water / air umpan secara fisika :

Sand Filter Carbon Filter

Reverse
Osmosis
 PENCEGAHAN MASALAH - EKSTERNAL

b) Proses Softening / Demineralization. c) Bleed Off / Blow Down

=> Untuk mengurangi
pemekatan air dan mineral
terlarut dalam cooling agar
tetap dibawah control limit.

Ion
Exchange

Blowdown
 PENCEGAHAN MASALAH - INTERNAL

2. INTERNAL TREATMENT
a) Pencegahan Korosi
• Material tahan korosi
• Coating (inert films)
• Anoda yang dikorbankan
• Merubah sifat kimia air (pH dan Alkalinity)
• Membatasi konsentrasi ion-ion agresif
• Chemical pencegah korosi (Corrosion Inhibitor)
=> Chemical EON : EONCOR CT 700
b) Pencegahan Scale
• Membatasi konsentrasi padatan terlarut / TDS (menurunkan cycle)
• Penambahan Asam (mengurangi pH dan Alkalinity)
• Perubahan Mekanik
- Meningkatkan flow
- Air rumbling
- Side-stream filter, dll
• Penggunaan bahan kimia pencegah kerak (Scale Inhibitor)
=> Chemical EON : EONSCALE T2511
 PENCEGAHAN MASALAH – INTERNAL

c) Pencegahan Fouling
• Membatasi konsentrasi padatan tidak terlarut pada Pre-treatment,
side-stream filter
• Blowdown
• Perubahan Mekanik
 Meningkatkan laju alir
 Backflushing
 Air rumbling
• Bahan Kimia Pencegah Fouling (dispersant)
=> Chemical EON : EONBIO BD 3291
d) Pencegahan Biological
• Me-minimalisir kontaminasi dari proses dan lingkungan (ammonia,
oli, organik; dll)
• Penggunaan bahan kimia pembunuh mikro-organisme
=> Oxidizing Biocide (Chlorine, Sodium Bromide, dll) & Non-oxidizing
Biocide (Gluteraldehyde, Quaternary Amine, dll)
=> Chemical EON : Oxidizing EONBAC BC 3107
Non-oxidizing
EONLINE T780
 MONITORING KUALITAS C/W SYSTEM

Untuk melihat kualitas C/W System perlu dilihat dari parameter berikut :
1. Evaporation Loss
E = x ∆T x Flowrate makeup water
dimana,
E = Evaporation loss (liter/day)
∆T = Perbedaan temperature
Flowrate makeup water (liter/day)
2. Windage Loss
W = ; W = Windage loss (liter/day)
3. Blowdown
B = - W ; B = Blowdown (liter/day)
E = Evaporation loss (liter/day)
C = Cycles of Concentration (3-10)
W = Windage loss (liter/day)
 MONITORING KUALITAS C/W SYSTEM

4. Makeup Water Quality

Makeup water adalah total volume air yang hilang karena evaporasi,
windage dan blowdown.
M = E + W + B ; M =Makeup water (liter/day)

5. Jumlah cycle (Cycles of Concentration)

 CoC = (Conductivity Cooling tower / Conductivity Makeup water)
 CoC perlu dimonitor untuk menjaga sistem berjalan pada CoC
puncak sehingga akan memaksimalkan efisiensi dan menjaga
peralatan dari potensi korosi, kerak, ataupun fouling.
 > Blowdown, maka < CoC
 < Blowdown, maka > CoC
 Range CoC yang direkomendasikan = 3 – 10 ; 3 = Min. Efisiensi
10 = Good Efisiensi
6. Chemical loss
CL = W + B ; CL = Chemical loss (liter/day)
 C/W SYSTEM CONTROL LIMIT

PARAMETER UNIT CONTROL LIMIT

pH   7.5 - 9.5
TDS ppm < 2000
Conductivity ppm < 3500

Total Hardness (as CaCO3) ppm < 100

P - Alkalinity (as CaCO3) ppm < 500

M - Alkalinity (as CaCO3) ppm < 800

Total Iron (Fe) ppm <2

Silica (SiO2-) ppm < 150
Free Chlorine ppm 0.2 - 1
Chloride (Cl-) ppm < 250
Bacterial Growth cfu / ml < 104
Fungal Growth cfu / ml < 104
Cycles of Concentration 3 - 10
 TROUBLESHOOTING BERDASARKAN KUALITAS
AIR BASIN / AIR SIRKULASI
CONTROL
NO. PARAMETER UNIT TROUBLESHOOTING
LIMIT

Bila pH < 6.5, tambah stroke / dosis EONCOR CT 700

1 PH 7.5 - 9.5
  Bila pH > 9.5, kurangi stroke / dosis EONCOR CT 700
Bila TDS air basin atau air sirkulasi mendekati 2000 ppm,
2 TDS ppm 2000, max buka valve blowdown / tambah rate blowdown hingga TDS <
2000 ppm
Bila Conductivity air basin atau air sirkulasi mendekati 3500
ppm, buka valve blowdown / tambah rate blowdown hingga
3 Conductivity ppm 3500, max
TDS < 3500 ppm

Bila silica mendekati 150 ppm, lakukan blowdown hingga

ppm 150, max
4 Silica (SiO )
2
-
nilainya normal kembali.
Bila Fe > 2 ppm, cek proses pre-treatment & dosis chemical
ppm 2, max eksternal. Lalu bila terjadi kenaikan Fe yang signifikan,
5 Iron (Fe) kurangi dosis EONBIO BD 3291.
Bila chloride mendekati 250 ppm, lakukan blowdown hingga
ppm 250, max
5 Chloride nilainya normal kembali.
Bila nilai bacterial growth >104 cfu/ml, tambah stroke / dosis
cfu/ml 104, max
6 Bacterial Growth EONBAC BC 3107 / EONLINE T780 & EONBIO BD 3291
Bila nilai fungal growth >104 cfu/ml, tambah stroke / dosis
cfu/ml 104, max
7 Fungal Growth EONBAC BC 3107 / EONLINE T780 & EONBIO BD 3291
Bila nilai Free Chlorine < 0.2, tambah stroke / dosis EONBAC
BC 3107
8 Free Chlorine ppm 0.2 - 1
Bila nilai Free Chlorine > 1, kurangi stroke / dosis EONBAC
BC 3107
 LAMPIRAN-1

MSDS
 LAMPIRAN-2

MSDS
 LAMPIRAN-3

BROSUR
 LAMPIRAN-4

BROSUR